Reaction-activity-controllable acrylate emulsion and preparation method thereof
An acrylate and reactive technology, which is applied in the coating and other directions, can solve the problems of poor water whitening resistance, poor viscosity storage stability, and poor storage stability of coatings, so as to ensure water whitening resistance, improve hydrophilic performance, and improve water resistance. staining effect
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[0033] The preparation method of the acrylate emulsion with controllable reactivity of the present invention comprises the following steps:
[0034] a: Preparation of monomer solution A and acid solution B: under normal temperature and pressure, mix isooctyl acrylate, methyl methacrylate, styrene, functional monomer and 50% water in total and stir evenly for 20-40 Minutes to make monomer solution A; mix the hydrophilic unsaturated organic acid with a total amount of 30% water and stir evenly for 10-20 minutes to make acid solution B;
[0035] b: Divide the monomer solution A and the acid solution B into two parts and mix them evenly to form a blend solution 1 and a blend solution 2. The mass ratio of the monomer solution A in the blend solution 1 and the blend solution 2 is 1: (1-4) , the mass ratio of the acid solution B in the blend 1 and the blend 2 is (1-4):1;
[0036] c: Preparation of pre-emulsion C: Add 50% emulsifier into blend 1 at normal temperature and pressure, an...
Embodiment 1
[0046] The acrylate emulsion with controllable reactivity of the present invention includes water, isooctyl acrylate, methyl methacrylate, styrene, acrylic acid, vinyltrimethoxysilane, sodium dodecylsulfonate and ammonium persulfate, the above-mentioned The component contents are calculated in parts by mass: 100 parts of water, 10 parts of isooctyl acrylate, 10 parts of methyl methacrylate, 5 parts of styrene, 30 parts of acrylic acid, 10 parts of vinyltrimethoxysilane, twelve parts 5 parts of sodium alkylsulfonate, 1 part of ammonium persulfate.
[0047] The preparation method of the acrylate emulsion with controllable reactivity of the present invention comprises the following steps:
[0048] a: Preparation of monomer solution A and acid solution B: under normal temperature and pressure, mix isooctyl acrylate, methyl methacrylate, styrene, functional monomer and 50% water in total and stir evenly for 20 minutes, Make monomer solution A; mix hydrophilic unsaturated organic a...
Embodiment 2
[0059] The reactive controllable acrylate emulsion of the present invention includes water, isooctyl acrylate, methyl methacrylate, styrene, acrylic acid, methacrylic acid, itaconic acid, vinyltrimethoxysilane, methacryloxy Propyltrimethoxysilane, Allyl Methacrylate Silicone Polymer, Sodium Dodecyl Sulfate, Sodium Dodecylbenzene Sulfonate, Sodium Lauryl Sulfate, Ammonium Persulfate, Potassium Persulfate and sodium persulfate, the contents of the above components are calculated in parts by mass: 100 parts of water, 40 parts of isooctyl acrylate, 50 parts of methyl methacrylate, 25 parts of styrene, 10 parts of acrylic acid, and 20 parts of methacrylic acid , 20 parts of itaconic acid, 10 parts of vinyltrimethoxysilane, 10 parts of methacryloxypropyl trimethoxysilane, 10 parts of silicon polymer of allyl methacrylate, 10 parts of dodecylsulfonic acid 3 parts sodium, 3 parts sodium dodecylbenzenesulfonate, 4 parts sodium lauryl sulfate, 1 part ammonium persulfate, 1 part potassiu...
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