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Modification-reinforced thermoplastic polyurethane composite material for 3D printing

A thermoplastic polyurethane and 3D printing technology, applied in the direction of additive processing, can solve the problems of limited polymer materials, achieve the best mechanical properties, broaden the application range, and excellent mechanical properties

Inactive Publication Date: 2016-10-12
佛山市高明区诚睿基科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the biggest problem of the selective laser sintering process is that the polymer materials available for sintering are very limited. Therefore, it is urgent to provide a composite material with better performance that can be applied to the selective laser sintering process.

Method used

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  • Modification-reinforced thermoplastic polyurethane composite material for 3D printing

Examples

Experimental program
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Effect test

Embodiment 1

[0024] A thermoplastic polyurethane composite material for 3D printing, which consists of the following raw materials in parts by weight: 100 parts of polyurethane, 8 parts of composite inorganic filler, 0.2 part of light stabilizer, 5 parts of coupling agent, 0.1 part of leveling agent, dispersive lubrication 3 parts of agent and 0.5 part of antioxidant; wherein, the composite inorganic filler is composed of graphene / SiO2 in parts by weight 5:3 2 The composite filler is composed of multi-walled carbon nanotube / calcium carbonate composite filler.

[0025] The preparation method of this composite material comprises the following steps:

[0026] (1) Pretreatment of polyurethane raw materials: pulverize polyurethane raw materials into 300-mesh powder, disperse them in pure water, ultrasonic (power 300W) for 1 hour, and microwave irradiation (2500MHz, temperature controlled at 85°C) for 1 hour while ultrasonic; Stop ultrasonic and microwave irradiation, wash, discharge, and dry t...

Embodiment 2

[0030] Based on Example 1, the difference is that the composite inorganic filler is made of graphene / SiO in parts by weight of 8:3 2 The composite filler is composed of multi-walled carbon nanotube / calcium carbonate composite filler.

Embodiment 3

[0032] Based on Example 1, the difference is that the composite inorganic filler is made of graphene / SiO in parts by weight 5:5 2 The composite filler is composed of multi-walled carbon nanotube / calcium carbonate composite filler.

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Abstract

The invention discloses a thermoplastic polyurethane composite material for modified and enhanced 3D printing, which consists of the following raw materials in parts by weight: 90-100 parts of polyurethane, 5-10 parts of composite inorganic filler, graphene quantum dots and porous graphene, 0.1 to 1 part of light stabilizer, 5 to 10 parts of coupling agent, 0.1 to 2 parts of leveling agent, 1 to 6 parts of dispersed lubricant and 0.1 to 1 part of antioxidant; wherein, the graphene quantum dot accounts for The weight percentage of the polyurethane is 0.5-1%, and the weight percentage of the porous graphene in the polyurethane is 0.5-2%. The prepared thermoplastic polyurethane composite material has good flexibility and excellent mechanical properties, which further broadens the scope of application of 3D printing, such as selective laser sintering technology, fused deposition technology, and photocuring molding that can be used in 3D printing technology Technology or layered entity manufacturing technology; the laser sintering performance of thermoplastic polyurethane is improved by adding composite inorganic fillers, and the scientific ratio is obtained through multiple experiments to achieve better mechanical properties of 3D printed products.

Description

technical field [0001] The invention relates to the field of composite materials, in particular to a thermoplastic polyurethane composite material for 3D printing. Background technique [0002] 3D printing technology, also known as additive manufacturing technology, is actually an emerging technology in the field of rapid prototyping. A technique for constructing objects in a manner. The basic principle is additive manufacturing, the technique of adding material layer by layer to generate a three-dimensional solid. At present, 3D printing technology is mainly used in product prototyping, mold manufacturing, art creation, jewelry making and other fields, replacing these traditional fine processing techniques. In addition, 3D printing technology is gradually applied in fields such as medicine, bioengineering, architecture, clothing, aviation, etc., opening up a broad space for innovation. [0003] 3D printing technologies include stereolithography, layered solid manufacturi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08K13/06C08K9/10C08K3/36C08K3/04C08K3/26C08K7/24C08K9/00B33Y70/00
CPCC08K13/06B33Y70/00C08K3/04C08K3/26C08K3/36C08K7/24C08K9/00C08K9/10C08K2003/265C08K2201/011
Inventor 黎淑娟
Owner 佛山市高明区诚睿基科技有限公司
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