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Thin polymer film preparation process

A technology of polymer film and preparation process, which is applied in the field of film manufacturing, and can solve problems such as alignment misalignment, difficulty, and device size deviation in the edge area

Active Publication Date: 2014-12-24
王磊 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The thick edge phenomenon will bring many problems to the subsequent electronic manufacturing process, such as the substrate warpage caused by the thick edge, the alignment misalignment of the edge area caused by the thick edge during the photolithography process, and the device size deviation, etc.
[0004] Although in the prior art, there are also measures to control the uniformity of the film, but to make the specific preparation process meet the needs of production is not the superposition of simple technical effects, but to meet the actual requirements of production, which can overcome the problem of thick edges and obtain uniformity. It is not easy to complete the thin film in a relatively short period of time. Often some processing methods meet one of the requirements but do not meet other requirements.

Method used

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Experimental program
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Effect test

Embodiment 1

[0029] combine figure 1 , describe in detail the preparation process of a polymer film of the present invention, including:

[0030] (1) Pre-coating, coating a polymer precursor solution on a carrier substrate to form a primary film. The polymer precursor solution in the step (1) of the present invention is a high-viscosity solution, and the viscosity range of the solution is 800cp-20000cp. For the viscosity range of the solution is 3000cp~5000cp, the technological effect of the present invention is better.

[0031] Specifically, the polymer precursor solution can be coated by blade coating, slit coating, spray coating or screen printing, and the thickness of the primary film is preferably 1 um to 1000 um.

[0032] After the pre-coating is completed, proceed to step (2).

[0033] (2) Centrifugal thick side adjustment, the carrier substrate in step (1) is transferred to the spin coating device together with the primary film coated thereon, and the spin coating device makes t...

Embodiment 2

[0044] In order to verify the effect of the present invention, two samples were prepared by the process of the present invention for performance research.

[0045] The specific preparation process of sample 1 is as follows:

[0046] (1) Select clean white glass as the carrier substrate, and use conventional cleaning process for cleaning.

[0047] (2) Scrape polyamic acid solution on white glass at a speed of 30mm / s to form a primary film. The viscosity of the polyamic acid solution is 3000cP, and the thickness of the primary film is about 0.5mm.

[0048] (3) Use a spin coating device to rotate at a speed of 500r / min for 12s, and then rotate at a speed of 1000r / min for 30s to adjust the centrifugal thickness.

[0049] (4) Send the primary film and the carrier substrate after the centrifugal thickening adjustment into the N 2 The polyamic acid primary film is cured and formed into a film in an oven in an atmosphere. The temperature control process of the oven is as follows: hea...

Embodiment 3

[0067] Adopt technology of the present invention to prepare sample 3, the concrete preparation process of sample 3 is as follows:

[0068] (1) Select clean white glass as the carrier substrate, and use conventional cleaning process for cleaning.

[0069] (2) Spray the polyamic acid solution on the white glass to form a primary film, the viscosity of the polyamic acid solution is 3200cP, and the primary film thickness is about 0.5mm.

[0070] (3) Use a spin coating device to rotate at a speed of 600r / min for 10s, and then rotate at a speed of 1000r / min for 25s to adjust the centrifugal thickness.

[0071] (4) The primary film and the carrier substrate adjusted by centrifugal thickening are sent as a whole into an oven with an inert gas argon atmosphere to solidify the primary film of polyamic acid to form a film. The temperature control process of the oven is as follows: heat preservation at 80°C for 30 minutes, heat preservation at 200°C for 30 minutes, heat preservation at 3...

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Abstract

A thin polymer film preparation process includes the steps of firstly, conducting pre-coating, wherein a carrier substrate is coated with a polymer precursor solution to form a primary body film; secondly, adjusting the thick centrifugal edge, wherein the carrier substrate is made to do high-speed centrifugal movement through a spin coating device, the solution on the thick edge portion of the primary body film is thrown out in the centrifugation process, and the edge of the primary body film on the carrier substrate is thinned; thirdly, solidifying the primary body film with the centrifugal thick edge adjusted in the second step and the carrier substrate together, and separating the thin film and the carrier substrate which are solidified to obtain a self-supported finished thin polymer film. The polymer precursor solution in the first step is a high-viscosity solution, wherein the viscosity of the solution ranges from 800 cp to 20000 cp. The centrifugal rotating speed of a centrifugation device in the second step ranges from 100 r / min to 10000 r / min, and the levelness of a centrifugation platform is smaller than 5 mm / m. The thin polymer film preparation process can effectively solve the thick edge problem generated in the film formation process of the high-viscosity polymer solution, and film forming uniformity is improved.

Description

technical field [0001] The invention relates to the technical field of film manufacture, in particular to a preparation process of a polymer film. Background technique [0002] Polymer films are widely used in the field of precision electronics manufacturing, such as flat panel displays, photovoltaic cells, and communication equipment, due to their advantages such as good toughness, high temperature resistance, and excellent insulation. A common way to prepare polymer films is to coat a polymer solution on a mold, cure the solution into a film, and finally release the film from the mold. The commonly used coating method is knife coating, but this process has the defect of uneven coating of polymer film. [0003] In the scraping process, the scraping solution flows to the edge of the scraper under the action of gravity, and the scraper moves relative to the carrier substrate so that the scraping solution forms a rectangular liquid film on the carrier substrate along with the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/18C08J5/18
CPCC08J5/18C08J2379/08C08L79/08C08L2203/16
Inventor 王磊许志平邹建华徐苗陶洪彭俊彪
Owner 王磊
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