Mobile phone case
A technology for mobile phone shells and plastic shells, which is applied to small shells, telephone structures, and other household appliances, etc., and can solve problems such as weak bonding between metal and plastic parts, non-abrasion resistance, drop resistance, and corrosion resistance
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[0033] The present invention simultaneously provides a preparation method for the above-mentioned mobile phone casing, comprising the following steps:
[0034] S1, anodize the surface of the pretreated metal shell body that needs to be combined with plastic parts to obtain a metal shell body with an oxide film layer with a pore size of 10-100 nm nanopores on the surface; anodic oxidation is an anodic well known to those skilled in the art Oxidation technology, the present invention may include putting the pretreated aluminum alloy as an anode into 10wt%-30wt% concentration of H2SO4, electrolysis at a temperature of 10-30°C for 1-40min at a voltage of 10V-100V to obtain a surface containing 1-10um thick For the aluminum alloy of the oxide film layer, the anodizing equipment adopts known anodizing equipment, such as an anodizing tank.
[0035] Among them, the metal shell body that needs anodized surface treatment can be part of the surface that needs to be combined with plastic ...
Embodiment 1
[0052] 1. Pretreatment: Cut the commercially available 1mm thick 5052 aluminum alloy shell body into a rectangular shell of 15mm*80mm (such as Figure 4 shown), put it into a polishing machine and grind it, and then wash it with absolute ethanol, then dip the aluminum alloy shell body in 40g / L sodium hydroxide aqueous solution, take it out after 2min and rinse it with deionized water to get Pre-treated aluminum alloy shell body;
[0053] 2. Surface treatment 1: Put the above-mentioned aluminum alloy shell body as an anode into an anodic oxidation tank containing H2SO4 with a concentration of about 20wt%, electrolyze it at 20V and 18°C for 10min, and dry it;
[0054] 3. Surface treatment 2: Prepare 500ml of 10wt% sodium carbonate (pH=12) in a beaker, soak the obtained aluminum alloy shell body in it at 20°C, take it out after 5min, put it in a beaker filled with water and soak for 1min , so that the cycle is 5 times, after the last water soaking, dry the aluminum alloy shell...
Embodiment 2
[0061] The same method as in Example 1 was used to prepare the mobile phone shell, except that the surface treatment 1 was to put the above-mentioned aluminum alloy shell body as an anode into an H2SO4 anodic oxidation tank containing about 20 wt% concentration, and electrolyze it at 15V and 18°C 10min, blow dry. Adopt the same method as claim 1 to measure the surface of the aluminum alloy shell body after electrolysis to make a 5um thick aluminum oxide film layer, which contains nano-micropores with a pore size of 20-40nm, and the pore depth of the nano-micropores It is 1um. It is measured that there are corrosion holes with a diameter of 300-1000nm on the surface of the main body of the aluminum alloy shell after soaking, and the depth of the corrosion holes is 4um. It can be observed that there are such as figure 1 The structure shown is similar to the double-layer three-dimensional hollow structure, and there are interconnected structures in the nanopores and corrosion p...
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