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A kind of nano ceramic material composition and standard capacitor and preparation method thereof

A material composition and nano-ceramic technology, applied in the field of precision electromagnetic measurement, can solve the problems of large loss factor, narrow capacity range, and low accuracy level, and achieve the effects of small loss factor, wide capacity range, and high dielectric strength

Inactive Publication Date: 2019-02-22
NAT INST OF METROLOGY CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Quartz standard capacitors have the advantages of high stability and small thermal expansion coefficient; however, the dielectric constant of quartz is small, and the capacity of standard devices made of it is generally less than 100pF. Therefore, quartz capacitors cannot meet the use requirements of a wide capacity range.
The standard capacitor with air or nitrogen as the medium has the advantages of small loss factor and good stability; but its effective electrode area and the distance between electrodes are connected and supported by metal parts, the mechanical structure is more complicated, and the air or nitrogen The dielectric constant is small, and the capacity range is relatively narrow, generally 1pF ~ 1000pF
Mica is used as a standard capacitor as a dielectric material, with excellent mechanical and electrical properties, and a loss factor of 10 -4 Order of magnitude, capacity range 10nF~1μF; However, due to the high impurity content of natural mica, when the electrode is sintered after silver plating, the process is not easy to control, and its accuracy level is low
[0004] At present, in the precision measurement of impedance and the transfer of capacitance value in our country, many scientific research institutes and testing institutions purchase standard capacitors produced at home and abroad, all of which have problems such as low accuracy level, large loss factor, and narrow capacity range, which cannot meet my country's requirements. Demand for High Accuracy, High Quality Standard Capacitors

Method used

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  • A kind of nano ceramic material composition and standard capacitor and preparation method thereof
  • A kind of nano ceramic material composition and standard capacitor and preparation method thereof
  • A kind of nano ceramic material composition and standard capacitor and preparation method thereof

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preparation example Construction

[0024] The present invention also provides a kind of preparation method of nano-ceramic material composition, and this method comprises the following steps:

[0025] (1) Nanoization: grind the ceramic material to the nanometer level; the particle size is less than or equal to 10 -9 m;

[0026] (2) Fine crystallization: adding nano-material additives to the nano-sized ceramic material; the addition method is, for example, grinding and adding;

[0027] (3) Porcelainization: Add glass frit sintering aid to the finely crystallized ceramic material, and sinter it into porcelain at 1300-1400°C for 2-4 hours.

[0028] The present invention also provides a standard capacitor and a preparation method thereof, wherein the dielectric of the capacitor is the nanometer ceramic material composition. The preparation method comprises the following steps: preparation of nano-ceramic material composition, casting into film, slicing, printing internal electrodes, stacking, hot pressing, cuttin...

Embodiment 1

[0032] Preparation of nano-ceramic material composition: grind 97g of ceramic material to nano-scale; particle size is less than or equal to 10 - 9 m; Add 1.8g SiO to the nano-sized ceramic material 2 ; Then add 1.2gB to the fine-grained ceramic material 2 o 3 -ZnO-Nd 2 o 3 -Bi 2 o 3 -SiO 2 -Li 2 O, and sintered into porcelain at 1300 ° C, the sintering time is 3 hours.

Embodiment 2

[0034] Preparation of nano-ceramic material composition: grind 98.5g of ceramic material to nano-scale; particle size is less than or equal to 10 -9 m; Add 1.0g CeO to the nano-sized ceramic material 2 ; Add 0.5g B to the fine-grained ceramic material 2 o 3 -ZnO-Bi 2 o 3 -Nd 2 o 3 , and sintered into porcelain at 1350 ° C, the sintering time is 4 hours.

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Abstract

The invention provides a nano ceramic material composition, and a preparation method thereof. The nano ceramic material composition comprises a nano ceramic material, a nanometer substance additive, and a glass frit sintering aid; the nanometer substance additive comprises at least one ingredient selected from Sm2O3, CeO2, Nd2O3, BiO2, SiO2, MnCO3, and MnO2. The invention also provides a standard capacitor, and a preparation method thereof. The nano ceramic material composition is taken as a medium of the standard capacitor. The standard capacitor prepared by taking the nano ceramic material composition as the medium is high in accurate, low in loss factor, wide in capacity range, and high in stability and reliability.

Description

technical field [0001] The invention relates to the technical field of precision electromagnetic measurement, more specifically, to a nano ceramic material composition, a standard capacitor and their preparation methods. Background technique [0002] The standard capacitors currently used in the market mainly include: quartz standard capacitors, air standard capacitors, mica standard capacitors, etc. [0003] Quartz standard capacitors have the advantages of high stability and small thermal expansion coefficient; however, the dielectric constant of quartz is small, and the capacity of standard devices made of it is generally less than 100pF. Therefore, quartz capacitors cannot meet the use requirements of a wide capacity range. The standard capacitor with air or nitrogen as the medium has the advantages of small loss factor and good stability; but its effective electrode area and the distance between electrodes are connected and supported by metal parts, the mechanical struc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/63
Inventor 何小兵戴冬雪金攀王维陈妍张欣刘夏
Owner NAT INST OF METROLOGY CHINA
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