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Preparation method of multifunctional carbon nanotube composite yarn

A carbon nanotube composite and carbon nanotube technology, which is applied in textiles, papermaking, fiber processing, etc. problem, to achieve the effect of low cost, realization of industrialization, and simple and easy method.

Inactive Publication Date: 2018-05-18
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, due to the small size of pores in carbon nanotube yarns and no active functional groups on the surface, thermoplastic macromolecular resins can hardly enter the interior, which limits the fabrication and application of carbon nanotube aggregate composites.
Such as patent CN101462391 A and patent No. CN 104371129 A in the manufacture method of the carbon nanotube composite material, the resin used is exactly thermosetting small molecular epoxy resin, and just can't be immersed in macromolecular resin, and this has just limited carbon nanotube composite material. Development of Nanotube Composite Materials

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Preparation of carbon nanotube polyvinyl alcohol composite yarn

[0028] (1) Choose a carbon nanotube yarn (Suzhou Jiedi Nano Material Co., Ltd.) with a diameter of 60 microns and a length of 10 to 20 centimeters, and soak it in 100 milliliters of 37% hydrochloric acid for 1.5 hours to remove Impurities such as Fe contained in carbon nanotubes;

[0029] (2) prepare the mixed solution of the hydrogen peroxide solution of mass percentage concentration 10%, the polyvinyl alcohol solution (Japan Kuraray Co., Ltd., brand PVA205), ethanol solution of mass percentage concentration 5%; Three weights are 100 grams.

[0030] (3) Put the carbon nanotube yarn in step (1) into the solution prepared in step (2), and place it at 40 degrees Celsius for 24 hours to realize the loose structure and resin infiltration of the carbon nanotube yarn;

[0031] (4) Take out the carbon nanotube yarn in step (3) and put it into an oven, adjust the temperature to 60 degrees Celsius, and dry and so...

Embodiment 2

[0035] Preparation of Carbon Nanotube Acrylic Composite Yarns

[0036] (1) Choose a carbon nanotube yarn (Suzhou Jiedi Nano Material Co., Ltd.) with a diameter of 60 microns and a length of 10 to 20 centimeters, and soak it in 100 milliliters of 37% hydrochloric acid for 1.5 hours to remove Impurities such as Fe contained in carbon nanotubes;

[0037] (2) Prepare 400 ml of water-soluble acrylic resin (Jinan Weizhen Chemical Co., Ltd.), and mix it with 200 ml of dichloromethane solution.

[0038] (3) Prepare a mixed solution of 10% by weight of dilute nitric acid solution and sodium sulfite, and mix it with the acrylic resin / dichloromethane solution in step (2).

[0039] (4) Put the carbon tube yarn in the step (1) into the mixed solution in the step (3), and soak for 12 hours in an environment with a temperature of 30 degrees Celsius.

[0040] (5) Take out the carbon tube composite yarn in step (1), put it into an oven, adjust the temperature to 70 degrees Celsius, dry and s...

Embodiment 3

[0043] Preparation of carbon nanotube / graphene / epoxy resin composite yarn

[0044] (1) Choose a carbon nanotube yarn (Suzhou Jiedi Nano Material Co., Ltd.) with a diameter of 60 microns and a length of 10 to 20 centimeters, and soak it in 100 milliliters of 37% hydrochloric acid for 1.5 hours to remove Impurities such as Fe contained in carbon nanotubes;

[0045] (2) Make epoxy resin (Guangzhou Hengyue Chemical Co., Ltd., brand: E-51) and curing agent in a volume ratio of 4:1 to make 400 ml of epoxy resin solution; and mix it with 400 ml of acetone.

[0046] (3) prepare 300 milliliters of concentration and be 70% hydrogen peroxide solution, mix with the epoxy resin / acetone solution prepared in 1 milliliter / mole graphene aqueous solution (New Material Co., Ltd. of Niumeitai) and step (2).

[0047](4) Put the carbon tube yarn in the step (1) into the mixed solution of the step (3), and soak it in an environment of 40 degrees Celsius for 24 hours, so that the polymer resin and g...

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Abstract

The invention provides a preparation method of a multifunctional carbon nanotube composite yarn. The method comprises the following steps: firstly, the carbon nanotube yarn is added to a mixed solution of a bulking agent, a compatilizer and a resin matrix, and the mixed solution is left to stand; the bulking agent in the mixed solution can be decomposed to generate micro bubbles when permeating into the inside of the carbon nanotube yarn, and micro blasting effect is produced, so that the structure of the carbon nanotube yarn is gradually loosened, and an impurity removal effect is achieved; resin matrix molecules or nanoparticles enter the yarn, and initial carbon nanotube composite yarn is formed; the initial carbon nanotube composite yarn is heated and dried and is compact in structureand cured by core suction force generated in the evaporation process of the mixed solution, and the multifunctional carbon nanotube composite yarn is prepared. The method is simple and easy to implement and low in cost, and industrialization can be achieved; the prepared composite yarn has important applications in the fields of intelligent yarn, linear electrodes, intelligent fabrics and the like.

Description

technical field [0001] The invention relates to a preparation method of multifunctional carbon nanotube composite yarn. Background technique [0002] Carbon nanotubes are one-dimensional quantum materials with a special carbon six-membered ring structure. The radial dimension is on the order of nanometers, and the axial dimension is on the order of micrometers. It has excellent mechanical, electrical and thermal properties. With the development of nanotechnology, carbon nanotubes can be directly prepared into yarns by chemical vapor deposition and other means. Carbon nanotube yarns inherit the excellent properties of carbon nanotubes. Carbon nanotube yarns can be woven or composed of engineering and application materials of various structures, and have very broad application prospects. [0003] However, due to the small size of pores in carbon nanotube yarns and no active functional groups on the surface, thermoplastic macromolecular resins can hardly enter the interior, w...

Claims

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Application Information

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IPC IPC(8): D06M11/50D06M15/333D06M15/263D06M11/64D06M11/54D06M15/55D06M11/74
CPCD06M11/50D06M11/54D06M11/64D06M11/74D06M15/263D06M15/333D06M15/55
Inventor 许福军徐思悦李维高扬应芷欣王志勇吴建花
Owner DONGHUA UNIV
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