Preparation method of crystallizer copper plate plated with ferro-nickel alloy layer

Abstract

The invention discloses a preparation method of a crystallizer copper plate plated with a ferro-nickel alloy layer. The crystallizer copper plate comprises the following components in percentage by mass: 1-2% of Ni, 0.05-0.2% of Be, 0.5-0.7% of Al, 3.0-5.0% of Zr, 1.2-1.4% of Mn, 1-3% of Mg, 0.8-1.2% of Cr, 14.0-16.0% of Zn, and the balance of Cu. The preparation method comprises the following steps: a copper alloy with the components is adopted to prepare a crystallizer; a plating layer is electroplated on the surface of the crystallizer; plating solution adopted by electroplating comprises the following components: 220-240 g / l of nickel sulfate, 17-19 g / l of nickel chloride, 11.0-13.0 g / l of ferric sulfate, 23-27 g / l of boric acid, 5-7 g / l of nickel chloride, 30-40 g / l of sodium chloride, 0.2-0.4 g / l of lauryl sodium sulfate, and 20-22 ml / L of additive, wherein solution prepared by adding 10-12 g of sodium gluconate, 33-37 g of ascorbic acid and 22-26 g of dextrin in 1 l of water is added; and the electroplating process has the following conditions: the PH value is 2.3-3.5; the current density is 3.5-4.5 A / dm2; the temperature is 44-46 DEG C; and the electroplating is performed until the thickness of the plating layer is 1.3-1.5 mm.

Description

technical field [0001] The invention relates to the technical field of electroplating, in particular to a preparation method of a crystallizer copper plate plated with a nickel-iron alloy layer. Background technique [0002] The mold copper plate is an important part of the continuous casting machine. The molten steel flows through the mold of the continuous casting machine and is cooled to form a billet. In the production process of continuous casting and drawing, the surface of the billet and the copper plate are in contact with each other to produce friction, and the surface of the copper plate is worn. Usually, functional electroplating technology is used to coat the surface of a layer of material with good thermal conductivity and wear resistance to reduce the surface of the copper plate. Wear, improve the repair times of copper plates, and prolong the service life of copper plates. With the development of continuous casting technology, copper plate electroplating tech...

AI Technical Summary

Problems solved by technology

With the development of continuous casting technology, copper plate electroplating technology develops rapidly: the coating material develops from simple metal to alloy material, from chromium to nickel to nickel-iron, nickel-cobalt alloy, and the coating form develops from composite layer to single layer. This functional electroplating Different from ordinary electroplating, the coating is relatively thick, usually with a thickness of 0.2mm-2mm, which inevitably leads to a large accumulation of internal stress in the coating. In the continuous casting production of copper plates, the coating working surface is in the environment of high-temperature molten steel and cooling water. Frequent alternation can induce cracks in the coating, and sometimes the coating will fall off, which affects the amount of steel passed through the copper plate and affects the production efficiency of the continuous casting machine

Moreover, there are many electroplating processes and the production cycle is long