Heat-resistant, antibacterial and sun-proof camellia flower nanometer microcapsule with long-term slow release effect and preparation method thereof
A technology of camellia and camellia oil, which is applied in the directions of microcapsule preparations, medical preparations with inactive ingredients, and medical preparations containing active ingredients, etc., can solve the problem of difficulty in obtaining submicron-sized essence microcapsules, difficulty in redispersion and processing. , poor heat resistance of urea-formaldehyde resin, etc., to achieve the effect of improving human immunity, less reunion, and preventing neurological decline.
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Embodiment 1
[0025] Step 1: Add camellia oil and sulfonate emulsifier into deionized water, and emulsify mechanically for 0.1h to obtain camellia emulsion, wherein the mass percentage of camellia oil, emulsifier, and deionized water is 1:0.01:0.1;
[0026] Step 2: Add butyl titanate and ethyl silicate to the camellia emulsion, add ammonia solution under constant stirring, adjust the pH to 7, and react for 0.5h to obtain a camellia emulsion containing silica sol and titanium sol, in which camellia oil and The mass percentage of butyl titanate and ethyl silicate is 1:0.2:0.2, and the molar concentration of ammonia solution is 0.1mol / L;
[0027] Step 3: Add the camellia emulsion containing silica sol and titanium sol into the spray reactor and spray it out, and react to obtain camellia nano-microcapsules with camellia oil as the core material and titanium dioxide and silicon dioxide as the wall materials. The reaction temperature is 120 °C , The reaction time is 24h. The particle size of tit...
Embodiment 2
[0029] Step 1: Add camellia oil, carboxylate emulsifier into deionized water, and emulsify mechanically for 6 hours to obtain camellia emulsion, wherein the mass percentage of camellia oil, emulsifier, and deionized water is 1:0.2:10;
[0030] Step 2: Add butyl titanate and ethyl silicate to the camellia emulsion, add ammonia solution under constant stirring, adjust the pH to 12, and react for 24 hours to obtain a camellia emulsion containing silica sol and titanium sol, in which camellia oil and titanium The mass percentage of butyl ester and ethyl silicate is 1:5:5, and the molar concentration of ammonia solution is 5mol / L;
[0031] Step 3: Add the camellia emulsion containing silicon sol and titanium sol into the spray reactor and spray it out, and react to obtain camellia nano-microcapsules with camellia oil as the core material and titanium dioxide and silicon dioxide as the wall materials. The reaction temperature is 300 °C , The reaction time is 0.5h. Among them, the p...
Embodiment 3
[0033] Step 1: Add camellia oil and sulfate emulsifier into deionized water, and emulsify mechanically for 0.5h to obtain camellia emulsion, wherein the mass percentage of camellia oil, emulsifier, and deionized water is 1:0.1:5;
[0034]Step 2: Add butyl titanate and ethyl silicate to the camellia emulsion, add ammonia solution under constant stirring, adjust the pH to 10, and react for 6 hours to obtain a camellia emulsion containing silica sol and titanium sol, in which camellia oil and titanium The mass percentage of butyl ester and ethyl silicate is 1:1.5:1.5, and the molar concentration of ammonia solution is 2mol / L;
[0035] Step 3: Add the camellia emulsion containing silicon sol and titanium sol into the spray reactor and spray it out, and react to obtain camellia nano-microcapsules with camellia oil as the core material and titanium dioxide and silicon dioxide as the wall materials. The reaction temperature is 200 °C , The reaction time is 4h. The particle size of t...
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