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High-gloss and waterproof photographic paper and preparation method thereof

A high-gloss, photographic paper technology, used in copying/marking methods, papermaking, paper coatings, etc., can solve the problem of poor air permeability surface gloss and scratch resistance, easy scratches on the surface, affecting the appearance of printed colors and problems such as storage, to achieve the effect of improving the ink absorption drying rate and printing resolution, improving the overall water resistance and storage performance, and improving the surface gloss and scratch resistance.

Inactive Publication Date: 2017-04-05
JIANGSU GEMEIGAO DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Coated paper photo paper has the advantages of good water resistance, high flatness, complete hydrophobicity on the back of the paper, vivid and bright output colors, and is suitable for long-term storage. However, its surface gloss is relatively low, the printing drying speed is slow, and the surface is prone to scratches And leave fingerprints, which will affect the printing color display and preservation
[0005] Cast-coated photo paper has high gloss, fast printing and drying speed, high surface hardness, and vivid and bright colors. However, because it uses paper as the base material, it has relatively poor water resistance and is easy to curl, which affects long-term storage applications.
[0006] The patent application number is: 201210186881.1, and the patent name is: nano-scale high-gloss cast-coated paper for printing. The nano-scale high-gloss cast-coated paper for printing provided by this patent can be obtained by one-time drying without super calendering, but Its air permeability, surface gloss and scratch resistance of the product are not good
[0007] The patent application number is: 201210187158.5, and the patent name is: New environmentally friendly high-gloss cast-coated paper made of recycled paper. This patent uses recycled paper as the cast-coated base paper to obtain high-gloss and easy-to-peel cast-coated paper, which is energy-saving and environmentally friendly. Lower ink blotting drying rate and print resolution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment 1

[0061] A high-gloss, water-resistant photographic paper consisting of an ink-receptive layer, a gloss layer, a base paper and a backcoat. The base paper is cast-coated base paper with a weight range of 60 grams per square meter.

[0062] The ink-absorbing layer coating solution is composed of the following components in parts by weight:

[0063] 50 parts of water;

[0064] 3 parts of color fixing agent;

[0065] 0.1 part of defoamer;

[0066] Brightener 0.1 part;

[0067] 5 parts of polyvinyl alcohol solution (15%);

[0068] Microporous silica 12 parts;

[0069]10 parts of polymer emulsion.

[0070] In the ink-absorbing layer coating solution formula:

[0071] The color fixing agent is a quaternary ammonium salt formaldehyde-free color fixing agent.

[0072] The defoamer is a polyether defoamer.

[0073] The whitening agent is a stilbene derivative, which is a sodium disulfonic acid salt.

[0074] The polyvinyl alcohol solution (15%) is polyvinyl alcohol 1799.

[00...

specific Embodiment 2

[0110] A high-gloss, water-resistant photographic paper consisting of an ink-receptive layer, a gloss layer, a base paper and a backcoat. The base paper is cast-coated base paper with a weight range of 260 grams per square meter.

[0111] The ink-absorbing layer coating solution is composed of the following components in parts by weight:

[0112] 70 parts of water;

[0113] Fixing agent 7 parts;

[0114] 0.5 part of defoamer;

[0115] 0.5 parts of whitening agent;

[0116] 10 parts of polyvinyl alcohol solution (15%);

[0117] Microporous silica 18 parts;

[0118] 15 parts of polymer emulsion.

[0119] In the ink-absorbing layer coating solution formula:

[0120] The color fixing agent is a quaternized reactive color fixing agent.

[0121] The defoamer is tributyl phosphate.

[0122] The whitening agent is a stilbene derivative, which is sodium tetrasulfonate.

[0123] The polyvinyl alcohol solution (15%) is polyvinyl alcohol 1788.

[0124] The particle size of the ...

specific Embodiment 3

[0159] A high-gloss, water-resistant photographic paper consisting of an ink-receptive layer, a gloss layer, a base paper and a backcoat. The base paper is cast-coated base paper with a weight range of 160 grams per square meter.

[0160] The ink-absorbing layer coating solution is composed of the following components in parts by weight:

[0161] 55 parts of water;

[0162] Fixing agent 4 parts;

[0163] 0.3 part of defoamer;

[0164] 0.2 parts of whitening agent;

[0165] 7 parts of polyvinyl alcohol solution (15%);

[0166] Microporous silica 14 parts;

[0167] 12 parts of polymer emulsion.

[0168] In the ink-absorbing layer coating solution formula:

[0169] The color fixing agent is a quaternized high polymer formaldehyde-free color fixing agent.

[0170] The defoamer is polydimethylsiloxane.

[0171] The whitening agent is a stilbene derivative, which is the sodium salt of hexasulfonic acid.

[0172] The polyvinyl alcohol solution (15%) is one of the Japanese Kur...

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Abstract

The invention discloses high-gloss and waterproof photographic paper. The high-gloss and waterproof photographic paper comprises an ink-absorbing layer, a lustering layer, raw paper and a back coating. A preparation method of the high-gloss and waterproof photographic paper comprises a preparation method of ink-absorbing coating liquid, a preparation process of lustering coating liquid, a preparation process of back-coating coating liquid and a preparation process of the high-gloss and waterproof photographic paper. According to the high-gloss photographic paper produced by the method, the glossiness can reach above 80 percent and is far more than that of photographic paper with the glossiness being 40 to 60 percent in the market; meanwhile, the high-gloss photographic paper has scratch resistance and the surface hardness of the photographic paper reaches level 7; the back side is coated with polymer emulsion, so the isolating effect and the anti-curl effect are achieved; and the surface tension of the back side is less than 25 dynes, so water cannot be spread on the surface. The flatness reaches the level of coated paper. The ink-absorbing drying rate is high, the effect that the paper is dry once being discharged out of a machine is achieved, and the drying rate is greatly increased compared with the drying rate, that the coated photographic paper is dry 2 minutes later when being discharged out of the machine, of the coated photographic paper.

Description

technical field [0001] The technical field of the present invention is the technical field of new materials, and the application field is the field of image output, in particular to a high-gloss water-resistant photographic paper and a preparation method thereof. Background technique [0002] In September 2012, my country Lucky Film Group, a giant film manufacturer in China, closed the last color film production line in Nanjing, marking that my country's digital inkjet printing technology has basically replaced the traditional silver salt output technology in the image output industry. [0003] Inkjet printing photo paper is the printing medium material in digital inkjet printing technology, which is made by coating the coating liquid on the surface of the substrate. At present, the types of photo paper on the market mainly include coated paper photo paper and cast-coated photo paper. Among them, the coated paper photo paper is coated with the ink-absorbing coating liquid on...

Claims

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Application Information

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IPC IPC(8): D21H19/82D21H21/16D21H21/14D21H21/32D21H19/20D21H19/14D21H19/12D21H19/40D21H19/60D21H19/58D21H21/12B41M5/52
CPCB41M5/5218B41M5/5254B41M2205/40D21H19/12D21H19/14D21H19/20D21H19/40D21H19/58D21H19/60D21H19/82D21H21/12D21H21/14D21H21/16D21H21/32
Inventor 陆建辉王玉丰
Owner JIANGSU GEMEIGAO DEV CO LTD
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