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Polypropylene non-woven fabric modified with chitosan-metal complex and preparation method thereof

A technology of polypropylene non-woven fabrics and metal complexes, used in textiles and papermaking, biochemical fiber treatment, fiber treatment, etc.

Pending Publication Date: 2017-12-08
苏州市苏真床垫有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, large-area chitosan non-woven fabrics are rarely reported.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A chitosan-metal complex modified polypropylene nonwoven fabric, in parts by weight, said nonwoven fabric comprising: 35 parts of polypropylene nonwoven fabric, 20 parts of chitosan, 11 parts of hydrochloric acid, hydrogen carbonate 8 parts of sodium, 2 parts of sodium hydrogen acetate, 7 parts of absolute ethanol, 12 parts of aluminum chloride, 13 parts of ferric chloride, 11 parts of zinc chloride, 13 parts of sodium styrene sulfonate, N-vinyl-2-pyrrolidone 4 parts, 4 parts acrylamide, 1 part acrylic acid.

[0026] A preparation method of polypropylene non-woven fabric modified by chitosan-metal complex, comprising the following steps:

[0027] (1) Cut the polypropylene non-woven fabric into a 10cm×10cm sample, wash it with absolute ethanol, dry it at 25°C, roll it into a cylinder around the glass rod, and tie it up;

[0028] (2) Dissolve sodium styrene sulfonate, N-vinyl-2-pyrrolidone, and acrylamide in deionized water at 20°C, add acrylic acid dropwise to it, mix w...

Embodiment 2

[0034] A chitosan-metal complex modified polypropylene non-woven fabric, in parts by weight, the non-woven fabric comprises: 48 parts of polypropylene non-woven fabric, 32 parts of chitosan, 16 parts of hydrochloric acid, bicarbonate 17 parts of sodium, 8 parts of sodium hydrogen acetate, 15 parts of absolute ethanol, 18 parts of aluminum chloride, 19 parts of ferric chloride, 18 parts of zinc chloride, 18 parts of sodium styrene sulfonate, N-vinyl-2-pyrrolidone 8 parts, 9 parts acrylamide, 6 parts acrylic acid.

[0035] A preparation method of polypropylene non-woven fabric modified by chitosan-metal complex, comprising the following steps:

[0036] (1) Cut the polypropylene non-woven fabric into a 10cm×10cm sample, wash it with absolute ethanol, dry it at 32°C, wrap it around a glass rod into a cylindrical shape, and tie it up;

[0037] (2) Dissolve sodium styrene sulfonate, N-vinyl-2-pyrrolidone, and acrylamide in deionized water at 24°C, add acrylic acid dropwise to it, m...

Embodiment 3

[0043] A chitosan-metal complex modified polypropylene nonwoven fabric, in parts by weight, said nonwoven fabric comprising: 55 parts of polypropylene nonwoven fabric, 35 parts of chitosan, 19 parts of hydrochloric acid, hydrogen carbonate 22 parts of sodium, 11 parts of sodium hydrogen acetate, 18 parts of absolute ethanol, 23 parts of aluminum chloride, 25 parts of ferric chloride, 23 parts of zinc chloride, 21 parts of sodium styrene sulfonate, N-vinyl-2-pyrrolidone 11 parts, acrylamide 12 parts, acrylic acid 8 parts.

[0044] A preparation method of polypropylene non-woven fabric modified by chitosan-metal complex, comprising the following steps:

[0045] (1) Cut the polypropylene non-woven fabric into a 10cm×10cm sample, wash it with absolute ethanol, dry it at 35°C, roll it into a cylinder around the glass rod, and tie it up;

[0046] (2) Dissolve sodium styrene sulfonate, N-vinyl-2-pyrrolidone, and acrylamide in deionized water at 28°C, add acrylic acid dropwise to it,...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses a polypropylene non-woven fabric modified with chitosan-metal complex and a preparation method thereof. The non-woven fabric comprises the following components in parts by weight: 35-55 parts of polypropylene non-woven fabric, 20-35 parts of chitosan, 11-19 parts of hydrochloric acid, 8-22 parts of sodium bicarbonate, 2-11 parts of sodium hydro-acetate, 7-18 parts of absolute ethyl alcohol, 12-23 parts of aluminum chloride, 12-23 parts of aluminum chloride, 13-25 parts of ferric chloride, 11-23 parts of zinc chloride, 13-21 parts of sodium p-styrenesulfonate, 4-11 parts of N-vinyl-2-pyrrolidone, 4-12 parts of acrylamide and 1-8 parts of acrylic acid. The polypropylene non-woven fabric modified with chitosan-metal complex disclosed by the invention is capable of effectively absorbing wastewater; the polypropylene non-woven fabric modified with chitosan-metal complex disclosed by the invention has a certain antibacterial function; and the polypropylene non-woven fabric modified with chitosan-metal complex disclosed by the invention is reusable.

Description

technical field [0001] The invention belongs to the field of material chemistry, and relates to a functional nonwoven fabric material, in particular to a chitosan-metal complex modified polypropylene nonwoven fabric and a preparation method thereof. Background technique [0002] Chitosan molecules contain a large number of intramolecular and intermolecular hydrogen bonds, so they are insoluble in water and alkaline solutions at normal temperature and pressure, soluble in inorganic acids such as dilute hydrochloric acid and nitric acid and most organic acids, and insoluble in dilute sulfuric acid and phosphoric acid. Chitosan molecules have a complex double-helix structure, and the molecular chain segments contain a large number of active amino groups, hydroxyl groups, and N-acetyl groups. At the same time, the active structure of its polymer chains also makes it highly efficient. On the one hand, they will form Various intramolecular and intermolecular hydrogen bonds, on the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M14/28D06M15/03C08B37/08D06M101/20
CPCD06M14/28C08B37/003D06M15/03D06M16/00D06M2101/20
Inventor 张俊武姚仟锋
Owner 苏州市苏真床垫有限公司
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