High-antibacterial-performance and high-wear-resistance TPE (thermal plastic elastomers) shock-absorption kneecap and preparation method thereof
A knee pad and chitosan technology, applied in the field of shock-absorbing knee pads and their preparation, can solve the problems of poor wear resistance, discomfort, growth of bacteria and molds, etc., and achieve the effects of excellent shock absorption performance, good skin contact, and high antibacterial properties.
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[0047] The preparation method of described amino-terminated hyperbranched polyamide-amine can be:
[0048]Add 1~2mol of N-aminoethylpiperazine and 1~4mol of bisacrylamide monomer into 30ml methanol aqueous solution, stir and react at 70~80°C for 80~90h, cool down naturally, wash with deionized dilution, and then The end-capped hyperbranched polymer is precipitated with cold acetone, and vacuum-dried at room temperature for 10-24 hours to obtain amino-terminated hyperbranched polyamide-amine.
[0049] In one embodiment, the preparation method of the glyoxal modified chitosan-amino-terminated hyperbranched polyamide-amine complex is as follows: in a 100ml three-necked bottle, add the above-mentioned synthetic glyoxal modified shell 0.1 g of polysaccharide, 0.2-2 g of amino-terminated hyperbranched polyamido-amine, and 50 ml of N,N-dimethylformamide, after stirring at room temperature; after reacting at 50-80°C for 10-24 hours, Settling and filtering in medium to obtain glyoxal ...
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