Organic electrolytic solution taking gamma-butyrolactone as basic solvent

An organic electrolyte and basic solvent technology, applied in the field of electrolytes, can solve the problems of reduced capacitor capacity, insufficient supply, and lack of discharge performance, and achieves small changes in electrical parameters, good low temperature performance, and improved low temperature conductivity and low temperature. performance effect

Inactive Publication Date: 2019-04-12
JIANGSU FALA ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] An aluminum electrolytic capacitor is a capacitor made of an aluminum cylinder as the negative electrode, which is filled with a liquid electrolyte, and a bent aluminum strip is inserted as the positive electrode. The capacitor is called an aluminum electrolytic capacitor; Expected capacitance, electrolyte The electrolyte is the actual cathode of the aluminum electrolytic capacitor, which plays an important role in providing oxygen ions and repairing the anodic oxide film. At present, the application field of aluminum electrolytic capacitors is obviously limited by the working temperature range, and does not have Provide suitable discharge performance in a wide temperature range; if the temperature is too low, the capacity of the capacitor will decrease, and it will not even be enough to provide sufficient DC support for the power supply. Generally, the electrolyte should have better low temperature performance, so high-performance electrolyte is essential for ensuring Aluminum electrolytic capacitors play a vital role; in addition, in hot summer weather, the capacitors of charging piles are also required to have better temperature control performance, which puts forward higher requirements for the electrolyte

Method used

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  • Organic electrolytic solution taking gamma-butyrolactone as basic solvent
  • Organic electrolytic solution taking gamma-butyrolactone as basic solvent

Examples

Experimental program
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Effect test

Embodiment 1

[0012] The organic electrolyte provided in this example is composed of tetraethylammonium tetrafluoroborate, a mixed solvent and a flame retardant additive. The concentration of tetraethylammonium tetrafluoroborate is 0.8M, and the mixed solvent consists of the following weight ratio: Composition of components: 40 parts of γ-butyrolactone, 21 parts of ethyl trifluoroacetate, 11 parts of 1,3-dioxolane-2-one, 14 parts of ethylene carbonate and 14 parts of ethyl methyl carbonate; The flame retardant additive occupies 2% of the total weight of the organic electrolyte, wherein the flame retardant additive is a mixture of trimethyl phosphate and tri-(2,2,2-trifluoroethyl) phosphate.

Embodiment 2

[0014] The organic electrolyte provided in this example is composed of tetraethylammonium tetrafluoroborate, a mixed solvent and a flame retardant additive. The concentration of tetraethylammonium tetrafluoroborate is 1M, and the mixed solvent consists of the following weight ratio: Composition: 33 parts of γ-butyrolactone, 22 parts of ethyl trifluoroacetate, 14 parts of 1,3-dioxolane-2-one, 16 parts of ethylene carbonate and 15 parts of ethyl methyl carbonate; The flame retardant additive accounts for 2.5% of the total weight of the organic electrolyte, and the flame retardant additive is triphenyl phosphate and hexamethylphosphazene.

Embodiment 3

[0016] The organic electrolyte solution provided in this example is composed of quaternary ammonium salt triethylmethylammonium tetrafluoroborate, a mixed solvent and a flame retardant additive. The concentration of the quaternary ammonium salt triethylmethylammonium tetrafluoroborate is 1.2M. The mixed solvent is composed of the following components by weight: 42 parts of γ-butyrolactone, 17 parts of ethyl trifluoroacetate, 13 parts of 1,3-dioxolane-2-one, 13 parts of ethylene carbonate and 15 parts of ethyl methyl carbonate; Described flame retardant additive occupies 1.5% of organic electrolyte gross weight, and flame retardant additive is hexamethylphosphazene and three one (2,2,2-trifluoroethyl) phosphoric acid ester mixture.

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Abstract

The invention discloses an organic electrolytic solution taking gamma-butyrolactone as a basic solvent. The organic electrolytic solution comprises a catenulate quaternaries main electrolyte, a mixedsolvent and a flame retardant additive, wherein the mixed solvent comprises the following components by weight proportion: 30-45 parts of gamma-butyrolactone, 15-25 parts of ethyl trifluoroacetate, 10-15 parts of 1,3-dioxolane-2-ketone, 10-20 parts of ethylene carbonate and 10-20 parts of methyl ethyl carbonate. The organic electrolytic solution replaces the traditional polycarbonate ammonium saltwith tetraethyl ammonium tetrafluoroborate, so that a battery has good low-temperature performance; the change of various electric parameters of the electrolytic solution is obviously small after 500h storage at 115 DEG C high temperature, so that the high-temperature service life of the electrolytic solution is long; and the methyl ethyl carbonate is added, so that the low-temperature conductivity and the low-temperature performance of the electrolytic solution can be improved.

Description

technical field [0001] The invention relates to the technical field of electrolytes, and more specifically relates to an organic electrolyte with gamma-butyrolactone as a base solvent. Background technique [0002] An aluminum electrolytic capacitor is a capacitor made of an aluminum cylinder as the negative electrode, which is filled with a liquid electrolyte, and a bent aluminum strip is inserted as the positive electrode. The capacitor is called an aluminum electrolytic capacitor; Expected capacitance, electrolyte The electrolyte is the actual cathode of the aluminum electrolytic capacitor, which plays an important role in providing oxygen ions and repairing the anodic oxide film. At present, the application field of aluminum electrolytic capacitors is obviously limited by the working temperature range, and does not have Provide suitable discharge performance in a wide temperature range; if the temperature is too low, the capacity of the capacitor will decrease, and it wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/035
CPCH01G9/035
Inventor 夏杰陈敏
Owner JIANGSU FALA ELECTRONICS
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