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Preparation method of low-temperature plasma modified Mo-TiO2 photocatalyst

A low-temperature plasma and photocatalyst technology, which is applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, separation methods, etc., can solve problems such as poor stability, deactivation, and low catalytic activity. Achieve the effects of promoting separation, narrow band gap, and high specific surface area

Inactive Publication Date: 2017-06-09
YANCHENG INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Preparation of ion-doped TiO by traditional sol-gel method 2 In the process of catalyst, when ions are introduced, impurities will also be introduced to attach to the surface and gaps of the crystal lattice of the catalyst, thereby generating a certain amount of defects and becoming recombination centers, resulting in TiO 2 Photocatalytic materials show some shortcomings in catalytic reactions, such as low catalytic activity, deactivation, poor stability, etc.

Method used

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  • Preparation method of low-temperature plasma modified Mo-TiO2 photocatalyst
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  • Preparation method of low-temperature plasma modified Mo-TiO2 photocatalyst

Examples

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Embodiment 1

[0028] The invention prepares Mo-TiO modified by low-temperature plasma 2 The method of photocatalytic material comprises the following steps:

[0029] (1) Add 10mL tetrabutyl titanate and 2mL triethanolamine to 50mL isopropanol to prepare a mixed solution, add 2g cetyl ammonium bromide (CTAB) and 3g glucose, stir at room temperature for 30min until the mixture is uniform , to obtain solution I;

[0030](2) Add 0.1g of ammonium molybdate and 1.5mL of deionized water into 25mL of isopropanol, adjust the pH value to 4-6 with 65%wt concentrated nitric acid, stir well to make it evenly mixed, and obtain solution II;

[0031] (3) Add solution II obtained in step (2) dropwise to solution I obtained in step (1) at a rate of 30-50 drops / min with a separatory funnel under vigorous stirring to make tetrabutyl titanate Slowly hydrolyze, continue to stir for 1 hour after the dropwise addition to obtain light yellow uniform and transparent TiO 2 Sol, then aged at room temperature for 24...

Embodiment 2

[0077] The invention prepares Mo-TiO modified by low-temperature plasma 2 The method of photocatalytic material comprises the following steps:

[0078](1) Add 10mL of isopropyl titanate and 5mL of acetylacetone to 100mL of absolute ethanol to prepare a mixed solution, add 1g of CTAB and 5g of glucose, and stir at room temperature for 30min until uniformly mixed to obtain solution I;

[0079] (2) Add 0.05g of ammonium molybdate and 2mL of deionized water into 50mL of isopropanol, adjust the pH value to 4-6 with 65%wt concentrated nitric acid, stir well to make it evenly mixed, and obtain solution II;

[0080] (3) Add solution II obtained in step (2) dropwise to solution I obtained in step (1) at a rate of 30-50 drops / min with a separating funnel under vigorous stirring to make isopropyl titanate Slowly hydrolyze, continue to stir for 1 hour after the dropwise addition to obtain light yellow uniform and transparent TiO 2 Sol, then aged at room temperature for 24h to make it ge...

Embodiment 3

[0085] The invention prepares Mo-TiO modified by low-temperature plasma 2 The method of photocatalytic material comprises the following steps:

[0086] (1) Add 10mL of titanium chloride and 3mL of acetylacetone to 60mL of absolute ethanol to prepare a mixed solution, add 2g of amphiphilic triblock copolymer and 3g of glucose, stir at room temperature for 30min until the mixture is uniform, and obtain solution Ⅰ ;

[0087] (2) Add 0.5g of ammonium molybdate and 1mL of deionized water into 30mL of isopropanol, adjust the pH value to 4-6 with 65%wt concentrated nitric acid, stir well to make it evenly mixed, and obtain solution II;

[0088] (3) Add solution II obtained in step (2) dropwise to solution I obtained in step (1) at a rate of 30-50 drops / min with a separatory funnel under vigorous stirring to slowly hydrolyze titanium chloride , continue to stir for 1h after the dropwise addition to obtain light yellow uniform and transparent TiO 2 Sol, then aged at room temperature...

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Abstract

The invention discloses a preparation method of a low-temperature plasma modified Mo-TiO2 photocatalyst. The preparation method includes: mixing a titanium source and an inhibitor with an organic solvent and adding glucose and a template agent to obtain a first solution; adding ammonium molybdate and deionized water into the organic solvent to obtain a second solution; dropwise adding the second solution to the first solution, stirring to obtain TiO2 sol, and performing ageing to obtain gel; drying and grinding the gel to obtain Mo-TiO2 after calcination; performing low-temperature plasma treatment. The preparation method has the advantages that the low-temperature plasma modified Mo-TiO2 photocatalyst is high in specific surface area and porosity, energy gap is narrower as compared with Mo-TiO2 and TiO2, good visible-light absorption is achieved, absorption capacity on the photocatalyst is effectively expanded, and volatile organic compounds can be excellently catalyzed and degraded under visible light.

Description

technical field [0001] The invention belongs to the field of photocatalysts, in particular to a low-temperature plasma modified Mo-TiO 2 Preparation method of photocatalyst. Background technique [0002] In recent years, with the rapid development of the world's industrial level, my country's industrial development has also entered a high-speed period. However, due to insufficient understanding of industrial development, the early industry emphasized rapid development, and did not take into account other factors, such as environmental pollution in the later period. Wait. As a result, our current environment is getting worse and worse. Therefore, the protection of the environment is extremely important at present. In recent years, smog has appeared in major cities, and it has shown a growing trend, revealing that the atmospheric environment is getting worse and worse. This is a serious warning from nature to us. Among them, the main cause of air pollution is volatile organ...

Claims

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Application Information

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IPC IPC(8): B01J23/28B01J35/10B01D53/86B01D53/72
CPCB01D53/8668B01J23/28B01D2257/708B01J35/60B01J35/61B01J35/39
Inventor 许琦潘帅乔旭崔咪芬曹昊苏
Owner YANCHENG INST OF TECH
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