Method for preparing melamine resin essence microcapsule finishing agent
A technology of essence microcapsules and melamine resin, which is applied in the direction of microcapsule preparation, microsphere preparation, fiber treatment, etc. It can solve the problems of short fragrance retention time, low fragrance wrapping rate, and low affinity of fabric fibers, etc., and achieves good results. The effect of simplifying the finishing process
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preparation example Construction
[0029] (3) Preparation of melamine resin prepolymer
[0030] Put 5-10 parts of melamine and 10-20 parts of 37% formaldehyde solution into a four-necked bottle in parts by weight, heat up to 60-80°C under stirring conditions, and add 0.1-1 part of triethanolamine after the melamine is completely dissolved, Adjust the pH to 7-10, and react for 10-30 minutes to obtain a transparent and viscous melamine resin prepolymer;
[0031] (4) Preparation of self-adhesive double-wall essence microcapsules
[0032] By weight, 10-30 parts of essence, 2-5 parts of methyl methacrylate, 2-5 parts of acrylonitrile, 1-3 parts of butyl acrylate, 1-3 parts of isooctyl acrylate, 0.2-0.5 parts of methyl Acrylic acid, 0.2-0.5 parts of hydroxyethyl acrylate, 0.1-0.3 parts of diacetone acrylamide, 0.1-0.3 parts of adipic acid dihydrazide, and 0.02-0.05 parts of azobisisobutyronitrile are placed in a beaker at a temperature of 30 Stir and mix at -50°C to form a homogeneous oil solution;
[0033] Mix th...
Embodiment 1
[0037] (1) Preparation of styrene-maleic anhydride copolymer powder
[0038] Add the monomer maleic anhydride, styrene and initiator into the solvent to fully dissolve, then heat the above reaction mixture to 100°C for 1.5h to obtain a metastable dispersion system of the copolymer. After the reaction is completed, centrifuge and Filter and finally dry to obtain styrene-maleic anhydride copolymer powder;
[0039] Wherein, described initiator is organic peroxide; Described solvent is organic acid alkyl ester; The consumption relation of styrene and maleic anhydride, by molar ratio is 9.7:0.3, monomer styrene and The sum of the mass concentrations of maleic anhydride is 15%; the quality of initiator in the reaction system is 0.5% of the monomer gross mass;
[0040] (2) Preparation of styrene-maleic anhydride copolymer solution
[0041] Add 1 part of styrene-maleic anhydride copolymer powder and 17 parts of deionized water into a four-necked bottle in parts by weight, heat up to 6...
Embodiment 2
[0050] (1) Preparation of styrene-maleic anhydride copolymer powder
[0051] Add the monomer maleic anhydride, styrene and initiator into the solvent to fully dissolve, then heat the above reaction mixture to 130°C for 24 hours to obtain a metastable dispersion system of the copolymer. After the reaction is completed, centrifuge and filter , finally dry to obtain styrene-maleic anhydride copolymer powder;
[0052] Wherein, described initiator is organic peroxide; Described solvent is organic acid alkyl ester; The consumption relation of styrene and maleic anhydride, by molar ratio is 5:5, monomer styrene and The sum of the mass concentrations of maleic anhydride is 55%; the quality of initiator in the reaction system is 5% of the monomer gross mass;
[0053] (2) Preparation of styrene-maleic anhydride copolymer solution
[0054] Add 3 parts of styrene-maleic anhydride copolymer powder and 17 parts of deionized water into the four-necked bottle in parts by weight, heat up to ...
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