A method of electrochemical reduction-thermochemical cycle decomposition of water to produce hydrogen
A thermochemical cycle and electrochemical technology, applied in chemical instruments and methods, hydrogen production, inorganic chemistry, etc., can solve the problems of difficult matching of heat sources and high temperature, and achieve the effect of avoiding material problems, being easy to implement, and simplifying the process route.
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Embodiment 1
[0028] Embodiment 1: Electrochemical reduction generates iron.
[0029] Step 1: Weigh 23.55g of 56.5mol% Li 0.87 Na 0.63 K 0.50 CO 3 – 43.5mol% LiOH mixture, and then weighed 1.87 g of Fe 2 o 3 Grind and mix well, use a nickel sheet as the anode (1 cm × 3 cm), and a 304 stainless steel sheet (1 cm × 3 cm) as the cathode, fix the anode and cathode, and put the ground and mixed electrolyte into a corundum crucible.
[0030] Step 2: Put the corundum crucible into an electric furnace to heat up to 500°C, and connect the anode and cathode to a DC power supply.
[0031] Step 3: Turn on the power supply and perform constant current electrolysis at 0.5 A for 240 min.
[0032] Step 4: After the electrolysis, cut off the power supply, take out the cathode, and use XRD to analyze the electrolysis product on the electrolyte and the cathode. The results are shown in figure 1 ,Depend on figure 1 It can be seen that iron is generated on the cathode after electrolysis.
Embodiment 2
[0034] Step 1 and Step 2 of this embodiment are the same as Step 1 and Step 2 in Embodiment 1.
[0035] Step 3: Turn on the power, and electrolyze for 5, 10, 20, 40 and 60 min at a constant current of 0.5 A, respectively.
[0036] Step 4: Cut off the power supply after the electrolysis, and then use the N with a flow rate of 80 mL / min 2 Water vapor at 250°C was carried and blown to the stainless steel sheet cathode to react with the new ecological Fe formed by electrolysis for 120 min.
[0037] Step 5: The gas discharged from the electrolytic cell is collected by the drainage and gas collection method, and the hydrogen content is analyzed by gas chromatography. see results figure 2 , it can be seen from the figure that as the electrolysis time increases, the amount of hydrogen produced increases, and the current efficiencies at 5, 10, 20, 40 and 60 min are 13.3%, 28.9%, 21.5%, 23.1% and 27.1% respectively .
Embodiment 3
[0039] Step 1 and Step 2 of this embodiment are the same as Step 1 and Step 2 in Embodiment 1.
[0040] Step 3: Turn on the power supply, and electrolyze for 60 min at a constant current of 0.5 A.
[0041] Step 4 of this embodiment is the same as step 4 in specific embodiment 2.
[0042] Step 5: The gas discharged from the electrolytic cell is collected by the drainage and gas collection method, and the hydrogen content is analyzed by gas chromatography.
[0043] Step 6: Recycle back to Step 1 of this embodiment to carry out the next electrochemical reduction process - thermochemical water splitting process to produce hydrogen. see results image 3 , it can be seen from the figure that the hydrogen production and current efficiency of the electrochemical reduction process-thermochemical water splitting process for hydrogen production are basically constant for 4 cycles, indicating that the electrochemical reduction process-thermochemical water splitting process for hydrogen pr...
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