Novel spectrum adjustable self-activated fluorescent powder
A technology of self-activation and fluorescent powder, applied in the direction of luminescent materials, chemical instruments and methods, etc., can solve the problem of high cost
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Embodiment 1
[0020] According to the expression Ca 2-x A x Ba 3 (PO 4 ) 2 SiO 4 , take A=Sr, x=0.4, weigh BaCO 3 (0.7464 g), NH 4 h 2 PO 4 (0.2900 g), CaCO 3 (0.2019 g), SrCO 3 (0.0744 g), SiO 2 (0.0758 grams). Grind thoroughly in an agate mortar and mix evenly, transfer to a corundum crucible, place the resulting mixture in a muffle furnace, 2 +N 2 Burned at 1000°C for 6 hours in a reducing atmosphere to obtain the required self-activated phosphor.
Embodiment 2
[0022] According to the expression Ca 2-x A x Ba 3 (PO 4 ) 2 SiO 4 , take A=Sr, x=0.8, weigh BaCO 3 (0.7289 g), NH 4 h 2 PO 4 (0.2832 g), CaCO 3 (0.1479 g), SrCO 3 (0.1454 g), SiO 2 (0.0740 grams). Grind thoroughly in an agate mortar and mix evenly, transfer to a corundum crucible, place the resulting mixture in a muffle furnace, 2 +N 2 Burned at 1000°C for 6 hours in a reducing atmosphere to obtain the required self-activated phosphor.
Embodiment 3
[0024] According to the expression Ca 2-x A x Ba 3 (PO 4 ) 2 SiO 4 , take A=Sr, x=1.6, weigh BaCO 3 (0.6903 g), NH 4 h 2 PO 4 (0.2706 g), CaCO 3 (0.0471 g), SrCO 3 (0.2778 g), SiO 2 (0.0707 grams). Grind thoroughly in an agate mortar and mix evenly, transfer to a corundum crucible, place the resulting mixture in a muffle furnace, 2 +N 2 Burned at 1000°C for 6 hours in a reducing atmosphere to obtain the required self-activated phosphor.
[0025] combine figure 2 , Figure 4 Illustrate embodiment 1~3, figure 2 It is the normalized emission spectrum of the self-activating phosphor material with adjustable spectrum in Examples 1 to 3 of the present invention. Curve 1 is the emission spectrum of the self-activating phosphor material with adjustable spectrum in Example 1, and curve 2 is the adjustable spectrum in Example 2. The emission spectrum of self-activating phosphor material, curve 3 is the emission spectrum of embodiment 3 spectrally adjustable self-activ...
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