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Glass fiber felt reinforced thermoplastic composite material and preparation method thereof

A glass fiber mat and reinforced thermoplastic technology, which is applied in the field of glass fiber mat reinforced thermoplastic composite materials and its preparation, can solve the problems of low tensile performance, low impact performance, glass fiber damage, etc., to improve high temperature fluidity, excellent molding Effect of Formability, High Tensile Strength and Notched Impact Strength

Active Publication Date: 2019-06-21
GUANGZHOU KINGFA CARBON FIBER NEW MATERIALS DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The product obtained by this patent uses glass fibers in the glass fiber mat with a fixed length of 3~24mm, which is bonded by a wet process with an emulsion adhesive. The odor of the emulsion adhesive is large, which limits the product's internal Use on trim and other parts with strict odor rating requirements
At the same time, the patented product is obtained through the banburying process, and the glass fiber will be damaged and shortened during the banburying process, resulting in low mechanical properties
In this patent example, under the premise that no compatibilizer or a large amount of compatibilizer is added to the formula, the tensile performance is low (30~50MPa), and the impact performance is low (2 ), which cannot meet the strength requirements and impact resistance requirements of the body and main load-bearing structure
Although the tensile strength and flexural strength are increased (>100 MPa) after adding a large amount of maleic anhydride grafted modification in this formula, the cost is greatly increased and the odor of the product is even heavier

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Preparation of glass fiber mat: the length of the glass fiber bundle used is 15mm, the diameter is 16um, and bisphenol A unsaturated polyester is used as the adhesive, and the addition amount is 5wt% based on the total weight of the glass fiber mat, and the glass fiber bundle Disperse on the mesh belt, spread the adhesive evenly in the glass fiber bundles, and then heat the adhesive to cure to form a glass fiber mat; preparation of the resin matrix: based on the total weight of the resin matrix, 97.5wt% of polypropylene Resin (melt index is 25g / 10min, odor level is 2.5 grades), 2wt% of carbon black M717, 0.25wt% of antioxidant 1010 and 0.25wt% of antioxidant 168, mix evenly in a high-speed mixer, and then In the extruder, the resin matrix particles are obtained by melting, blending, extruding and granulating, and then the resin matrix particles are pressed into a resin matrix; the preparation of the glass fiber mat reinforced thermoplastic composite material: the resin m...

Embodiment 2

[0046]Preparation of glass fiber mat: the length of the glass fiber bundle used is 25mm, the diameter is 16um, and bisphenol A unsaturated polyester is used as the adhesive, and the addition amount is 5wt% based on the total weight of the glass fiber mat, and the glass fiber bundle Disperse on the mesh belt, spread the adhesive evenly in the glass fiber bundles, and then heat the adhesive to cure to form a glass fiber mat; preparation of the resin matrix: based on the total weight of the resin matrix, 97.5wt% of polypropylene Resin (melt index is 25g / 10min, odor level is 2.5 grades), 2wt% of carbon black M717, 0.25wt% of antioxidant 1010 and 0.25wt% of antioxidant 168, mix evenly in a high-speed mixer, and then In the extruder, the resin matrix particles are obtained by melting, blending, extruding and granulating, and then the resin matrix particles are pressed into a resin matrix; the preparation of the glass fiber mat reinforced thermoplastic composite material: the resin ma...

Embodiment 3

[0049] Preparation of glass fiber mat: The length of the glass fiber bundle used is 70mm, the diameter is 16um, and bisphenol A unsaturated polyester is used as the adhesive, and the addition amount is 5wt% based on the total weight of the glass fiber mat, and the glass fiber bundle Disperse on the mesh belt, spread the adhesive evenly in the glass fiber bundles, and then heat the adhesive to cure to form a glass fiber mat; preparation of the resin matrix: based on the total weight of the resin matrix, 97.5wt% of polypropylene Resin (melt index is 25g / 10min, odor level is 2.5 grades), 2wt% of carbon black M717, 0.25wt% of antioxidant 1010 and 0.25wt% of antioxidant 168, mix evenly in a high-speed mixer, and then In the extruder, the resin matrix particles are obtained by melting, blending, extruding and granulating, and then the resin matrix particles are pressed into a resin matrix; the preparation of the glass fiber mat reinforced thermoplastic composite material: the resin m...

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Abstract

The invention discloses a glass fiber felt reinforced thermoplastic composite material, which is mainly formed by carrying out hot pressing on 35-60 wt% of a glass fiber felt and 40-65 wt% of a resinmatrix, wherein the glass fiber felt comprises 90-97 wt% of a glass fiber bundle and 3-10 wt% of a binder, the glass fiber bundle has a length of 15-70 mm and a fiber diameter of 5-20 [mu]m, the binder of the glass fiber felt is at least one selected from a thermosetting adhesive, the thermosetting adhesive at least one selected from an unsaturated polyester type adhesive, a polyurethane type adhesive and a urea formaldehyde resin, and the melt mass flow rate of the thermoplastic resin is 25-60 g / 10 min at a temperature of 190 DEG C under a load of 2.16 Kg. According to the present invention,the glass fiber felt reinforced thermoplastic composite material has advantages of low odor, excellent tensile strength, excellent notched impact strength and excellent compression moldability.

Description

technical field [0001] The invention relates to the field of composite polymer materials and processing thereof, in particular to a glass fiber mat reinforced thermoplastic composite material and a preparation method thereof. Background technique [0002] Glass fiber mat reinforced thermoplastic is a new type of engineering plastic. Glass fiber mat reinforced thermoplastic is a composite material with thermoplastic resin as the matrix and glass fiber mat as the reinforced skeleton. Generally, semi-finished sheets can be produced, and then directly processed into products of the required shape. It can be chopped glass fiber mat or continuous glass fiber mat, and the thermoplastic resin can be general purpose plastic, engineering plastic or other high performance plastic. Glass fiber mat-reinforced thermoplastics have good mechanical properties, short molding cycle, low production cost, can mold large and complex parts, and have good dimensional stability. They are widely use...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L67/06C08K13/04C08K7/14C08K3/04
Inventor 黄险波范欣愉孟姗姗陈大华孙雅杰秦永利邓荣坚李晓拓熊鑫刘玲宋威
Owner GUANGZHOU KINGFA CARBON FIBER NEW MATERIALS DEV
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