Transparent conductive film, optoelectronic device and manufacturing method thereof

Abstract

The invention provides a transparent conductive film, a photoelectric device and a method for preparing the transparent conductive film. The transparent conductive film includes: a target structure; asilver nanowire film layer on the surface of a target structure; a transparent conductive polymer filling layer filling voids inside the silver nanowire film layer and covering the silver nanowire film layer. The transparent conductive film has high electrical conductivity and high transmittance. The transparent conductive polymer filling layer can uniformly coats the silver nanowire film layer by subjecting the silver nanowire film layer to a hydrophilic treatment. By means of the covering of the transparent conductive polymer filling layer and a graphene film, surface roughness is reduced while high transmittance and high conductivity of the transparent conductive film are guaranteed. In addition, the transparent conductive film also has a flexible property. Bent a plurality of times, the transparent conductive film prepared on a flexible substrate has no significant change in transmittance and square resistance, and shows great potential to be applied to photoelectric devices, especially flexible photoelectric devices instead of ITO.

Description

technical field [0001] The invention belongs to the technical field of material preparation, and in particular relates to a transparent conductive film, a photoelectric device and a manufacturing method thereof. Background technique [0002] OLED (Organic Light-Emitting Diode), that is, organic electroluminescent devices, has the advantages of high luminous efficiency, fast response speed, and low driving voltage, and is one of the hot research directions in the field of optoelectronic devices. In recent years, through the continuous exploration of new materials and the continuous optimization of the device manufacturing process, OLED has made great progress, but to give full play to its advantages in the field of flat panel display, OLED device stability, cost control, flexibility, etc. Still needs further improvement. Among them, the surface work function, photoelectric characteristics, surface flatness, chemical stability and compatibility with organic layers of its tran...

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Problems solved by technology

[0007] In view of the shortcomings of the prior art described above, the purpose of the present invention is to provide a transparent conductive film, a photoelectric device and a manufacturing method thereof, which are used to solve the problem of the high cost of the transparent conductive material ITO in the prior art, lack of flexibility, and the indium element. Diffusion affects the life of the device, and the flatness of the film surface of the silver nanowire film layer and its composite film applied to the OLED device is not good, which leads to problems such as low performance of the OLED device, complicated preparation process, high cost and difficulty in practical application.

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