Liquid crystal resin composition for camera module
A technology of resin composition and liquid crystallinity, which can be applied in television, electrical components, image communication, etc., can solve the problems of lowering the optical characteristics of camera modules, and achieve the effects of high dimensional stability, high mechanical strength, and warping deformation suppression
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[0057] The preparation of the (A) liquid crystalline resin used in the present invention can be carried out by the above-mentioned monomer compound (or monomer mixture) using direct polymerization method, transesterification method according to known methods, usually can use melt polymerization method, sludge pulp polymerization, etc. The above-mentioned compounds having ester-forming ability may be used in the polymerization as they are, or may be modified from a precursor to a derivative having the ester-forming ability in the previous stage of polymerization. In their polymerization, various catalysts can be used, and typical catalysts include dialkyltin oxides, diaryltin oxides, titanium dioxide, alkoxytitanosilicates, titanium alkoxides, carboxylate Alkali and alkaline earth metal salts of acids, BF 3 such as Lewis acid salts, etc. The amount of the catalyst used is generally preferably about 0.001 to 1% by mass, particularly preferably about 0.01 to 0.2% by mass, based...
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[0109] Hereinafter, although an Example is given and this invention is demonstrated in more detail, this invention is not limited to these Examples.
[0110]
[0111] Liquid crystal resin (liquid crystal polyester amide resin): VECTRA (registered trademark) E950i (manufactured by Polyplastics Co., Ltd.)
[0112] Fibrous filler 1: TISMO N-102 manufactured by Otsuka Chemical Co., Ltd. (potassium titanate fiber, average fiber diameter 0.3-0.6 μm, average fiber length 10-20 μm)
[0113] Fibrous filler 2: PF70E001 manufactured by Nitto Bosho Co., Ltd. (ground fiber, average fiber diameter: 10 μm, average fiber length: 70 μm)
[0114] Flaky filler 1: AB-25S manufactured by Yamaguchi Mica Industry Co., Ltd. (mica, average particle diameter: 24 μm)
[0115] Flaky filler 2: CROWNTALC PP manufactured by Matsumura Sangyo Co., Ltd. (talc, average particle diameter: 12.8 μm, average aspect ratio: 6)
[0116] Olefin-based copolymer: BOND FAST2C (ethylene-glycidyl methacrylate copolymer ...
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