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High-fluidity, scratch-resistant and low-temperature-folding-resistant ABS (acrylonitrile butadiene styrene)/TPU (thermoplastic polyurethane) alloy material and preparation method and application thereof

An alloy material and scratch-resistant technology, which is applied in the field of high-flow, scratch-resistant, low-temperature foldable ABS/TPU alloy materials and its preparation, and ABS composite modified materials, to achieve excellent processing performance, good fluidity, and scratch resistance Good results

Inactive Publication Date: 2016-04-20
JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] "ABS / TPU Alloy Properties and Microstructure" "Modern Plastics Processing Application" and "Research on Blending Modification of Thermoplastic Polyurethane to ABS" "Synthetic Resins and Plastics" pointed out that TPU has good compatibility with ABS, and the addition of TPU The toughness and fluidity of ABS can be improved at the same time, but how to prepare ABS / TPU alloy materials with balanced mechanical strength, excellent scratch resistance, low-temperature folding properties, and high fluidity has not been reported yet.

Method used

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  • High-fluidity, scratch-resistant and low-temperature-folding-resistant ABS (acrylonitrile butadiene styrene)/TPU (thermoplastic polyurethane) alloy material and preparation method and application thereof
  • High-fluidity, scratch-resistant and low-temperature-folding-resistant ABS (acrylonitrile butadiene styrene)/TPU (thermoplastic polyurethane) alloy material and preparation method and application thereof
  • High-fluidity, scratch-resistant and low-temperature-folding-resistant ABS (acrylonitrile butadiene styrene)/TPU (thermoplastic polyurethane) alloy material and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~14

[0029] First, the components of Examples 1-14 and Comparative Examples 1-2 shown in Tables 2-3 were successively added to a high-speed mixer according to the proportioning ratio, and the ABS resin was dried at 85°C for 4 hours before mixing. , thermoplastic polyurethane TPU is dried at 100°C for 4 hours before mixing, and the speed of the high-speed mixer is set to 800rpm; then the above mixture is sent to a twin-screw extruder for mixing, extrusion, stranding, cooling, and pelletizing; among them, The length-to-diameter ratio of the twin-screw extruder is 40:1; the temperature of the screw barrel is set as follows: the temperature of the first zone is 80°C, the temperature of the second zone is 190°C, the temperature of the third zone is 200°C, the temperature of the fourth zone is 210°C, and the temperature of the fifth zone is 220°C , the temperature of the sixth zone is 220°C, the temperature of the seventh zone is 220°C, the temperature of the eighth zone is 220°C, the tem...

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Abstract

The invention discloses a high-fluidity, scratch-resistant and low-temperature-folding-resistant ABS / TPU alloy material which is prepared from the components by weight percentage of 60 wt%-85 wt% of ABS resin, 10 wt%-30 wt% of TPU and 1 wt%-10 wt% of compatilizer; the preparation method comprises the steps that the ABS resin and the TPU are dried under the condition of 85 DEG C to 100 DEG C for 2-4 hours, then the ABS resin and the TPU are fully mixed with other component raw materials according to the ratio by a high-speed mixer for 2-10 minutes, the mixtures is then transmitted to a double-screw extruder by a precision metering feeding device, and a product is obtained through mixing, extrusion, bracing, cooling and grain cutting; the prepared ABS / TPU alloy material has excellent scratch resistance, low low temperature folding resistance and high fluidity, the preparation method is simple in process, convenient to operate and suitable for industrial production, and the ABS / TPU alloy material can be applied to the fields of small electronic consumer products, electric tools, computer keys, automobile bumpers and the like.

Description

technical field [0001] The invention relates to an ABS composite modified material, in particular to a high-flow, scratch-resistant, low-temperature foldable ABS / TPU alloy material and its preparation method and application, belonging to the field of polymer materials. Background technique [0002] ABS resin is a terpolymer composed of styrene, butadiene and acrylonitrile. It combines the high fluidity of styrene, the rubber toughness of butadiene and the chemical resistance of acrylonitrile. It has excellent processing performance, Low temperature resistance, electrical insulation, chemical corrosion resistance, high gloss and excellent electroplating performance, as well as good creep resistance, high dimensional stability, small molding shrinkage, etc., are widely used in military industry, automobiles, electronic appliances, etc. The field of application is very wide. However, the scratch resistance of ABS resin is not good, and the low temperature bending resistance is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L75/04C08L35/06C08L91/00C08K5/00C08K5/134C08K5/526C08K5/098
CPCC08L55/02C08L2205/035C08L75/04C08L35/06C08L91/00C08K5/00C08K5/1345C08K5/526C08K5/098
Inventor 汪炉林王林许晶玮胡付余黄池光郭少华夏建盟
Owner JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD
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