Rigid polyurethane foam plastic and preparation method thereof

A technology of rigid foam plastics and polyurethane, applied in the field of foam plastics, can solve the problems of low closed cell ratio, influence on product strength, low compressive strength, etc., and achieve stable chemical properties, easy manual operation, and small thermal conductivity Effect

Inactive Publication Date: 2019-11-19
浙江大众隔热科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The production process is complex and pollutes the environment
[0004] The following defects in the prior art: in the synthesis process of polyurethane, due to the problem of raw materials, it is easy to cause problems such as foam collapse, shrinkage, short gel time, and low closed cell rate of the cavity, which eventually leads to the impact of the strength of the product and the resistance to corrosion. Low compressive strength; moreover, in the process of using the foaming mold in the prior art with the mixture, not only the raw materials are easy to overflow during the foaming process, resulting in poor quality of the final foamed plastics but also the produced foamed products cannot Meet the demand, the operation is cumbersome and not suitable for industrial production

Method used

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  • Rigid polyurethane foam plastic and preparation method thereof
  • Rigid polyurethane foam plastic and preparation method thereof
  • Rigid polyurethane foam plastic and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A preparation method for rigid polyurethane foam, comprising the steps of:

[0040] a with 40 parts of vegetable oil polyether polyols; 20 parts of petroleum polyester polyols; 10 parts of polyethylene oxide polyols; 1 part of pentamethyldialkylene triamine; 4 parts of esters, 6 parts of trialkyl phosphates); After mixing, a mixture is obtained;

[0041] b. Control the temperature of the mixture at 30-40°C. Under the condition of ambient temperature of 30-35°C, quickly add 3 parts of silicone oil as a stabilizer; 20 parts of water as a foaming agent; 0.02 parts of stannous octoate as an organometallic catalyst ; Under the condition of controlling the rotational speed of 1000-2000r / min, stirring for 10-20s to obtain the combined material;

[0042] c. Pour the obtained combination into a polyurethane foaming mold, quickly cover and lock the mold, and release the mold in 15 to 20 minutes to obtain rigid polyurethane foam.

[0043] Polyurethane foam mold includes:

[004...

Embodiment 2

[0061] A preparation method for rigid polyurethane foam, comprising the steps of:

[0062] a with 42 parts of vegetable oil polyether polyols; 22 parts of petroleum polyester polyols; 13 parts of polyethylene oxide polyols; 1.4 parts of pentamethyldialkylene triamines; 14 parts of flame retardants (trialkyl 5 parts of phosphoric acid esters, 9 parts of tetraalkyl diphosphonate compounds); After mixing, a mixture is obtained;

[0063] b. Control the temperature of the mixture at 30-40°C. Under the condition of ambient temperature of 30-35°C, quickly add 3.5 parts of silicone oil as a stabilizer; 22 parts of water as a foaming agent; 0.02 parts of stannous octoate as an organometallic catalyst ; Under the condition of controlling the rotational speed of 1000-2000r / min, stirring for 10-20s to obtain the combined material;

[0064] c. Pour the obtained combination into a polyurethane foaming mold, quickly cover and lock the mold, and release the mold in 15 to 20 minutes to obtain...

Embodiment 3

[0069] A preparation method for rigid polyurethane foam, comprising the steps of:

[0070] a with 46 parts of vegetable oil polyether polyols; 24 parts of petroleum polyester polyols; 16 parts of polyethylene oxide polyols; 1.6 parts of pentamethyldialkylene triamines; 8 parts of esters, 4 parts of trialkyl phosphates, 8 parts of tetraalkyl diphosphonate compounds); after mixing, a mixture is obtained;

[0071] b. Control the temperature of the mixture at 30-40°C. Under the condition of ambient temperature of 30-35°C, quickly add 3.6 parts of silicone oil as a stabilizer; 24 parts of water as a foaming agent; 0.03 parts of stannous octoate as an organometallic catalyst ;Under the condition of controlling the rotational speed of 1000-2000r / min, stirring for 10-20s to obtain the combined material;

[0072] c. Pour the obtained combination into a polyurethane foaming mold, quickly cover and lock the mold, and release the mold in 15 to 20 minutes to obtain rigid polyurethane foam...

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Abstract

The invention discloses a rigid polyurethane foam plastic. The rigid polyurethane foam plastic is characterized by comprising the following components in parts by weight: 1-2 parts of pentamethyldialkylene triamine, 60-80 parts of water, 10 to 26 parts of a flame retardant, 3-4 parts of a stabilizer, 20-30 parts of a foaming agent, 0.02 to 0.03 part of an organic metal catalyst, 40 to 50 parts ofvegetable oil polyether polyol, 20 to 30 parts of petroleum polyester polyol, and 10 to 20 parts of polyethylene oxide polyol. The rigid polyurethane foam plastic disclosed by the invention has the beneficial effects that a foaming body is a low-temperature thermal-insulation material with a pore cavity high in the percentage of close area and low in water absorption rate, and the rigid polyurethane foam plastic has the advantages of small heat conductivity coefficient, high strength, stable chemical performance and convenience in construction; according to the preparation method for the rigidpolyurethane foam plastic, a polyurethane foaming mold is adopted in the preparation process, so in the process of foaming, raw materials do not overflow, foam does not collapse or shrink, the arrangement of a bracket allows the mold to be convenient to take after foaming is finished, and manual operation is facilitated.

Description

technical field [0001] The invention relates to the technical field of foamed plastics, in particular to a rigid polyurethane foamed plastic and a preparation method thereof. Background technique [0002] Polyurethane is a new generation of synthetic polymer materials. Its mechanical properties and physical and chemical properties are very special. By choosing different numbers of functional groups and different types of functional groups, and using different processes, polyurethane products with different removal properties can be prepared. [0003] Polyurethane foam castables are widely used in many fields of the national economy because of their excellent thermal insulation properties: such as thermal insulation of central heating pipelines, insulation layers of refrigerators, freezers, water heaters, and cold storage. The production process is complex and pollutes the environment. [0004] The following defects in the prior art: in the synthesis process of polyurethan...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/67C08G18/66C08G18/48C08G18/42C08K5/521C08K5/523C08K5/5333C08G101/00
CPCC08G18/4018C08G18/42C08G18/4833C08G18/6618C08G18/6795C08K5/521C08K5/523C08K5/5333C08G2110/0025C08G2110/0083
Inventor 项品海
Owner 浙江大众隔热科技有限公司
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