Catalyst for catalytic combustion of chloralkane, preparation method and application thereof
A technology of catalytic combustion and chlorinated alkanes, which is applied in the direction of combustion methods, physical/chemical process catalysts, chemical instruments and methods, etc., to improve the anti-chlorine poisoning performance, increase the content of active oxygen species and oxygen mobility, and facilitate oxidation detoxification The effect of removing
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Embodiment 1-3
[0037] This embodiment 1-3 is the component and content of the catalyst of catalytic combustion chlorinated alkanes of the present invention, specifically see following table 1:
[0038] Table 1
[0039] Example MnO x -SrO 2 The mass percentage of composite oxides in the catalyst SrO 2 % of active ingredient TiO 2 -ZrO 2 The mass percentage of composite oxides in the catalyst Ti / Zr value of x Example 1 3wt% 10wt% 97wt% 1 2, 3 or 4 Example 2 5wt% 30wt% 95wt% 1 2, 3 or 4 Example 3 10wt% 50wt% 90wt% 1 2, 3 or 4
Embodiment 4
[0041] The preparation method of the catalyst of above-mentioned embodiment 1-3 comprises the following steps:
[0042] (1) Dissolve a certain amount of manganese nitrate and strontium nitrate in a certain concentration of oxalic acid solution, and mix after the solution is fully dissolved;
[0043] (2), add pre-prepared TiO to the mixed solution in step (1) 2 -ZrO 2 Composite oxide carrier, stirred evenly, impregnated for 24 hours;
[0044] (3) Dry the mixture in step (2) at 110°C for 12 hours;
[0045] (4) Put the dried product of step (3) into a muffle furnace and calcinate for 3 hours at 400°C in the air, and then grind and sieve to obtain a catalyst. The catalyst is expressed as: (MnO x ) m -(SrO 2 )n / Ti 0.5 Zr 0.5 , where m and n represent MnO x and SrO 2 Accounting for the mass fraction of the catalyst, X is a positive integer greater than 2. The catalyzer as embodiment 1 is (MnO x ) 0.027 -(SrO 2 ) 0.003 / Ti 0.5 Zr 0.5 , the catalyst of embodiment 2 is ...
Embodiment 5
[0047] The catalyst of above-mentioned embodiment 1-3 can also be made through the following steps:
[0048] (1) Dissolve a certain amount of manganese nitrate and strontium nitrate in a certain concentration of hydrochloric acid solution, and mix after the solution is fully dissolved;
[0049] (2), add pre-prepared TiO to the mixed solution in step (1) 2 -ZrO 2 Composite oxide carrier, stirred evenly, impregnated for 36 hours;
[0050] (3) Dry the mixture in step (2) at 90°C for 10 hours;
[0051] (4) Put the dried product of step (3) into a muffle furnace for calcination at 350° C. in air for 2 hours, and then grind and sieve to obtain a catalyst.
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