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Automotive antifreeze fluid and preparation method thereof

An automobile antifreeze and polyol technology, applied in the field of antifreeze, can solve the problems of non-compliance with environmental protection requirements, low thermal conductivity of scale, corrosion damage of metal parts, etc. Anti-freeze effect, excellent anti-corrosion protection effect

Active Publication Date: 2017-01-25
中山大桥化工集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] If it is not handled properly, the antifreeze will easily corrode metal parts during use, and the metal parts that have been corroded for a long time will generate a large amount of rust, which will gradually corrode the metal plate and cause leakage, which is directly related to the service life of the car cooling system; At the same time, scale is easy to form. The thermal conductivity of scale is small, which is 1 / 25 of that of cast iron and 1 / 50 of that of brass, which greatly reduces the thermal conductivity of the coolant and seriously reduces the cooling effect; the temperature of the engine increases and the corrosion increases, which further promotes Scale increases, forming a vicious circle; scale may also clog cooling system pipes
[0005] In the prior art, there are many types of antifreeze, which can be divided into alcohol antifreeze, inorganic salt antifreeze, polysaccharide antifreeze and water antifreeze according to the difference of the base fluid. The advantages of anti-corrosion performance, continuous development and application, are now very popular, but there are still problems that long-term use is easy to cause corrosion damage to metal parts. In addition, many existing automotive antifreezes also contain nitrite, amine salts, and phosphates , chromate and other ingredients are harmful to human body and environment, and do not meet environmental protection requirements

Method used

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  • Automotive antifreeze fluid and preparation method thereof
  • Automotive antifreeze fluid and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Put 550kg of ethylene glycol and 429kg of deionized water into a 2000L platform tank, start the agitator and stir for 10 minutes, after mixing evenly, add 1.5kg of acrylic acid-acrylate-sulfonate terpolymer TH-615 under stirring , 3.5kg of polyoxyethylene polyoxypropylene ether block copolymer Pluronic L61, fully stirred until the copolymer is uniformly dispersed, and then 8.4kg of triethylamine, 1kg of benzotriazole, 0.8kg of dibenzothiazole disulfide, 1.2kg sodium hydroxide, 1kg sodium nitrate, 1kg sodium metasilicate, 2.5kg adipic acid, 0.01kg fluorescein sodium, 0.05kg turquoise blue pigment and 0.04kg defoamer BYK-094, fully stir for 1 hour after feeding Packaging, get car antifreeze.

Embodiment 2

[0030] Put 454kg of propylene glycol and 525kg of deionized water into a 2000L platform tank, start the stirrer and stir for 15min, after mixing evenly, add 3kg of acrylic acid-acrylic acid ester-sulfonate terpolymer XT-613, 2kg of poly Oxyethylene polyoxypropylene ether block copolymer Antarox L64, stir well until the copolymer is evenly dispersed, then add 8kg triethanolamine, 1kg benzotriazole, 1kg2-mercaptobenzothiazole, 1.2kg sodium hydroxide, 1kg nitric acid Sodium, 1kg of sodium metasilicate, 2.7kg of sebacic acid, 0.02kg of sodium fluorescein, 0.05kg of turquoise blue and 0.03kg of antifoaming agent BYK-028 were fully stirred for 1.2 hours after feeding and packed to obtain automobile antifreeze.

Embodiment 3

[0032] Put 246kg of ethylene glycol, 254kg of propylene glycol, and 479kg of deionized water into a 2000L platform tank, start the agitator and stir for 20 minutes, after mixing evenly, add 3.8kg of acrylic acid-acrylic acid ester-sulfonate terpolymer under stirring XT-241, 1.2kg polyoxyethylene polyoxypropylene ether block copolymer Tergitol L62, fully stirred until the copolymer is uniformly dispersed, then put in 8kgN,N-dimethylethanolamine, 1kgbenzotriazole, 1kg2-( 2,4-dinitrophenylthio)benzothiazole, 1.2kg sodium hydroxide, 1kg sodium nitrate, 1kg sodium metasilicate, 2.66kg lauric acid, 0.01kg fluorescein sodium, 0.08kg turquoise blue and 0.05 kg defoamer Tego Foamex 810, fully stirred for 1.5 hours after feeding, and packed to obtain automobile antifreeze.

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Abstract

The invention belongs to the technical field of antifreeze fluid and discloses an automotive antifreeze fluid and a preparation method thereof. The automotive antifreeze fluid is prepared from, by mass, 400.0-600.0%o of polyalcohol, 1.0-5.0%o of acrylic acid-acrylate-sulfonate ternary copolymer, 1.0-5.0%o of polyoxyethylene polyoxypropylene segmented copolymer, 5.0-10.0%o of organic amine, 0.5-5.0%o of benzotriazole, 0.5-5.0%o of accelerants, 0.5-5.0%o of sodium hydroxide, 0.5-5.0%o of sodium nitrate, 0.5-5.0%o of sodium metasilicate, 2.0-8.0%o of organic acid, 0.005-0.5%o of sodium fluorescein, 0.005-0.5%o of turquoise blue pigment, 0.005-0.5%o of an anti-foaming agent and the balance deionized water. The automotive antifreeze fluid has advantages of low freezing point, high boiling point, excellent anti-freezing and anti-boiling performances and great corrosion resistance and anti-scaling performances.

Description

technical field [0001] The invention belongs to the technical field of antifreeze, and in particular relates to an automobile antifreeze and a preparation method thereof. Background technique [0002] Antifreeze, also known as antifreeze coolant, is used to prevent the coolant from freezing and bursting the radiator and freezing the engine cylinder when the vehicle is parked in cold winter. Antifreeze is used in the cooling systems of automobiles, trains, diesel locomotives, tractors, ships, engines, water tanks, and various mechanical equipment, diesel engines, and gasoline engines. In the coolant path of the internal combustion engine, there are materials such as aluminum, cast iron, steel, brass, solder, copper, etc., and the antifreeze should be able to effectively inhibit the corrosion of these materials. Therefore, the antifreeze should not only have good cooling performance, but also have the functions of anti-freezing, anti-rust and anti-scaling. [0003] The measu...

Claims

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Application Information

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IPC IPC(8): C09K5/20
CPCC09K5/20
Inventor 何炳槐胡志标
Owner 中山大桥化工集团有限公司
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