Inorganic-organic polymer treatment agent for drilling fluid and preparation method thereof
A technology of treating agent and drilling fluid, which is applied in the field of synthesis and preparation of water-soluble polymer materials, can solve the problems that the treating agent no longer faces the difficulties of temperature resistance and salt resistance, and can achieve good protection effect and control hydration. The effect of dispersion and simple production process
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Embodiment 1
[0019] 1) Add 14 kg of sodium hydroxide and 160 kg of water into the neutralization kettle, add 20 kg of aluminum tripolyphosphate after complete dissolution, and grind with a colloid mill after stirring evenly. Add the ground mixed liquid to the reaction kettle, slowly add 30 kg of 2-acrylamide-2-methylpropanesulfonic acid and 15 kg of acrylic acid under the condition that the temperature does not exceed 35°C, and continue stirring for 10 minutes after the addition is complete. Add 55 kg of acrylamide, and continue stirring for 25 minutes after the addition, to obtain a reaction mixture.
[0020] 2) Add the reaction mixture obtained in step 1) into the polymerization tank, stir for 5 minutes, and adjust the pH value of the system to 9.0 with 10% sodium hydroxide solution by mass fraction. Add 0.3 kg of ammonium persulfate and 0.5 kg of sodium bisulfite (aqueous solution prepared with an appropriate amount of water), stir for about 15 min and then stand still, control the init...
Embodiment 2
[0022] 1) Add 19.4 kg of sodium hydroxide and 150 kg of water into the neutralization kettle, add 32 kg of aluminum tripolyphosphate after complete dissolution, and grind with a colloid mill after stirring evenly. Add the ground mixed liquid to the reaction kettle, slowly add 70 kg of 2-acrylamide-2-methylpropanesulfonic acid and 18 kg of maleic acid under the condition that the temperature does not exceed 35 °C, and continue to stir for 15 minutes after the addition is complete . Add 40 kg of acrylamide, and continue stirring for 15 minutes after the addition, to obtain a reaction mixture.
[0023] 2) Add the reaction mixture obtained in step 1) into the polymerization tank, stir for 8 minutes, and adjust the pH value of the system to 9.5 with a 20% mass fraction of sodium hydroxide solution. Add 0.8 kilograms of potassium persulfate and 1.6 kilograms of sodium metabisulfite (aqueous solution prepared with an appropriate amount of water), stir for about 8 minutes and stand s...
Embodiment 3
[0025] 1) Add 10.4 kg of sodium hydroxide and 150 kg of water into the neutralization kettle, add 15 kg of aluminum tripolyphosphate after complete dissolution, and grind with a colloid mill after stirring evenly. Add the ground mixed liquid to the reaction kettle, and slowly add 28 kg of 2-acrylamide-2-phenylethanesulfonic acid and 13 kg of methacrylic acid under the condition that the temperature does not exceed 35 °C, and continue to stir for 20 minutes after the addition is complete . Add 83 kg of isobutylacrylamide, and continue stirring for 25 minutes after the addition is complete to obtain a reaction mixture.
[0026] 2) Add the reaction mixture obtained in step 1) into the polymerization tank, stir for 6 minutes, and adjust the pH value of the system to 11 with 20% sodium hydroxide solution by mass fraction. Add 0.25 kg of sodium persulfate and 0.5 kg of sodium metabisulfite (aqueous solution prepared with an appropriate amount of water), stir for about 6 minutes and...
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