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Thermal-inductive fluorocarbon function coating containing azobenzene/carbon-hybrid material and preparation method of thermal-inductive fluorocarbon function coating

A technology of functional coatings and azobenzene, which is applied in the field of heat-sensitive fluorocarbon functional coatings and its preparation, can solve the problems of not having the function of self-storage and heat release, achieve excellent weather resistance, reduce power consumption, and reduce power consumption Effect

Active Publication Date: 2016-05-04
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the problems of the prior art, the object of the present invention is to provide a new type of heat-sensitive fluorocarbon functional coating combined with azobenzene / carbon material hybrid material and traditional fluorocarbon coating, through photothermal storage conversion, the The light energy stored in the light, such as solar energy, is released in the form of heat in the absence of light, which solves the problem that fluorocarbon materials do not have the function of self-storage and heat release under special environmental requirements, and greatly reduces power consumption

Method used

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  • Thermal-inductive fluorocarbon function coating containing azobenzene/carbon-hybrid material and preparation method of thermal-inductive fluorocarbon function coating
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  • Thermal-inductive fluorocarbon function coating containing azobenzene/carbon-hybrid material and preparation method of thermal-inductive fluorocarbon function coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

Matting agent

[0059] The structural formula of AZO is selected from:

[0060]

[0061] The preparation process of RGO-AZO is as follows:

[0062] (1) Weigh 10mmol of 5-aminoisophthalic acid (also can be 10mmol of 5-aminoresorcinol, 5-aminoresorcinol), 10.5mmol of NaOH, 100ml of deionized water into a beaker, ultrasonically dissolve; Equimolar NaNO with anthranilic acid 2 Dissolve in 50 mL and add the previous solution. Place the beaker in an ice bath to lower the temperature to 0-5°C; under stirring, slowly add this solution dropwise to 40ml of 1M HCl solution, the temperature is controlled at 0-5°C, and stir for 1 hour to obtain a diazonium salt solution .

[0063] (2) Weigh 3,5-diethoxyaniline (also can be equimolar 3,5-dimethoxyaniline, 3,5-dimethylaniline) with 5-aminoisophthalic acid equimolar, Add 1ml of concentrated HCL solution and 50ml of deionized water into the flask, stir to dissolve it under ice bath conditions, slowly add the diazonium salt soluti...

Embodiment 2

Matting agent

[0070] Wherein the structural formula of AZO in the embodiment two is selected from

[0071]

[0072] The preparation process of RGO-AZO is as follows:

[0073] (1) Weigh 10mmol of 3,5-difluoroaniline (also can be 10mmol of 3,5-dibromoaniline, 3,5-dichloroaniline, 3,5-diiodoaniline, 3,5-dinitroaniline), Add 10.5mmol of NaOH and an appropriate amount of deionized water into a beaker, and ultrasonically dissolve; weigh the NaNO equivalent to 3,5-difluoroaniline 2 Dissolve in 50 ml of deionized water and add the previous solution. Place the beaker in an ice bath and lower the temperature to 0-5°C; under stirring, slowly add this solution dropwise into 40ml of 1M HCl solution, the temperature is controlled at 0-5°C, and stir for 2 hours to obtain diazo saline solution.

[0074] (2) Weigh 3,5-bis(trifluoromethyl)aniline (also can be equimolar 3,5-bis(trifluoromethoxy)aniline, 3,5- Difluoroaniline), 1ml concentrated HCL solution, 40ml deionized water we...

Embodiment 3

Matting agent

[0081] Wherein the structural formula of AZO in the embodiment three is selected from

[0082]

[0083] The preparation process of RGO-AZO is as follows:

[0084] ⑴Weigh 10mmol p-aminophenylboronic acid (also can be 10mmol p-aminophenylboronic acid, p-aminobenzoic acid, p-aminobenzenesulfonic acid), 400mgNaOH, appropriate amount of deionized water into a beaker, ultrasonically dissolve; weigh and p-aminophenylboronic acid, etc. moles of NaNO 2 After dissolving in an appropriate amount of deionized water, add the aforementioned solution. Place the beaker in an ice bath and lower the temperature to 0-5°C; under stirring, slowly add this solution dropwise into 40ml of 1M HCl solution, the temperature is controlled at 0-5°C, and stir for 2 hours to obtain diazo saline solution.

[0085] (2) Weigh 3,5-difluoroaniline (or 3,5-dibromoaniline, 3,5-dichloroaniline) which is equimolar to p-aminophenylboronic acid, 1ml concentrated HCL solution, 40ml deionize...

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Abstract

The invention discloses a thermal-inductive fluorocarbon function coating containing an azobenzene / carbon-hybrid material and a preparation method of the thermal-inductive fluorocarbon function coating. The coating is prepared from the following components: 40 to 60 parts of fluorocarbon resin, 10 to 20 parts of crosslinking resin, 15 to 20 parts of mixed solvent, 10 parts of pigment, 5 to 15 parts of the azobenzene / carbon-hybrid material, 0.5 part of delustering agent, 0.1 part of flatting agent, 0.15 part of defoaming agent, 0.25 part of dispersant and 0.00035 part of curing agent. The coating disclosed by the invention has the advantages that light energy, such as solar energy, stored in an illumination process is released in the form of heat under the condition without illumination through photo-thermal storage conversion, so that the problem that a fluorocarbon material has no heat self-storage / release function under special environments is solved, and the power consumption is greatly reduced; the coating can be widely applied to the fields of architecture, electrical and electronic industries, aerospace industry and the like; as a new and green energy, the coating has immeasurable application prospects and economic benefits for dealing with the global energy crisis.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a thermally sensitive fluorocarbon functional coating containing an azobenzene / carbon hybrid material and a preparation method thereof; a thermally sensitive coating and a preparation method applied to the outer layer of high-end precision machinery such as aerospace. Background technique [0002] Fluorocarbon resin has a strong C-F bond as the skeleton. Compared with other resins, it has better heat resistance, chemical resistance, cold resistance, low temperature flexibility, weather resistance and electrical properties, and because of its good crystallinity , so it is non-adhesive and non-wetting. Widely used in kitchen and cooking utensils, molding molds, mechanical sliding parts, advanced coil coatings for food, textile, papermaking and other industrial machinery, various tanks, pipelines, pumps, reactors, heat exchangers and precision instruments And other coating and lin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D127/16C09D127/12C09D7/12
CPCC09D7/61C09D7/63C09D127/12C09D127/16C08L33/00C08K13/02C08K5/23C08K3/04C08L61/20
Inventor 封伟赵肖泽冯奕钰
Owner TIANJIN UNIV
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