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Adhesive composition for resin-bonded wire saw and method for producing resin-bonded wire saw

A technology for bonding wires and adhesives, which is applied in the field of adhesive composition for resin-bonded wire saws and the manufacture of resin-bonded wire saws, can solve problems such as low holding force, reduced sharpness, and thinner wire diameters. Achieve the effects of small thickness deviation, thin damage layer, and high-efficiency uneven thickness

Inactive Publication Date: 2015-02-25
TKX
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the other hand, it is pointed out that due to the low holding power of the resin, the diamonds fall off one after another during the cutting process, the sharpness is easily reduced, the wire diameter is thinned, and the life is short.
In addition, when using a thermosetting resin adhesive, the curing cannot be carried out in a short time, and when it is carried out at a high temperature, there are failures such as foaming due to the decomposition of the curing agent and the volatile components accompanying the reaction. Therefore, there is a problem that the speed of wire saw manufacturing cannot be realized.

Method used

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  • Adhesive composition for resin-bonded wire saw and method for producing resin-bonded wire saw
  • Adhesive composition for resin-bonded wire saw and method for producing resin-bonded wire saw
  • Adhesive composition for resin-bonded wire saw and method for producing resin-bonded wire saw

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0081] Compounding ratio of adhesive composition for resin bonded wire saw

[0082] Novolac type phenolic resin composition (trade name: Shonol BRP-5417) 80 parts by weight

[0083] Details: Novolak type phenolic resin ((C 6 h 6 ·CH 2 O) n) 86% by weight, 5% by weight of phenol, 9% by weight of urotropine

[0084] Resole type phenolic resin composition (trade name: Shonol BRL-131) 20 parts by weight

[0085] Details: Resole phenolic resin ((C 6 h 6 ·CH 2 O)n) 80% by weight, 5.9% by weight of phenol, 0.6% by weight of formaldehyde, 1.2% by weight of NaOH, 12.2% by weight of moisture, 0.1% by weight of other additives

[0086] Amine-based silane coupling agent (trade name: SilaAce S330) 1 part by weight

[0087] (note: the compounding quantity of the novolac type phenolic resin in this compounding is 80 weight parts * 0.86=68.8 weight parts, the compounding quantity of the resol type phenolic resin is 20 weight parts * 0.80=16 weight parts. Therefore , In Example 1, abo...

Embodiment 2

[0094] Compounding ratio of adhesive composition for resin bonded wire saw

[0095] Novolac type phenolic resin composition (trade name: Shonol BRP-5417) 90 parts by weight

[0096] Resole type phenolic resin composition (trade name: Shonol BRL-131) 10 parts by weight

[0097] Amine-based silane coupling agent (trade name: SilaAce S330) 1 part by weight

[0098] Paste compounding ratio

[0099] Adhesive composition 100 parts by weight

[0100] Nickel-coated diamond abrasive (average particle size: 10-20 μm) 80 parts by weight

[0101] Filler (silicon carbide powder; #8000) 50 parts by weight

[0102] Solvent (o-cresol) 170 parts by weight

[0103] (Note: In Example 2, about 10.3 parts by weight of the resol-type phenolic resin were blended when converted in terms of ratios relative to 100 parts by weight of the novolak-type phenolic resin.)

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Abstract

[Problem] To provide: a method for efficiently producing a resin-bonded wire saw that stabilizes the step of cutting an ingot and that obtains a smooth wafer in which the thickness of a damaged layer on the wafer surface caused by cutting is small; and an adhesive composition for resin-bonded wire saws that is suitable for said method. [Solution] This method for producing a resin-bonded wire saw comprises: a step of applying, to the surface of a metal core wire, a paste including an adhesive composition, abrasive grains, and a solvent for dissolving the adhesive composition, said adhesive composition being used for producing resin-bonded wire saws in which abrasive grains are firmly fixed to the surface of a metal core wire by means of a resin bond, said adhesive composition for resin-bonded wire saws including, as essential components, 100 parts by weight of a novolac-type phenolic resin, 10-30 parts by weight of a resol-type phenolic resin, and 0.1-5 parts by weight of an amine-based silane coupling agent; and a heating step of heating the applied paste with infrared rays including near-infrared rays, and causing said adhesive composition to undergo a cross-linking reaction.

Description

technical field [0001] The present invention relates to solar cell / electronic substrates represented by wafers cut from large-diameter silicon ingots, compound semiconductor substrates such as gallium arsenide, or magnetic / optical components such as magnets, crystals, and glass. Fixed-abrasive wire saws used for cutting substrates, etc., especially related to fixed-abrasive wire saws suitable for precision cutting of hard and brittle materials, which relate to resin-bonded wire saws A method of manufacturing a wire saw bonded to a wire and an adhesive composition used in the manufacturing method. Background technique [0002] For the cutting of silicon ingots for TFT (thin film transistor) applications and solar cell applications, which have been increasing in diameter year by year, the inner peripheral sharpening stone (ID blade) that has been used has been pointed out to be low in processing efficiency and productivity, resulting in processing improvements. There are prob...

Claims

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Application Information

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IPC IPC(8): C09J161/06B24B27/06B24D3/20B24D11/00B28D5/04C09J11/06
CPCB23D65/00C08L2205/025C09J161/06B23D61/185B24D18/009B24B27/0633B24D3/20C09J11/06C08K5/544C08L61/06
Inventor 池内正彦远藤忠
Owner TKX
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