Cordierite aluminum magnesium titanate compositions and ceramic articles comprising same

A technology of ceramic products and cordierite, which is applied in the field of composite ceramic compositions, and can solve problems such as failure to achieve thermodynamic equilibrium, high thermal expansion value, and microcracks

Inactive Publication Date: 2015-10-21
CORNING INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Second, the thermal expansion of AT is relatively low only at larger particle sizes, and microcracks form on cooling in the kiln
These large particles and microcracks tend to make the mechanical strength of the material lower
Third, microcracks cause thermal expansion curves with large hysteresis, resulting in very high instantaneous thermal expansion values, especially when cooling
However, cordierite and pure aluminum titanate cannot reach thermodynamic equilibrium at any temperature

Method used

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  • Cordierite aluminum magnesium titanate compositions and ceramic articles comprising same
  • Cordierite aluminum magnesium titanate compositions and ceramic articles comprising same
  • Cordierite aluminum magnesium titanate compositions and ceramic articles comprising same

Examples

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Embodiment approach

[0055] According to another example embodiment, the sintering aid may include cerium oxide (CeO 2 ) or cerium oxide with one or more other metal oxides such as Fe 2 TiO 5 ,Y 2 o 3 , and La 2 o 3 The combination. For example, the sintering aid may include a combination of ceria and yttrium oxide, a combination of ceria and lanthanum oxide, or a combination of ceria and yttrium oxide and lanthanum oxide. The inventors found that cerium oxide or cerium oxide and one or more other metal oxides such as Fe 2 TiO 5 A mixture of , yttrium oxide and lanthanum oxide gives similar CTE, porosity, pore size and pore size distribution, and the rare earth cost is lower than using yttrium oxide alone.

[0056] In an example embodiment, the amount of cerium oxide may range from 0.1 to 5.0 wt%. For example, the amount of cerium oxide may range from 0.2-2.0 wt%, 0.3-1.0 wt%, and 1.5-2.5 wt%. As noted above, in an example embodiment, cerium oxide and one or more other metal oxides such ...

Embodiment

[0058] The invention will be further described below with reference to some exemplary and specific embodiments of the invention, which are intended to be illustrative only and not intended to be limiting. According to some examples, a series of inventive ceramic articles were prepared having a basic inorganic batch composition as provided in Table 1 by weight percent of the final constituent phase, and in Table 2 by weight percent of a single component oxide. Compositions expressed in weight percent do not include any sintering additives.

[0059] Table 1

[0060]

[0061] Table 2

[0062]

[0063] Tables 3 through 11 and 13 provide data for examples of the invention made according to the basic compositions of Tables 1 and 2. The raw materials, porogens, and sintering aids used to make the samples are listed (median particle size in parentheses). These examples are provided by grinding the component powders with water and an organic binder, followed by extrusion, dryi...

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Abstract

Disclosed are ceramic bodies comprised of composite cordierite aluminum magnesium titanate ceramic compositions and methods for the manufacture of same.

Description

[0001] Cross References to Related Applications [0002] This application is a continuation-in-part of, and claims priority to, U.S. Patent Application Serial No. 13 / 676,567, filed November 14, 2012, which is a continuation-in-part of U.S. Patent Application Serial No. 13 / 584,993, filed August 14, 2012 application, the entire contents of the above two articles are incorporated herein by reference as if fully set forth herein. field of invention [0003] The present invention relates to ceramic compositions, and more particularly, to composite ceramic compositions comprising cordierite aluminum magnesium titanate. technical background [0004] Refractory materials with low thermal expansion and thus high thermal shock resistance are used in applications such as catalytic converter substrates and diesel particulate filters that generate high thermal gradients during use. One of the best materials for these applications is cordierite because of its low thermal expansion, high ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/478C04B38/00
CPCC04B35/478C04B35/632C04B38/00C04B38/0074C04B2235/3206C04B2235/3217C04B2235/322C04B2235/3222C04B2235/3225C04B2235/3227C04B2235/3229C04B2235/3234C04B2235/3236C04B2235/3272C04B2235/3418C04B2235/3445C04B2235/3463C04B2235/3481C04B2235/349C04B2235/5436C04B2235/6567C04B2235/661C04B2235/80C04B2235/9615C04B38/0051
Inventor A·M·迪文斯-道彻尔P·D·特珀谢E·M·维连诺G·A·默克尔R·R·伍斯利卡
Owner CORNING INC
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