Processless computer to plate precursor, and ultra-short pulse laser plate making method
An ultra-short pulse laser and treatment-free technology, which is applied in printing plates, chemical instruments and methods, printing, etc., can solve the problems of increased difficulty in plate manufacturing, complex photosensitive system, waste liquid treatment, etc., to reduce production difficulty and cost , High energy, thin beam effect
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Embodiment 1
[0031] A treatment-free lithographic printing plate precursor, consisting of a grained metal substrate and a laser-ablative ink-loving resin layer or a UV-curable resin layer on the metal substrate, the ink-loving resin layer or UV-curable The resin layer is 0.5-5um. The metal substrate is selected from one of pure aluminum plate, aluminum alloy plate, iron plate and galvanized plate with a thickness of 0.1-0.5 mm. The metal substrate is pre-treated by electrolytic oxidation or laser engraving to form an average surface roughness of The grain size of 0.1~0.9um, in order to achieve the water retention performance and friction resistance hardness performance required for printing.
[0032] The ink-loving resin layer is composed of an organic solvent and a mass fraction of 0.1% to 25% organic pigment or dye, 5% to 65% high polymer, 2.0% to 20% adhesive and auxiliary agent dissolved in the organic solvent. agent composition; the UV-curable resin layer is composed of 0.1-25 parts ...
Embodiment 2
[0043] 1.0% acrylic oligomer, 10% epoxy resin, 25% phenolic resin, 0.1% phenylethyl alcohol oleate, 0.15% ethyl violet, 0.8% butyl hydroxyanisole (BHA), 2.0% poly Dissolve and disperse methyl siloxane in 50L ethylene glycol monoethyl ether, heat at 30~50°C to disperse and dissolve the above substances, and configure it into a coating liquid. Coat the prepared coating liquid on a surface with a roughness of 0.5, On an aluminum plate base with a thickness of 0.2mm, dry to obtain a lithographic original plate, and the thickness of the resin layer after drying is 2um.
[0044] The viscosity of the coating solution in the present invention is 2.8 centipoise, the surface tension is 22 dyn / cm, and the solid content is 5.2%.
[0045] The ultra-short pulse laser platesetter uses Ti:Sapphire mode-locked to regenerate and amplify the femtosecond laser beam. The pulse width is 94fs, the repetition frequency is 1kHz, and the center wavelength is 700nm. The beam control system includes bea...
Embodiment 3
[0048] 1.0% sodium carboxymethylcellulose, 15% modified acrylic resin, 30% modified phenolic resin, 0.1% lauryl phenylacetate, 0.18% phthalocyanine, 2.0% octadecylamine acetate, 1.0 % phenylethyl alcohol oleate, 0.8% 2,6-tertiary butyl-4-methylphenol is dispersed and dissolved in 50L ethylene glycol monoethyl ether and methyl ethyl ketone (2:1) solution, heated at 30~50°C to make the above The material is dispersed, dissolved and dispersed, and configured into a coating liquid. The configured coating liquid is coated on an aluminum substrate with a roughness of 0.5 and a thickness of 0.2 mm, and the coating is dried to obtain a lithographic printing plate precursor. After drying, the resin layer The thickness is 5um.
[0049] The viscosity of the coating solution in the present invention is 3.0 centipoise, the surface tension is 24 dyn / cm, and the solid content is 5.5%.
[0050] Use a titanium-sapphire ultra-short pulse laser platesetter, the output laser wavelength is 800nm,...
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