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Rubber composition, application to foam products and production method

A rubber composition and foaming agent technology, applied to rubber compositions, can solve the problems of decreased tensile strength and tear strength, difficulty in achieving vulcanization and foaming, etc.

Active Publication Date: 2018-07-20
HANGZHOU XINGLU TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the conventional rubber foaming process, the traditional method is to add an ultra-fast accelerator to the rubber to achieve rapid pre-crosslinking of the rubber, but this method is difficult to achieve the matching of vulcanization and foaming; One-step molding process, that is, the first molding at a lower temperature (120-140°C) for 20-50 minutes, so that the rubber has a certain degree of pre-crosslinking and begins to partially foam, and then the size is 20 times larger than the original. ~50% of the mold is heated for the second time to completely decompose the foaming agent and vulcanize and set it
In order to obtain good heat resistance, aging resistance and compression set resistance, some ethylene-propylene rubber foam materials will use a peroxide vulcanization system, and the foam material will form a single carbon-carbon crosslink bond, but compared to Sulfur vulcanization system, which also has the problem of decreased tensile strength and tear strength, and difficulty in pre-vulcanization at a lower temperature of 120-140°C

Method used

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  • Rubber composition, application to foam products and production method
  • Rubber composition, application to foam products and production method
  • Rubber composition, application to foam products and production method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0111] The number of branched polyethylene used is PER-9.

[0112] The processing steps of rubber composition are as follows:

[0113] (1) Rubber mixing: set the temperature of the internal mixer to 90°C, and the rotor speed to 50 rpm, add 90 parts of EPDM rubber and 10 parts of branched polyethylene for pre-compression mixing for 90 seconds; add 10 parts of oxidized Zinc and 2 parts of stearic acid, kneaded for 1 minute; then added 5 parts of calcium oxide and 2 parts of polyethylene glycol PEG4000, kneaded for 1 minute; then added 50 parts of carbon black N550, Mix 20 parts of carbon black N765, 50 parts of calcium carbonate and 70 parts of paraffin oil SUNPAR2280 for 4 minutes; finally add 3 parts of crosslinking agent dicumyl peroxide (DCP), 1 part of auxiliary crosslinking agent triallyl isocyanide Urate ester (TAIC), 20 parts of foaming agent azodicarbonamide (AC) and 2 parts of foaming agent urea, after mixing for 3 minutes, discharge glue. Thinly pass the mixed rubbe...

Embodiment 2

[0116] The branched polyethylene code used is PER-2.

[0117] The processing steps of rubber composition are as follows:

[0118] (1) Rubber mixing: set the temperature of the internal mixer to 90°C, the rotor speed to 50 rpm, add 20 parts of binary ethylene propylene rubber, 50 parts of EPDM rubber and 30 parts of branched polyethylene for pre-compression mixing Refining for 90 seconds; adding 10 parts of zinc oxide and 2 parts of stearic acid, kneading for 1 minute; then adding 5 parts of calcium oxide and 2 parts of polyethylene glycol PEG4000, kneading for 1 minute; Add 75 parts of carbon black N550, 50 parts of carbon black N765, 75 parts of calcium carbonate and 90 parts of paraffin oil SUNPAR2280 and mix for 4 minutes; finally add 6 parts of cross-linking agent dicumyl peroxide (DCP), 2 parts of cross-linking agent Linking agent triallyl isocyanurate (TAIC), 8 parts of co-crosslinking agent liquid 1,2-polybutadiene, 20 parts of blowing agent azodicarbonamide (AC) and 2...

Embodiment 3

[0121] The number of branched polyethylene used is PER-5.

[0122] The processing steps of rubber composition are as follows:

[0123] (1) Rubber mixing: set the temperature of the internal mixer to 90°C, and the rotor speed to 50 rpm, add 50 parts of EPDM rubber and 50 parts of branched polyethylene for pre-compression mixing for 90 seconds; add 10 parts of oxidized Zinc and 2 parts of stearic acid, kneaded for 1 minute; then added 5 parts of calcium oxide and 2 parts of polyethylene glycol PEG4000, kneaded for 1 minute; then added 75 parts of carbon black N550, Mix 50 parts of carbon black N765, 75 parts of calcium carbonate and 70 parts of paraffin oil SUNPAR2280 for 4 minutes; finally add 3 parts of crosslinking agent dicumyl peroxide (DCP), 1 part of auxiliary crosslinking agent triallyl isocyanide Urate ester (TAIC), 22 parts of foaming agent azodicarbonamide (AC) and 3 parts of foaming agent urea, after mixing for 3 minutes, discharge the rubber, and put the mixed rubb...

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Abstract

The invention discloses rubber composition, a processing method thereof, an application of the composition to foam product production and a method. The rubber composition is prepared from a rubber matrix and essential components, wherein the rubber matrix contains a parts of branched polyethylene and b parts of EPM rubber and EPDM rubber, a is larger than 0 and smaller than or equal to 100 parts,and b is larger than or equal to 0 and smaller than 100 parts; the essential components comprise 0.5-10 parts of a crosslinking agent and 1.5-25 parts of a foaming agent. The rubber composition applies to processing of sponge sealing strips, foam materials with high foaming ratio, damping foam rubber boards, light-color high-strength foam boards, foam solid compound sealing strips as well as solidtires filled with foam elastomers. The rubber composition has the beneficial effects as follows: branched polyethylene not only contains short branch chains of methyl, ethyl, propyl, butyl, amyl andthe like, but also contains long branch chains with carbon number larger than 6, by replacing ethylene propylene rubber in the foam rubber composition partially or completely with branched polyethylene, melt strength of the rubber composition can be improved, foamability, especially pre-foamability of the composition is improved, and the obtained rubber products have lower compression set.

Description

technical field [0001] The invention belongs to the field of rubber, and in particular relates to a rubber composition and a processing method thereof. The invention also relates to the application of the rubber composition in foamed products, and a method for producing foamed rubber products using the rubber composition , Foamed rubber products include but not limited to sponge sealing strips, high foaming ratio foam materials, shock-absorbing foam rubber sheets, light-colored high-strength foamed sheets, foamed solid composite sealing strips, solid tires filled with foamed elastomers . Background technique [0002] The vulcanization system of ethylene-propylene rubber foaming material is mainly sulfur and peroxide vulcanization system. When the sulfur vulcanization system is used, the foamed material forms a cross-linked structure mainly composed of polysulfide bonds, which has high tensile strength and high tear strength, but the heat resistance and aging resistance are ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08L23/06C08L71/02C08L91/06C08K13/02C08K3/22C08K5/09C08K3/04C08K3/26C08K5/14C08K5/3477C08J9/10
CPCC08J9/0023C08J9/0028C08J9/0061C08J9/0066C08J9/103C08J2323/16C08J2203/04C08K5/3477C08K2003/265C08K2003/2296C08K13/02C08K2003/2206C08J2471/02C08K5/09C08J2491/06C08K3/04C08K5/14C08J2423/06B60C7/1015C08L23/16C08L23/04C08L2205/03C08L2203/14C08J9/105C08J9/32C08J2203/22C08J9/0095C08J9/0042C08J2323/06C08J2423/16C08J2203/18B60C1/00B60C2001/0091B60C2200/12C08K3/22C08K3/26C08K5/21C08K5/23C08L71/02C08L91/06C08J9/142C08J2203/184C08J2203/204C08L23/06C08L2205/025C08L2312/00
Inventor 不公告发明人
Owner HANGZHOU XINGLU TECH CO LTD
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