Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Solar polyurethane thermal insulation material

A thermal insulation material, polyurethane technology, applied in the field of solar polyurethane thermal insulation materials, can solve the problems of reducing the thermal insulation effect of water tanks, vacuum nozzle foam cracking, foam and shell falling off, etc., to achieve the effect of reducing its own characteristics, increasing strength, and reducing material compression

Inactive Publication Date: 2016-06-22
GUANGXI JISHUN ENERGY TECH
View PDF3 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Vegetable oil is mostly obtained from stable raw materials, so it is a cost-effective polyurethane raw material. The disadvantage is that it lacks the active hydrogen necessary for the reaction with isocyanate, so it needs to be modified.
[0006] During the production process of rigid polyurethane foam, due to various reasons such as its own characteristics, production process and production workers' operating skills, there is a common problem of foam shrinkage, which may easily cause part or all of the foam and the shell to fall off, and eventually cause the shell to deform. The mouth foam cracks, what's more, the hard polyurethane foam between the inner tank and the outer shell cracks horizontally or vertically, which greatly reduces the thermal insulation effect of the water tank

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Solar polyurethane thermal insulation material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] First prepare polyether polyol I, the process is as follows:

[0034] (1) Weigh 80g of lignin, 40g of water, 5g of lignin peroxidase, 1g of catalase, 1g of furfural acetaldehyde and 5g of furfuryl alcohol in a reactor, the reaction temperature is 80°C, and the reaction is stirred for 5 hours to obtain Enzymatic modification of lignin;

[0035] (2) Mix 100g of enzymatically modified lignin, 300g of glycerol, 200g of diethylene glycol and 0.03g of Pd-Fe catalyst in the reactor, control the reaction temperature at 120°C, and bubble the reaction with nitrogen from the bottom of the reactor , and then vacuumized, 8 g of propylene oxide was added, and the reaction was sealed under normal pressure for 2 hours to obtain the polyether polyol I with a functionality of 4.6 and a hydroxyl value of 400 mgKOH / g.

[0036] Then prepare polyether polyol II, the process is as follows:

[0037] (1) Weigh 40g of ethylene glycol and 3g of magnesium chloride into 200g of olive oil, control t...

Embodiment 2

[0041] First prepare polyether polyol I, the process is as follows:

[0042] (1) Weigh 50g of lignin, 30g of water, 3g of lignin peroxidase, 2g of catalase, 3g of furfural acetaldehyde and 10g of furfuryl alcohol in a reactor, the reaction temperature is 80°C, and the reaction is stirred for 5 hours to obtain Enzymatic modification of lignin;

[0043] (2) Mix 100g of enzymatically modified lignin, 250g of glycerol, 100g of diethylene glycol and 0.01g of Pd-Fe catalyst in the reactor, control the reaction temperature at 120°C, and bubble the reaction with nitrogen from the bottom of the reactor , and then vacuumized, adding 4 g of propylene oxide, and reacting under normal pressure for 2 hours to obtain the polyether polyol I with a functionality of 5.0 and a hydroxyl value of 400 mgKOH / g.

[0044] Then prepare polyether polyol II, the process is as follows:

[0045] (1) Weigh 20g of ethylene glycol and 1g of magnesium chloride into 100g of olive oil, control the reaction tem...

Embodiment 3

[0049] First prepare polyether polyol I, the process is as follows:

[0050] (1) Weigh 100g of lignin, 50g of water, 2g of lignin peroxidase, 3g of catalase, 8g of furfural acetaldehyde and 6g of furfuryl alcohol in a reactor, the reaction temperature is 80°C, and the reaction is stirred for 5 hours to obtain Enzymatic modification of lignin;

[0051] (2) Mix 100g of enzymatically modified lignin, 350g of glycerol, 250g of diethylene glycol and 0.05g of Pd-Fe catalyst in the reactor, control the reaction temperature at 120°C, and bubble the reaction with nitrogen from the bottom of the reactor , and then vacuumized, 10 g of propylene oxide was added, and the reaction was sealed under normal pressure for 2 hours to obtain the polyether polyol I with a functionality of 4.7 and a hydroxyl value of 410 mgKOH / g.

[0052] Then prepare polyether polyol II, the process is as follows:

[0053] (1) Weigh 50g of ethylene glycol and 5g of magnesium chloride into 300g of olive oil, contr...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle size (mesh)aaaaaaaaaa
hydroxyl valueaaaaaaaaaa
hydroxyl valueaaaaaaaaaa
Login to View More

Abstract

The invention relates to a thermal insulation material and discloses a solar polyurethane thermal insulation material. The thermal insulation material is prepared by mixing and foaming the following raw materials in parts by weight: 70-100 parts of diphenylmethane diisocyanate, 40-80 parts of polyether polyol I, 10-30 parts of polyether polyol II, 3-6 parts of expanded vermiculite, 5-8 parts of nano silicon dioxide, 10-20 parts of dichlorofluoroethane, 1-5 parts of catalyst and 1-5 parts of foam stabilizer, wherein the polyether polyol I is lignin polyether polyol; and the polyether polyol II is polyether polyol polymerized by taking modified olive oil as an initiator and epoxy propane as a polymerization monomer. The thermal insulation material has better compressive strength, tensile strength and impact strength while the phenomena of water tank deformation, bulking, ridging and even cracking are avoided.

Description

technical field [0001] The invention relates to thermal insulation materials, in particular to a solar polyurethane thermal insulation material. Background technique [0002] With the increasing shortage of energy and the increasing pressure on environmental protection, countries around the world have begun to promote the development of renewable energy, among which solar energy is the most widely used and developed renewable energy with the best development prospects, and has been widely used in various industries , the solar water heater industry is one of them. Our country is rich in solar energy resources and has broad prospects for solar energy utilization. At present, it is the first user and producer of solar water heaters in the world. [0003] As we all know, for solar water heaters, the selection of water tank insulation materials is very important. At present, the insulation materials that can be used as water tanks mainly include polyurethane foam, phenolic foam...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/48C08G18/64C08G18/76C08J9/14C08K3/34C08K3/36
CPCC08G18/4081C08G18/4891C08G18/6492C08G18/7671C08J9/144C08J2375/04C08K3/34C08K3/36C08K2201/011
Inventor 蒙胜杰马庆马珍马佳乐马祥黄可煜马付杰吴定超
Owner GUANGXI JISHUN ENERGY TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com