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A 125°C irradiation cross-linked PE cable material for UL high-temperature electronic wires and its preparation method

A technology of electronic wire and cable material, which is applied in the field of 125°C irradiation cross-linked PE cable material for UL high-temperature electronic wire and its preparation, which can solve the problem of high price, low flame retardant efficiency of flame retardant, and reduced tensile strength of cable material , elongation at break and other issues, to achieve the effect of low price, increased smoothness and excellent performance

Active Publication Date: 2017-01-11
HEBEI XINHAI GAOKE NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, domestic polyolefin cable materials mainly use inorganic hydroxides such as aluminum hydroxide, magnesium hydroxide, red phosphorus, and zinc borate as flame retardants. A certain flame retardant effect; as we all know, a large filling amount will inevitably reduce the mechanical properties such as tensile strength and elongation at break of the cable material
This problem has become a technical bottleneck for many domestic cable material manufacturers. UL high-temperature electronic wire manufacturers can only choose expensive imported cable materials to meet their own needs. How to solve the above problems has become an important research topic in the field of cable material production.

Method used

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  • A 125°C irradiation cross-linked PE cable material for UL high-temperature electronic wires and its preparation method
  • A 125°C irradiation cross-linked PE cable material for UL high-temperature electronic wires and its preparation method
  • A 125°C irradiation cross-linked PE cable material for UL high-temperature electronic wires and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] In Example 1: the weight parts of polyethylene A, polyethylene B, and ethylene-octene copolymer in the matrix resin are 12 parts, 17 parts, and 6 parts respectively; in the brominated flame retardant, decabromodiphenylethane The parts by weight of antimony trioxide and antimony trioxide are 22.5 parts and 7.5 parts respectively; the parts by weight of aluminum hydroxide and zinc borate in the inorganic flame retardant are 2.5 parts and 2.5 parts respectively; silicone masterbatch, The weight parts of polyethylene wax are 0.7 part and 0.3 part respectively; the main antioxidant and auxiliary antioxidant in the antioxidant are 0.3 part and 0.3 part respectively.

Embodiment 2

[0031] In Example 2: the weight parts of polyethylene A, polyethylene B, and ethylene-octene copolymer in the matrix resin are 16 parts, 22 parts, and 7 parts respectively; decabromodiphenylethane in the brominated flame retardant The parts by weight of antimony trioxide and antimony trioxide are 30 parts and 10 parts respectively; the parts by weight of aluminum hydroxide and zinc borate in the inorganic flame retardant are 4 parts and 4 parts respectively; the silicone masterbatch, The weight parts of the two polyethylene waxes are respectively 1.2 parts and 0.3 parts; the weight parts of the main antioxidant and the auxiliary antioxidant in the antioxidant are respectively 0.4 parts and 0.4 parts.

Embodiment 3

[0032] In Example 3: the weight parts of polyethylene A, polyethylene B, and ethylene-octene copolymer in the matrix resin are 17 parts, 23 parts, and 8 parts respectively; in the brominated flame retardant, decabromodiphenylethane The parts by weight of antimony trioxide and antimony trioxide are 33 parts and 11 parts respectively; the parts by weight of aluminum hydroxide and zinc borate in the inorganic flame retardant are 7.5 parts and 7.5 parts respectively; the silicone masterbatch, The weight parts of the two polyethylene waxes are respectively 1.2 parts and 0.4 parts; the weight parts of the main antioxidant and the auxiliary antioxidant in the antioxidant are respectively 0.5 parts and 0.5 parts.

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Abstract

The invention belongs to the preparation of cable materials and particularly relates to a PE cable material subjected to irradiation cross-linking at 125 DEG C for UL high-temperature electronic wire and preparation method of the PE cable material. The PE cable material is prepared from an effective amount of matrix resin, a compatilizer, a bromine flame retardant, an organic flame retardant, a silane coupling agent, a lubricants, an antioxidant, an anti-UV agent, and an irradiation crosslinking aid by virtue of carrying out surface activation treatment on the flame retardant, mixing in a mixer, granulating and the like, wherein the matrix resin comprises linear low-density polyethylene A, linear low-density polyethylene B and an ethylene-octene copolymer. By the preparation method, the defect that such mechanical properties as tensile strength and elongation at break of the cable material due to large filling amount of the flame retardant in the prior art can be inevitably reduced, the PE cable material has the advantages that the technical indicators such as tensile strength and elongation at break of the prepared electronic line are higher than the existing standard and the product has good flame retardant property and surface degree of finish, low cost and the like, and the situation that UL high-temperature electronic wire manufacturers can only use expensive imported cable materials to meet needs is broken.

Description

technical field [0001] The invention belongs to the preparation of cable materials, in particular to a 125°C irradiation cross-linked PE cable material for UL high-temperature electronic wires and a preparation method thereof. Background technique [0002] UL electronic wire is a general term for electronic wires that have passed UL certification. It is an electronic wire that meets the EU ROHS environmental protection requirements. It is generally used for weak current projects, such as internal connecting wires for electronics and electrical equipment. UL electronic wire has high requirements on the tensile strength, elongation at break, and fire resistance of cable materials. For example, the UL3173 high-temperature electronic wire standard stipulates that the tensile strength of cross-linked PE electronic wire irradiated at 125°C is ≥1.41 kgf / mm 2 , Elongation at break ≥ 300%, flame retardant passed the VW-1 test. At present, domestic polyolefin cable materials mainly ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/08C08L83/04C08L23/06C08K13/06C08K9/06C08K5/03C08K3/22C08K3/38H01B3/44
CPCC08K2201/005C08L23/0815C08L2201/02C08L2203/202C08L2205/025C08L2205/035C08L2312/06H01B3/441C08L51/06C08L83/04C08L23/06C08K13/06C08K9/06C08K5/03C08K3/2279C08K2003/2227C08K3/38C08K5/34922
Inventor 李兵任路宾胡广青
Owner HEBEI XINHAI GAOKE NEW MATERIAL TECH CO LTD
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