Cordierite aluminum magnesium titanate compositions and ceramic articles comprising same
A technology of ceramic products and cordierite, which is applied in the field of composite ceramic compositions, and can solve problems such as failure to achieve thermodynamic equilibrium, high thermal expansion value, and microcracks
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[0055] According to another example embodiment, the sintering aid may include cerium oxide (CeO 2 ) or cerium oxide with one or more other metal oxides such as Fe 2 TiO 5 ,Y 2 o 3 , and La 2 o 3 The combination. For example, the sintering aid may include a combination of ceria and yttrium oxide, a combination of ceria and lanthanum oxide, or a combination of ceria and yttrium oxide and lanthanum oxide. The inventors found that cerium oxide or cerium oxide and one or more other metal oxides such as Fe 2 TiO 5 A mixture of , yttrium oxide and lanthanum oxide gives similar CTE, porosity, pore size and pore size distribution, and the rare earth cost is lower than using yttrium oxide alone.
[0056] In an example embodiment, the amount of cerium oxide may range from 0.1 to 5.0 wt%. For example, the amount of cerium oxide may range from 0.2-2.0 wt%, 0.3-1.0 wt%, and 1.5-2.5 wt%. As noted above, in an example embodiment, cerium oxide and one or more other metal oxides such ...
Embodiment
[0058] The invention will be further described below with reference to some exemplary and specific embodiments of the invention, which are intended to be illustrative only and not intended to be limiting. According to some examples, a series of inventive ceramic articles were prepared having a basic inorganic batch composition as provided in Table 1 by weight percent of the final constituent phase, and in Table 2 by weight percent of a single component oxide. Compositions expressed in weight percent do not include any sintering additives.
[0059] Table 1
[0060]
[0061] Table 2
[0062]
[0063] Tables 3 through 11 and 13 provide data for examples of the invention made according to the basic compositions of Tables 1 and 2. The raw materials, porogens, and sintering aids used to make the samples are listed (median particle size in parentheses). These examples are provided by grinding the component powders with water and an organic binder, followed by extrusion, dryi...
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