Low odor acrylate adhesive for level bonding and preparation method of low odor acrylate adhesive

An acrylate, low-odor technology, used in adhesives, adhesive additives, polymer adhesive additives, etc., can solve the problems of poor plastic bonding strength, unfriendly environment, low temperature resistance and impact resistance, etc. Good low temperature impact, good peel strength and shear strength, low odor effect

Pending Publication Date: 2019-05-21
康达新材料(集团)股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In order to overcome the above-mentioned defects of the prior art, one of the objects of the present invention is to provide a low-odor acrylic adhesive for level bonding, which can solve the problem that the existing adhesive is not friendly to the environment, is not resistant to low temperature and Impact ability and poor bonding strength to plastics

Method used

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  • Low odor acrylate adhesive for level bonding and preparation method of low odor acrylate adhesive
  • Low odor acrylate adhesive for level bonding and preparation method of low odor acrylate adhesive
  • Low odor acrylate adhesive for level bonding and preparation method of low odor acrylate adhesive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 and

[0048] Embodiment 1 and comparative example:

Embodiment 1

[0049] Embodiment 1 and comparative example are specifically shown in Table 1:

[0050] Table 1

[0051]

[0052]

[0053] Preparation Process:

[0054] Preparation of component A: tetrahydrofuryl methacrylate, hydroxypropyl methacrylate, hydroxyethyl methacrylate, ethoxylated bisphenol A dimethacrylate, B564, SBS, polybutadiene rubber, paraffin wax , Hydroquinone, and oxalic acid are put into the reaction kettle, and stirred until B564 and SBS are completely dissolved; then, cumene hydroperoxide and KH560 are put into the reaction kettle and stirred for 1-2 hours until the mixture is uniform, and the bubbles are removed in a vacuum to obtain component A ;

[0055] Preparation of component B: tetrahydrofuryl methacrylate, hydroxypropyl methacrylate, hydroxyethyl methacrylate, ethoxylated bisphenol A dimethacrylate, B564, SBS, polybutadiene rubber, paraffin wax , hydroquinone, and oxalic acid were put into the reactor, and stirred until B564 and SBS were completely dis...

Embodiment 2

[0058] Embodiment 2 is specifically shown in Table 2:

[0059] Table 2

[0060]

[0061]

[0062] The preparation process is the same as in Example 1.

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PUM

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Abstract

The invention discloses a low odor acrylate adhesive for level bonding, which comprises a component A and a component B, wherein the component A comprises the following raw materials: 40-65wt% of monofunctional acrylate monomer, 1-10wt% of bifunctional acrylate monomer, 15-30wt% of shock resistance core-shell resin, 5-15wt% of elastomer, 1-5wt%of initiator, 0.1-1wt% of stabilizer, 0.1-2wt%of coupling agent and 0.3-1wt% of volatilization inhibitor; the component B comprises the following raw materials: 40-65wt% of monofunctional acrylate monomer, 1-10wt% of bifunctional acrylate monomer, 15-30wt% of shock resistance core-shell resin, 5-15wt% of elastomer, 1-3wt% of adhesion accelerator, 0.1-1wt% of reducer, 0.1-1wt% of stabilizer, 0.01-1wt% of accelerator and 0.3-3wt% of volatilization inhibitor; and the component A and the component B are uniformly mixed at a volume ratio of 1:1. The prepared acrylate structural adhesive has the characteristics of low odor, environmental friendliness,good low temperature impact resistance and the like, and higher stripping strength and shear strength for plastics and metals.

Description

technical field [0001] The invention relates to the technical field of two-component acrylic structural adhesives, in particular to a low-odor acrylic adhesive used for level bonding and a preparation method thereof. Background technique [0002] Two-component acrylate adhesives are widely used in structural bonding in various industries due to their characteristics of fast curing at room temperature, high strength, good toughness, and simple process. With the improvement of environmental protection requirements, many factory workers require the use of acrylic structural adhesives that do not contain strong pungent odors (such as methyl methacrylate). [0003] Instant adhesive has excellent fast positioning performance, but usually has poor heat resistance and moisture resistance, low peel strength and impact strength, especially in low temperature environments with almost no impact strength. [0004] Two-component epoxy adhesive has the characteristics of high temperature ...

Claims

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Application Information

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IPC IPC(8): C09J4/06C09J4/02C09J11/06C09J11/08C08F220/28C08F220/20
Inventor 葛于晶陈勇
Owner 康达新材料(集团)股份有限公司
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