Perylene bay 1,7-bit nitro-containing perylene bisimide derivative and application of perylene bisimide derivative in ammonia gas detection
A technology of perylene imide and derivatives, applied in the field of organic synthesis, can solve the problems of limited application, efficient and fast detection of unfavorable gases, poor selectivity of gas sensors, etc.
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[0030] (1) Preparation of perylene 1,7-perylene imide derivatives containing nitro group (PDI2N)
[0031] 2.2 g S -(+)-2,6-Dimethyl-8-bromo-2-octene was dissolved in 20 mL ethanol dispersion of palladium carbon (disperse 0.05~0.1g palladium carbon in 20 mL ethanol), and passed through Hydrogen, reacted at room temperature for 24 h, and removed ethanol by rotary evaporation to obtain S -(+)-3,6-Dimethyl-1-bromo-octane (2 g, 9.67 mmol); then S -(+)-3,6-Dimethyl-1-bromo-octane dissolved in 45 mL and dried N, N’ - Add phthalimide potassium salt (1.79 g, 9.67 mmol) to dimethylformamide (DMF), react at 90 °C for 16 h, cool to room temperature, add 150 mL of water, stir, and extract 3 times with chloroform (100 mL chloroform each time), combined organic phases, MgSO 4 dried, evaporated N -( S -(+)-3,6-Dimethyl-1-octyl)-phthalimide (2.72 g, 98 %); N -( S-(+)-3,6-Dimethyl-1-octyl)-phthalimide was mixed with 4 mL of hydrazine hydrate (80 %) and 100 mL of methanol, stirred at 95...
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