High-hardness scratch-resistant high-gloss modified polypropylene (PP) material
A polypropylene material, scratch-resistant technology, applied in the field of polymer materials, can solve problems such as poor appearance, improve mechanical strength, ensure service life, and improve gloss.
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Embodiment 1
[0024] 1. Take 46 parts of homopolypropylene and / or copolymerized polypropylene and 9.5 parts of polymethyl methacrylate, mix with 14 parts of compatibilizer, then treat with 0.5 part of coupling agent, mix and stir for 5-10 minutes and set aside. Described compatibilizer is maleic anhydride grafted polypropylene, and described coupling agent is titanate coupling agent;
[0025] 2. Add 15 parts of barium sulfate and 5 parts of modifier to the mixture treated with coupling agent, and mix at high speed for 5-10 minutes. The modifier is β(3,5-di-tert-butyl-4 -Hydroxyphenyl)propionate pentaerythritol, 2-(2'-hydroxy-3',5'bis(a,a-dimethylbenzyl)phenyl)benzotriazole, 2,2'-methylene Bis(4,6-di-tert-butylphenyl)sodium phosphate, ethylene oxide amine antistatic agent, N,N'-bis[β(3,5-di-tert-butyl-4-hydroxybenzene Base) the mixture of propionyl] hydrazine and terpolymer rubber, the diameter particle of described barium sulfate is 3000 orders;
[0026] 3. Through the twin-screw extruder...
Embodiment 2
[0029] 1. Take 60 parts of homopolypropylene and / or copolymerized polypropylene and 5 parts of polymethyl methacrylate, mix 9.3 parts of compatibilizer, and then treat with 0.2 parts of coupling agent, mix and stir for 5-10 minutes and set aside. The compatibilizer is maleic anhydride grafted polyethylene, and the coupling agent is a titanate coupling agent;
[0030] 2. Add 20 parts of barium sulfate and 0.5 parts of modifier to the mixture treated with coupling agent, and mix at high speed for 5-10 minutes. The modifier is 1,3,5-tris(3,5- Di-tert-butyl-4-hydroxybenzyl) 2,4,6-trimethylbenzene, 4,4'-butylenebis(6-tert-butyl-3-methylphenol), 2-(2'- Hydroxy-3',5'-di-tert-butylphenyl)-benzotriazole, 2,2'-methylene bis(4-tert-octyl-6-benzotriazole phenol), complex sorbitol Aldehyde nucleating agent 390, ANSTEX SA-8MB type antistatic agent, N,N'-bis[β(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl]-1,6-hexanedi A mixture of amine and POE, the particle size of the barium sulfate is 30...
Embodiment 3
[0034] 1. Take 40 parts of homopolypropylene and / or copolymerized polypropylene and 30 parts of polymethyl methacrylate, mix with 5.4 parts of compatibilizer, then treat with 0.6 parts of coupling agent, mix and stir for 5-10 minutes and set aside. The compatibilizer is maleic anhydride grafted polyethylene, and the coupling agent is a titanate coupling agent;
[0035] 2. Add 16 parts of barium sulfate and 2 parts of modifier to the mixture treated with coupling agent, and mix at high speed for 5-10 minutes. The modifier is 2,6-di-tert-butyl-4-methanol phenylphenol and bis(3,5-di-tert-butylphenyl)pentaerythritol diphosphite, [[3,5-di-tert-butyl-4-hydroxyphenyl]methyl]butylmalonate bis(1 ,2,2,6,6-pentamethyl-4-piperidinyl) ester, bis-2,2,6,6-tetramethylpiperidinol sebacate, β crystal nucleating agent, ANSTEX SA-8MB antistatic agent, N,N'-bis[β(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl]hydrazine, N,N'-bis[β(3,5- The mixture of di-tert-butyl-4-hydroxyphenyl) propionyl]-1,6-he...
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