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Quartz sand supported lanthanum titanate photocatalyst and method for preparing same

A technology of photocatalyst and quartz sand, which is applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve problems that have not caused researchers, and achieve the goal of improving capabilities Effect

Inactive Publication Date: 2016-09-21
SHENYANG LIGONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, the research on the immobilization of lanthanide titanate photocatalysts has not attracted the attention of researchers, and there are few reports on the research on supported lanthanum titanate photocatalysts and their preparation methods.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A quartz sand-supported lanthanum titanate photocatalyst, mainly composed of: 6 mL absolute ethanol, 1 mL absolute methanol, 1 mL acetone, 1 mL tetrabutyl titanate, 0.5 mL guiding agent AP-6, 7 mL distilled water , 0.6 g lanthanum acetate, 5 g ammonium acetate, 1 mL glacial acetic acid, 0.5 mL butanediol and 0.3 g quartz sand.

[0023] The particle size of the quartz sand is 0.3 μm.

[0024] A preparation method of quartz sand loaded lanthanum titanate photocatalyst mainly comprises the following steps:

[0025] (1) Precursor preparation:

[0026] Measure 6 mL of absolute ethanol, 1 mL of absolute methanol and 1 mL of acetone into a 100 mL beaker, place the beaker on a magnetic stirrer, add 1 mL of tetrabutyl titanate and 0.5 mL of directing agent AP under full stirring -6, and then continue to stir for 10 min to form a titanium alkoxide solution.

[0027] Take another 100 mL beaker, add 7 mL of distilled water, then add 0.6 g of lanthanum acetate and make it fully d...

Embodiment 2

[0036] A quartz sand-supported lanthanum titanate photocatalyst, mainly composed of: 15 mL absolute ethanol, 5 mL absolute methanol, 6 mL acetone, 3 mL tetrabutyl titanate, 2 mL directing agent AP-6, 15 mL distilled water , 2 g lanthanum acetate, 10 g ammonium acetate, 7 mL glacial acetic acid, 3 mL butanediol and 3 g quartz sand.

[0037] The particle size of the quartz sand is 10 μm.

[0038] A preparation method of quartz sand loaded lanthanum titanate photocatalyst mainly comprises the following steps:

[0039] (1) Precursor preparation:

[0040] Measure 15 mL of absolute ethanol, 5 mL of absolute methanol and 6 mL of acetone into a 100 mL beaker, place the beaker on a magnetic stirrer, add 3 mL of tetrabutyl titanate and 2 mL of directing agent AP under full stirring -6, and then continue to stir for 10 min to form a titanium alkoxide solution.

[0041] Take another 100 mL beaker, add 15 mL of distilled water, then add 2 g of lanthanum acetate and make it fully dissolv...

Embodiment 3

[0050] A quartz sand-supported lanthanum titanate photocatalyst is mainly composed of: 10 mL absolute ethanol, 3 mL absolute methanol, 3 mL acetone, 2 mL tetrabutyl titanate, 1 mL guiding agent AP-6, 10 mL distilled water, 1 g lanthanum acetate, 8 g ammonium acetate, 5 mL glacial acetic acid, 2 mL butanediol and 2 g quartz sand.

[0051] The particle size of the quartz sand is 5 μm.

[0052] A preparation method of quartz sand loaded lanthanum titanate photocatalyst mainly comprises the following steps:

[0053] (1) Precursor preparation:

[0054] Measure 10 mL of absolute ethanol, 3 mL of absolute methanol and 3 mL of acetone into a 100 mL beaker, place the beaker on a magnetic stirrer, add 2 mL of tetrabutyl titanate and 1 mL of directing agent AP under full stirring -6, and then continue to stir for 10 min to form a titanium alkoxide solution.

[0055] Take another 100 mL beaker, add 10 mL of distilled water, then add 1 g of lanthanum acetate and make it fully dissolved,...

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Abstract

The invention discloses a quartz sand supported lanthanum titanate photocatalyst. The quartz sand supported lanthanum titanate photocatalyst mainly comprises absolute ethyl alcohol, absolute methanol, acetone, titanium alkoxide, guiding agents, lanthanum acetate, ammonium acetate, glacial acetic acid, butylene glycol and quartz sand. A method for preparing the quartz sand supported lanthanum titanate photocatalyst includes preparing precursors, to be more specific, adding the titanium alkoxide and the guiding agents into the absolute ethyl alcohol, the absolute methanol and the acetone to obtain titanium alkoxide solution, forming lanthanum acetate solution from distilled water, the lanthanum acetate, the ammonium acetate and the glacial acetic acid, adding the titanium alkoxide solution into the lanthanum acetate solution drop by drop and adding the butylene glycol into the lanthanum acetate solution to obtain final transparent solution; carrying out support and heat treatment, to be more specific, adding the quartz sand into the final transparent solution, arranging beakers in magnetic stirring constant-temperature water bath kettles, stirring the final transparent solution under the condition of the temperature of 50-90 DEG C to obtain light yellow gel, drying the light yellow gel until the light yellow gel is dehydrated, grinding the light yellow gel to obtain powder, arranging the powder in a program-control chamber electric furnace, heating the program-control chamber electric furnace at the room temperature at the heating rate of 2-10 DEG C / min until the temperature of the program-control chamber electric furnace reaches a calcination temperature, keeping the calcination temperature unchanged for 1-10 h, cooling the powder and then grinding the powder to obtain materials. The quartz sand supported lanthanum titanate photocatalyst and the method have the advantage that the pollutant photocatalytic purification capacity of lanthanum titanate can be obviously improved.

Description

Technical field: [0001] The invention relates to the field of environmental purification functional materials, and is a quartz sand-loaded lanthanum titanate photocatalyst and a preparation method thereof. Background technique [0002] In more than 40 years of research, the activity of photocatalysts is the most important factor restricting its industrial application. At the same time, large-scale environmental pollution control must also solve the catalyst recycling technology. Loading the catalyst powder on a carrier with a large specific surface area can solve the problem of catalyst powder recycling and provide the possibility for the practical application of the catalyst. At the same time, the dispersion of photocatalysts on the carrier will weaken self-agglomeration, inhibit grain growth, and improve photocatalytic performance. The choice of carrier is a key factor in the preparation of supported photocatalytic materials. Researchers have used many materials as catal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/10
CPCB01J21/063B01J23/10B01J35/39
Inventor 张文杰
Owner SHENYANG LIGONG UNIV
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