Special heat-resisting and flame-retarding epoxy resin adhesive for stone material

An epoxy resin and adhesive technology, applied in the direction of epoxy resin glue, adhesive type, polymer adhesive additives, etc., can solve the problems of short storage time, easy combustion, poor impact toughness of cured products, etc.

Inactive Publication Date: 2017-05-31
安徽艾蒂贝生物股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although epoxy resin materials are widely used, there are many shortcomings when used as epoxy resin adhesives, such as short storage time, poor impact tough...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A special heat-resistant and flame-retardant epoxy resin adhesive for stone proposed by the present invention, its raw materials include: 85 parts of modified epoxy resin, 5 parts of polyamic acid, poly 2,6-dimethyl-1 , 15 parts of 4-phenylene ether, 5 parts of acrylonitrile-styrene-acrylate copolymer, 20 parts of polyethersulfone, 2 parts of hydroxyl-terminated liquid nitrile rubber, 12 parts of dicyandiamide, 3 parts of benzoxazine, linear 10 parts of phenolic resin, 1 part of liquid methyl tetrahydrophthalic anhydride, 5 parts of curing accelerator, 2 parts of nano-aluminum hydroxide, 5 parts of silicon micropowder, 5 parts of ferric oxide, 8 parts of nano-titanium dioxide, and 2 parts of hexagonal boron nitride .

Embodiment 2

[0017] A special heat-resistant and flame-retardant epoxy resin adhesive for stone proposed by the present invention, its raw materials include: 70 parts of modified epoxy resin, 20 parts of polyamic acid, poly 2,6-dimethyl-1 , 3 parts of 4-phenylene ether, 12 parts of acrylonitrile-styrene-acrylate copolymer, 5 parts of polyethersulfone, 10 parts of hydroxyl-terminated liquid nitrile rubber, 2 parts of dicyandiamide, 12 parts of benzoxazine, linear 2 parts of phenolic resin, 5 parts of liquid methyl tetrahydrophthalic anhydride, 1 part of curing accelerator, 10 parts of nano-aluminum hydroxide, 2 parts of silicon micropowder, 15 parts of ferric oxide, 2 parts of nano-titanium dioxide, and 11 parts of hexagonal boron nitride .

Embodiment 3

[0019] A special heat-resistant and flame-retardant epoxy resin adhesive for stone proposed by the present invention, its raw materials include by weight: 82 parts of modified epoxy resin, 8 parts of polyamic acid, poly 2,6-dimethyl-1 , 11 parts of 4-phenylene ether, 7 parts of acrylonitrile-styrene-acrylate copolymer, 16 parts of polyethersulfone, 4.8 parts of hydroxyl-terminated liquid nitrile rubber, 10 parts of dicyandiamide, 6 parts of benzoxazine, linear 7 parts of phenolic resin, 3.2 parts of liquid methyl tetrahydrophthalic anhydride, 4 parts of curing accelerator, 4 parts of nano-aluminum hydroxide, 4.3 parts of silicon micropowder, 7 parts of ferric oxide, 7 parts of nano-titanium dioxide, and 4 parts of hexagonal boron nitride ;

[0020] Wherein, the modified epoxy resin is prepared according to the following process: heat 100 parts of epoxy resin to 55°C in parts by weight, then add 5 parts of tetraethyl orthosilicate and 0.05 part of catalyst, heat to 120°C and th...

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PUM

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Abstract

The invention discloses a special heat-resisting and flame-retarding epoxy resin adhesive for a stone material. The special heat-resisting and flame-retarding epoxy resin adhesive is prepared from the following raw materials in parts by weight: 70 to 85 parts of modified epoxy resin, 5 to 20 parts of polyamide acid, 3 to 15 parts of 2,6-dimethyl-1,4-phenylate, 5 to 12 parts of an acrylonitrile-styrene-acrylate copolymer, 5 to 20 parts of polyethersulfone, 2 to 10 parts of hydroxyl-terminated liquid nitrile butadiene rubber, 2 to 12 parts of dicyandiamide, 3 to 12 parts of benzoxazine, 2 to 10 parts of linear phenol-formaldehyde resin, 1 to 5 parts of liquid methyl tetrahydrophthalic anhydride, 1 to 5 parts of a curing accelerant, 2 to 10 parts of nano aluminum hydroxide, 2 to 5 parts of silicon micro-powder, 5 to 15 parts of ferroferric oxide, 2 to 8 parts of nano titanium dioxide and 2 to 11 parts of hexagonal boron nitride. The special heat-resisting and flame-retarding epoxy resin adhesive for the stone material, provided by the invention, has long storage time, high binding performance on a cured material, good impacting toughness, excellent anti-stripping effect and excellent heat-resisting performance and flame-retarding performance.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a special heat-resistant and flame-retardant epoxy resin adhesive for stone. Background technique [0002] At present, with the progress of society, people have higher and higher requirements for building decoration, and various natural stone materials and various exquisitely crafted ceramic finishes emerge in an endless stream. People commonly use stone materials such as marble, granite, and ceramic finishes such as ceramic tiles, glazed tiles, mosaics, etc., and the adhesives for pasting these decorative fabrics are mainly cement mortar. The cost is higher, and the separation is serious, and the construction is very inconvenient, especially the sticking of the top plate is very difficult, labor-intensive and time-consuming. [0003] Due to its good mechanical properties, electrical properties and chemical corrosion resistance, epoxy resin is widely used in surface coatings, ...

Claims

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Application Information

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IPC IPC(8): C09J163/00C09J11/04C09J11/06C09J11/08C08G59/14
CPCC09J163/00C08G59/1438C08G59/1488C08G59/1494C08L2201/02C08L2201/22C08L2205/035C09J11/04C09J11/06C09J11/08C08L79/08C08L25/14C08L81/06C08L15/00C08K13/02C08K5/31C08K5/357C08K2003/2227C08K3/36C08K2003/2275C08K2003/2241C08K2003/385
Inventor 杨立新
Owner 安徽艾蒂贝生物股份有限公司
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