Current collector, preparation method thereof, electrode plate, preparation method of electrode plate, and lead-acid battery
A current collector and electrode sheet technology, applied in the field of lead-acid batteries, can solve the problems of short cycle life, incomplete reaction of positive and negative active materials, and low specific energy of lead-acid batteries, so as to improve cycle life, high rate performance and Utilization efficiency, effect of density reduction
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[0042] The present invention also provides a method for preparing a fluid collector, comprising the steps of:
[0043] In the first step, a precursor solution is configured, and the precursor solution is a polymerizable water-based polymer precursor solution.
[0044] In the second step, fibers are added into the precursor solution and the fibers are uniformly dispersed in the precursor solution.
[0045] In the third step, the precursor solution is heated to cause in-situ polymerization to obtain a hydrogel. The fibers are packed within the hydrogel.
[0046] The fourth step is to dry the hydrogel to obtain an organogel with ideal network structure.
[0047] The fifth step is to heat and carbonize the organogel in an oxygen-free environment to obtain a fiber-reinforced carbon-airgel composite material.
[0048] Wherein, the fiber is used to increase the flexibility and processability of the fiber-reinforced carbon airgel composite material.
[0049] Wherein, before the step...
Embodiment 1
[0085] Embodiment 1 Preparation of fiber-reinforced carbon aerogel
[0086] In a 3-liter cuboid container, mix resorcinol and formaldehyde dissolved in water at a molar ratio of 1:2, the ratio of phenolic formaldehyde to water is 1:8, and add sodium carbonate accounting for 1 / 1000 of resorcinol solution. Stir for 30 minutes to combine well. Add 30 grams of carbon fibers with a length of 5 mm, and disperse them by stirring and ultrasonic to make the carbon fibers uniformly dispersed. Seal the container, place it in an environment of 85° C., and keep it for 4 days to obtain a hydrogel. Dry at 60° C. for 24 hours under normal pressure to obtain an organogel. Machined and cut into grid shapes. Carbonize at 800°C for 2 hours in an oxygen-free environment. Fiber-reinforced carbon airgel can be obtained.
Embodiment 2
[0087] Example 2 Preparation of Fiber Reinforced Carbon Aerogel
[0088] In a 3-liter cuboid container, mix resorcinol and formaldehyde dissolved in water at a molar ratio of 1:2, the ratio of phenolic formaldehyde to water is 1:9, and add sodium carbonate accounting for 1 / 800 of resorcinol solution. Stir for 30 minutes to combine well. Add 40 grams of polyacrylonitrile fibers with a length of 4 mm and 1 gram of sodium benzenesulfonate, and disperse by stirring and ultrasonic to make the polyacrylonitrile fibers evenly dispersed. Seal the container, place it in an environment of 85° C., and keep it for 3 days to obtain a hydrogel. Dry at 60° C. for 24 hours under normal pressure to obtain an organogel. Machined and cut into grid shapes. Carbonize at 800°C for 2 hours in an oxygen-free environment. Carbon fiber-reinforced carbon airgel can be obtained.
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Abstract
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