High-clearing-point and high-refractive-index anisotropic negative liquid crystal composition and application thereof
A liquid crystal composition, high refractive index technology, applied in liquid crystal materials, nonlinear optics, optics, etc., can solve problems such as the risk of damage to the display, and achieve the effects of allowing time and cost, reducing pre-tilt angle, and effective manufacturing process
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preparation example Construction
[0185] The preparation method of the compound of general formula I:
[0186] Step 1) the compound of general formula Ia
[0187]
[0188] Carry out hydrogenation reaction, obtain the compound of general formula IIa
[0189]
[0190] Step 2) After reacting the compound of general formula IIa with p-bromophenol, triphenylphosphine, tetrahydrofuran and diethyl azodicarboxylate, the compound of general formula IIIa is obtained
[0191]
[0192] Step 3) combining the compound of general formula Ⅲa with the compound of Ⅳa
[0193]
[0194] Potassium carbonate, tetrakis (triphenylphosphine) palladium, toluene, ethanol and water react, obtain the negative liquid crystal compound of described general formula I
[0195]
[0196] in,
[0197] R 1 and R 2 The same or different, each independently represents H, an alkyl or alkoxy group with 1-10 carbon atoms, or an alkenyl or alkenyloxy group with 2-10 carbon atoms;
[0198] ring express or
[0199] n represents...
Embodiment 1
[0226] The liquid crystal composition of Example 1 was prepared by each compound listed in Table 3 and the weight percentage, which was filled between the two substrates of the liquid crystal display for performance testing. The test data are shown in the following table:
[0227] Table 3 liquid crystal composition formula and test performance thereof
[0228]
[0229]
Embodiment 2
[0235] The liquid crystal composition of Example 2 was prepared by each compound listed in Table 5 and the weight percentage, which was filled between the two substrates of the liquid crystal display for performance testing. The test data are shown in the following table:
[0236] Table 5 liquid crystal composition formula and test performance thereof
[0237]
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