Preparation method of multifunctional carbon nanotube composite yarn
A carbon nanotube composite and carbon nanotube technology, which is applied in textiles, papermaking, fiber processing, etc. problem, to achieve the effect of low cost, realization of industrialization, and simple and easy method.
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Embodiment 1
[0027] Preparation of carbon nanotube polyvinyl alcohol composite yarn
[0028] (1) Choose a carbon nanotube yarn (Suzhou Jiedi Nano Material Co., Ltd.) with a diameter of 60 microns and a length of 10 to 20 centimeters, and soak it in 100 milliliters of 37% hydrochloric acid for 1.5 hours to remove Impurities such as Fe contained in carbon nanotubes;
[0029] (2) prepare the mixed solution of the hydrogen peroxide solution of mass percentage concentration 10%, the polyvinyl alcohol solution (Japan Kuraray Co., Ltd., brand PVA205), ethanol solution of mass percentage concentration 5%; Three weights are 100 grams.
[0030] (3) Put the carbon nanotube yarn in step (1) into the solution prepared in step (2), and place it at 40 degrees Celsius for 24 hours to realize the loose structure and resin infiltration of the carbon nanotube yarn;
[0031] (4) Take out the carbon nanotube yarn in step (3) and put it into an oven, adjust the temperature to 60 degrees Celsius, and dry and so...
Embodiment 2
[0035] Preparation of Carbon Nanotube Acrylic Composite Yarns
[0036] (1) Choose a carbon nanotube yarn (Suzhou Jiedi Nano Material Co., Ltd.) with a diameter of 60 microns and a length of 10 to 20 centimeters, and soak it in 100 milliliters of 37% hydrochloric acid for 1.5 hours to remove Impurities such as Fe contained in carbon nanotubes;
[0037] (2) Prepare 400 ml of water-soluble acrylic resin (Jinan Weizhen Chemical Co., Ltd.), and mix it with 200 ml of dichloromethane solution.
[0038] (3) Prepare a mixed solution of 10% by weight of dilute nitric acid solution and sodium sulfite, and mix it with the acrylic resin / dichloromethane solution in step (2).
[0039] (4) Put the carbon tube yarn in the step (1) into the mixed solution in the step (3), and soak for 12 hours in an environment with a temperature of 30 degrees Celsius.
[0040] (5) Take out the carbon tube composite yarn in step (1), put it into an oven, adjust the temperature to 70 degrees Celsius, dry and s...
Embodiment 3
[0043] Preparation of carbon nanotube / graphene / epoxy resin composite yarn
[0044] (1) Choose a carbon nanotube yarn (Suzhou Jiedi Nano Material Co., Ltd.) with a diameter of 60 microns and a length of 10 to 20 centimeters, and soak it in 100 milliliters of 37% hydrochloric acid for 1.5 hours to remove Impurities such as Fe contained in carbon nanotubes;
[0045] (2) Make epoxy resin (Guangzhou Hengyue Chemical Co., Ltd., brand: E-51) and curing agent in a volume ratio of 4:1 to make 400 ml of epoxy resin solution; and mix it with 400 ml of acetone.
[0046] (3) prepare 300 milliliters of concentration and be 70% hydrogen peroxide solution, mix with the epoxy resin / acetone solution prepared in 1 milliliter / mole graphene aqueous solution (New Material Co., Ltd. of Niumeitai) and step (2).
[0047](4) Put the carbon tube yarn in the step (1) into the mixed solution of the step (3), and soak it in an environment of 40 degrees Celsius for 24 hours, so that the polymer resin and g...
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