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Modified calcium carbonate with high whiteness and wide application range and preparation method thereof

A calcium carbonate and range technology, applied in the field of modified calcium carbonate and its preparation, can solve the problems of poor direct application effect, uneven dispersion of polymers, interface defects, etc., and achieve high mechanical strength, good suspension stability, Improve the effect of light fastness

Inactive Publication Date: 2015-11-25
CHIZHOU CELT NANO TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the product, and reduce the cost of the product, but its surface has hydroxyl groups with strong hydrophilicity. It presents a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion in the polymer, resulting in two materials. The effect of direct application is not good, and calcium carbonate is used as a filler, and its acid resistance, smoothness, whiteness and other properties need to be further improved. Therefore, in order to improve the reinforcing effect of calcium carbonate and the dispersion performance in composite materials And the physical properties of modified calcium carbonate filled composite materials, it is necessary to use different surface modifiers and treatment methods to modify the surface of calcium carbonate powder, thereby broadening the application field of calcium carbonate

Method used

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Embodiment Construction

[0012] specific implementation plan

[0013] The present invention will be described in detail below through specific examples.

[0014] A modified calcium carbonate with high whiteness and wide application range and its preparation method is prepared from the following raw materials in parts by weight (kg): calcium carbonate 150, sodium oleate 46, sodium dodecylbenzenesulfonate 0.6, Sodium bicarbonate 2, styrene 7, potassium persulfate 0.05, fumed silica 5, organic bentonite 3, shea butter 2, nano barium sulfate 3, active zinc oxide 3, appropriate amount of deionized water;

[0015] A kind of modified calcium carbonate with high whiteness and wide application range and preparation method thereof of the present invention is made by the following specific steps:

[0016] (1) Dissolve sodium oleate and deionized water to make a 1% aqueous solution of sodium oleate, stir electrically for 10 minutes and raise the temperature to 60°C, add calcium carbonate and stir for 1.5 hours, ...

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Abstract

The invention discloses modified calcium carbonate with high whiteness and a wide application range and a preparation method thereof. Modified calcium carbonate is characterized by being prepared from the following raw materials in parts by weight: 100-150 parts of calcium carbonate, 30-50 parts of sodium oleate, 0.3-0.7 part of sodium dodecyl benzene sulfonate, 1-3 parts of sodium bicarbonate, 4-8 parts of styrene, 0.02-0.05 part of potassium persulfate, 3-5 parts of fumed silica, 2-3 parts of organic bentonite, 1-2 parts of shea butter, 2-3 parts of nano barium sulfate, 2-3 parts of activated zinc oxide and proper amount of deionized water. The whiteness of calcium carbonate powder is improved and the light, weather and chemical corrosion resistance, impact strength, and the like of the product can be improved through synergistic effects of the shea butter, nano barium sulfate and activated zinc oxide, so that the quality of the product is greatly improved and the product is worthy to be popularized.

Description

technical field [0001] The invention relates to the field of industrial fillers, in particular to a modified calcium carbonate with high whiteness and wide application range and a preparation method thereof. Background technique [0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the product, and reduce the cost of the product, but its surface has hydroxyl groups with strong hydrophilicity. It presents a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion in the polymer, resulting in two materials. The effect of direct application is not good, and calcium carbonate is used as a filler, and its acid resistance, smoothness, whiteness and other properties need to be further improved. Therefore, in order to improv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/02C09C3/06C09C3/08C09C3/10
Inventor 顾宗军
Owner CHIZHOU CELT NANO TECH
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