Preparation method of low stress state composite substrate for GaN growth
A composite substrate, low stress technology, applied in electrical components, circuits, semiconductor devices, etc., can solve the problems of GaN epitaxial film wrinkling, poor high temperature stability, stress residual and other problems, to improve the quality of epitaxial growth, good thermal conductivity and electrical conductivity, The effect of suppressing the wrinkle of the epitaxial film
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Embodiment 1
[0044] Embodiment 1: Using Ni as the stress compensation layer, conductive Agpaste bonding CuMo metal substrate and GaN epitaxial layer, obtain the preparation method of the low stress state composite substrate used for GaN growth:
[0045] (1) Epitaxial growth of a GaN single crystal layer on a sapphire substrate: On a 2-inch 430-micron-thick flat sapphire substrate, first use MOCVD technology to epitaxially grow a 4-micron-thick GaN single-crystal layer, and then grow thicker in HVPE The thickness of the GaN layer is up to 15 microns.
[0046] (2) use magnetron sputtering deposition thickness to be the Ni thin layer of 500 nanometers on the back side of 300 microns thick CuMo metal substrate (wherein the mass percentage of Mo and Cu is respectively 20% to 80%), as stress compensation layer, as Figure 4 (a) shown.
[0047] (3) On the GaN surface of the above-mentioned sapphire-based GaN composite substrate and the front surface of the CuMo substrate with a thickness of 300 ...
Embodiment 2
[0049] Example 2: Using Au / Pd as the stress compensation layer, Ti / Pd bonded Si substrate and adhesively transferred GaN epitaxial layer to obtain a low-stress state composite substrate for GaN growth with the gallium polarity facing outward Preparation:
[0050] (1) Preparation of adhesive transfer sapphire-based GaN composite substrate: On a 2-inch 430-micron-thick flat sapphire substrate, a 4-micron-thick GaN single crystal layer is epitaxially grown by MOCVD technology, and then grown in HVPE to thicken GaN layer thickness to 15 microns, and then use UV anaerobic adhesive to bond the GaN epitaxial film to a 2-inch 430-micron thick sapphire temporary substrate, the new sapphire substrate is used as a transfer support substrate, and then the original The epitaxial sapphire substrate is removed, and the GaN single crystal layer bonded on the new sapphire substrate is obtained, such as Figure 5 a) as shown.
[0051] (2) On the back of the Si substrate with a thickness of 30...
Embodiment 3
[0054] Example 3: Using SiN x As a stress compensation layer, AuAu bonded AlSi metal substrate and GaN epitaxial layer to obtain the preparation method of the low stress state composite substrate for GaN growth, the specific process steps are as follows (such as Image 6 shown):
[0055] (1) Epitaxial growth of a GaN single crystal layer on a sapphire substrate: On a 2-inch 430-micron-thick flat sapphire substrate, first use MOCVD technology to epitaxially grow a 4-micron-thick GaN single-crystal layer, and then grow thicker in HVPE The thickness of the GaN layer is up to 15 microns.
[0056] (2) Using plasma-enhanced chemical vapor deposition to prepare SiN with a thickness of 5 microns on the back of a 150 micron thick AlSi metal substrate (wherein the composition of Al is 30%, and the composition of Si is 70%) x thin layer, as a stress compensation layer.
[0057] (3) On the GaN surface of the above-mentioned sapphire-based GaN composite substrate, use magnetron sputteri...
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