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Preparation method of two-dimensional nano electrode material

A two-dimensional nanometer and electrode material technology, which is applied in the direction of nanotechnology, nanotechnology, nanotechnology for materials and surface science, etc., can solve the problems of cumbersome process and low yield, and achieve no precious metal doping and low cost , to prevent the effect of compounding

Active Publication Date: 2016-11-23
UNIV OF JINAN
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, most of the synthesis methods are synthesized separately, and then compound the catalyst and the carrier, the process is cumbersome and the yield is not high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Example 1 Cu-TiO 2 / MoS 2 preparation of

[0023] (1) Add 0.6 g of molybdenum disulfide powder and 0.2 mmol of copper salt to 3 mL of n-butyllithium solution, and stir for 12 hours under nitrogen protection at 60 °C to obtain the reacted solution;

[0024] (2) Wash the reacted solution in step (1) with a non-polar solvent, and then perform ultrasonic treatment in a water bath at 60 °C. After the treatment, wash the treated solution with a non-polar solvent, and dry it in vacuum to obtain copper Intercalated molybdenum disulfide nanomaterials;

[0025] (3) Take 500 mg of copper-intercalated molybdenum disulfide nanomaterials prepared in step (2) and add them to 5 mL of tetrabutyl titanate. After stirring for 1 hour, slowly add 0.5 mL of hydrofluoric acid while stirring, and then Reaction in the reactor at 160°C for 18 hours;

[0026] (4) The reaction product obtained in step (3) was centrifuged and washed three times with ultrapure water and absolute ethanol, and the...

Embodiment 2

[0031] Example 2 Cu-TiO 2 / MoS 2 preparation of

[0032] (1) Add 0.6 g of molybdenum disulfide powder and 1.0 mmol of copper salt to 5 mL of n-butyllithium solution, and stir for 24 hours under nitrogen protection at 30 °C to obtain the reacted solution;

[0033] (2) Use a non-polar solvent to wash the solution after the reaction in step (1), and then perform ultrasonic treatment in a water bath at 30 °C. After the treatment, use a non-polar solvent to wash the treated solution, and dry it in vacuum to obtain copper Intercalated molybdenum disulfide nanomaterials;

[0034] (3) Take 200 mg of copper-intercalated molybdenum disulfide nanomaterials prepared in step (2) and add them to 5 mL of tetrabutyl titanate. After stirring for 1 hour, slowly add 0.6 mL of hydrofluoric acid while stirring, and then Reaction in the reactor at 180°C for 20 hours;

[0035](4) The reaction product obtained in step (3) was centrifuged and washed three times with ultrapure water and absolute et...

Embodiment 3

[0040] Example 3 Cu-TiO 2 / MoS 2 preparation of

[0041] (1) Add 0.6 g of molybdenum disulfide powder and 2.0 mmol of copper salt to 10 mL of n-butyllithium solution, and stir for 48 hours under nitrogen protection at 50 °C to obtain the reacted solution;

[0042] (2) Wash the reacted solution in step (1) with a non-polar solvent, and then perform ultrasonic treatment in a water bath at 50 °C. After the treatment, wash the treated solution with a non-polar solvent, and dry it in vacuum to obtain copper Intercalated molybdenum disulfide nanomaterials;

[0043] (3) Take 10 mg of copper-intercalated molybdenum disulfide nanomaterials prepared in step (2) and add them to 5 mL of tetrabutyl titanate. After stirring for 1 hour, slowly add 0.8 mL of hydrofluoric acid while stirring, and then Reaction in the reactor at 200°C for 24 hours;

[0044] (4) The reaction product obtained in step (3) was centrifuged and washed three times with ultrapure water and absolute ethanol, and the...

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Abstract

The invention discloses a preparation method of a two-dimensional nano electrode material which is free of noble metal doping, low in cost, easy to prepare and high in electrooptic activity, and belongs to the technical field of novel nano functional materials and green energy. The method comprises the steps that a copper doped titanium dioxide nanosheet material is composited in situ on a molybdenum disulfide nanosheet of a copper intercalation layer, and the two-dimensional nano composite material Cu-TiO2 / MoS2 is obtained by in-situ compositing molybdenum disulfide with copper doped titanium dioxide nano blocks through a one-pot method. The prepared Cu-TiO2 / MoS2 can be applied to the fields of solar energy photovoltaic cell preparation, photoelectrochemistry sensor construction, photocatalytic water splitting for hydrogen production, photocatalytic degradation of organic pollutants and the like.

Description

technical field [0001] The invention relates to a method for preparing a two-dimensional nanomaterial. The prepared two-dimensional nanomaterial has photoelectrochemical activity and can be applied to the preparation of solar photovoltaic cells, the construction of photoelectrochemical sensors, photocatalytic water splitting to produce hydrogen, and photocatalytic degradation of organic pollution. things and other fields. The invention belongs to the technical field of novel nano functional materials and green energy. Background technique [0002] Solar cells, also known as "solar chips" or "photovoltaic cells", are photoelectric semiconductor sheets that use sunlight to generate electricity directly. As long as it is illuminated by light that meets certain illumination conditions, it can output voltage instantly and generate current when there is a loop. In physics, it is called solar photovoltaic, or photovoltaic for short. A solar cell is a device that directly convert...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G39/06C01G23/053B82Y30/00H01L31/0224
CPCC01G39/06C01P2004/84C01P2006/40C01P2006/60H01L31/022425Y02E10/50
Inventor 史御书张国庆郑娜张勇
Owner UNIV OF JINAN
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