Low-tension hydroxyoximido emulsion oil-displacement polymer and preparation method thereof
An oil-displacing polymer and low-tension technology, applied in drilling compositions, chemical instruments and methods, etc., can solve the problem of reducing the interfacial tension of emulsion polymer oil-displacing product system, poor solution uniformity and fluidity, and oil-displacing effect. It can reduce the ground investment, dissolve quickly, and reduce the investment in ground construction.
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Embodiment 1
[0048] The low-tension hydroxime-based emulsion flooding polymer provided in this embodiment consists of the following components: acrylamide, acrylic acid, water, liquid caustic soda, 2-acrylamido-2-methylpropanesulfonic acid, methylene bis Allylamine, potassium bromate, sodium formate, pentasodium diethylenetriamine pentaacetate, copper sulfate pentahydrate, white oil D110, algin oleamide, Span-80, Tween-81, emulsifying dispersant OA90, azo, hydroxylamine sulfate, isomer Cetyloxyethylene ether.
[0049] The content of each component in parts by weight is:
[0050] 80~180 parts of acrylamide
[0051] Acrylic 50~100 parts
[0052] 50~180 parts of water
[0053] 50~100 parts of liquid caustic soda
[0054] 10-40 parts of 2-acrylamido-2-methylpropanesulfonic acid
[0055] 0.002~0.008 parts of methylene bis allylamine
[0056] 20-50 parts of hydroxylamine sulfate
[0057] 0.055 parts of potassium bromate
[0058] 0.140 parts of sodium formate
[0059] 0.800 parts of pentasodium diethylenetriam...
Embodiment 2
[0118] The preparation method of the low tension hydroxime-based emulsion oil displacement polymer provided in the second embodiment of the present invention includes:
[0119] (1) Add water, acrylamide, acrylic acid, and liquid caustic soda sequentially to 2-acrylamido-2-methylpropanesulfonic acid to neutralize the pH to the preset range, and control the temperature of the whole process to be lower than 50 degrees to form a reaction liquid;
[0120] (2) Add white oil D110, Alginolamide, Span 80, Tween 81, emulsifying and dispersing agent OA90, and azo to the reaction solution in sequence, and dissolve potassium bromate, sodium formate, and copper sulfate pentahydrate in an appropriate amount of water. Add the reaction liquid; in this example, the algin oleamide is obtained by extracting triglycerides from microalgae, adding liquid ammonia, and reacting for 10 hours at 1 Mpa and 150 degrees. (3) Emulsify with an emulsifier to a viscosity of 800~1200mPa·s, blow nitrogen for 20~60 mi...
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