Protective film, separator using same, and secondary battery
A technology of rechargeable battery and protective film, applied in the field of protective film for protecting lithium-containing anodes, can solve the problems such as the specific method for the mobile growth of lithium ions that is not recorded.
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[0107] Hereinafter, the present invention will be described concretely with reference to examples, but the present invention is not limited thereto.
[0108] In this example, various protective films were produced under the conditions shown in Table 1, and coin batteries were produced using these protective films. The total resistance (Ω) of the protective film and the spacer was measured, and a charge-discharge test of a coin cell (Li / Li coin cell cycle) was performed. The charge-discharge test measures the average charge-discharge efficiency and the number of cycles until Li dendrites cause an internal short circuit, and evaluates the lifetime of each coin cell. Hereinafter, it demonstrates in more detail.
[0109] 【Table 1】
[0110]
[0111] As the reinforcement layer (porous polymer membrane) constituting the protective membrane, a PTFE membrane [manufactured by Nippon Gore Co., Ltd.], which is a membrane composed of a tetrafluoroethylene (TFE) polymer or copolymer, wa...
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