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Conductive heat-conductive graphene slurry and coating

A technology of electrical and thermal conductivity and graphene, applied in the field of materials, can solve the problems of low resistance, poor chemical stability, and low aspect ratio, and achieve the effects of increased overall adhesion, high resin content, and reduced pollution

Inactive Publication Date: 2014-11-26
SUPERCDONGGUAN TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Conductive carbon black, graphite, conductive mica, metals (gold, silver, copper, nickel), and carbon fiber are the traditional conductive and thermal conductive materials currently used in the mainstream of conductive coatings. Carbon materials have the characteristics of good chemical stability and small particles, which can effectively However, because carbon black is an amorphous spherical carbon structure with a low aspect ratio, although it forms a conductive network, the network interface is point-to-point contact, so the resistance value is still relatively high. Higher than graphite; graphite is another mainstream conductive material, which has excellent chemical stability like carbon black, but its particle size is much larger than carbon black and its aspect ratio is not high. Therefore, under the same addition amount, It is difficult to form a complete conductive network like carbon black; in electronics, LED, solar energy and other industries, the mainstream conductive materials used are metal (gold, silver, copper, nickel) materials, whose electrical and thermal conductivity are better than carbon materials, but Poor chemical stability (copper, nickel), and expensive (gold, silver); carbon nanotubes and nanocarbon fibers are relatively new types of conductive materials, which have lower resistance values ​​and higher aspect ratios than graphite, theoretically It should have the best electrical conductivity, but its disadvantages such as difficulty in dispersing, low purity, metal pollution, and high price greatly increase the difficulty in practical use, which has become the reason why this type of conductive material has not been popularized in large quantities

Method used

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  • Conductive heat-conductive graphene slurry and coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A kind of conductive and heat-conducting graphene slurry and coating thereof, concrete preparation is as follows:

[0032] Take few-layer graphene: 5.3g, epoxy resin E51: 50.0g, organic solvent: 50.0g, after high-speed mixing, stirring, and cleavage, a conductive and heat-conducting graphene slurry is prepared and set aside.

[0033] Take the above-mentioned graphene slurry: 12.8g, 25.0g, 37.5g, 50g; E51 epoxy resin: 50.0g, 45g, 42g, 38g; curing agent EN125: 50g, 45g, 42g, 38g; talcum powder: 20g; Leveling agent: 0.1g; coupling agent: 0.1g; appropriate amount of organic solvent; high-speed mixing uniformly to prepare conductive and thermally conductive coatings.

[0034] Apply the paint, wait for the film to dry, and test the resistivity (see figure 1 ).

Embodiment 2

[0036] A kind of conductive and heat-conducting graphene slurry and coating thereof, concrete preparation is as follows:

[0037] Take few-layer graphene: 5.3g; polyester polyol 1200: 50.0g; organic solvent: 50.0g; after high-speed mixing, stirring, and cleavage, a conductive and thermally conductive graphene slurry is prepared for future use.

[0038] Take the above-mentioned few-layer graphene slurry: 2.8g, 25.0g, 37.5g, 50g; polyester polyol 1200: 50.0g, 45g, 42g, 38g; curing agent N3390: 50g, 45g, 42g, 38g; talcum powder : 20g; leveling agent: 0.1g; coupling agent: 0.1g; appropriate amount of organic solvent mixed evenly at high speed to prepare conductive and thermally conductive coating.

[0039] Apply the paint, wait for the film to dry, and test the resistivity (see figure 2 ).

Embodiment 3

[0041] A kind of conductive and heat-conducting graphene slurry and coating thereof, concrete preparation is as follows:

[0042] Take few-layer graphene: 5.3g; hydroxyacrylic acid A160: 50.0g; organic solvent: 50.0g, mix and stir at a high speed, and cleavage to prepare a conductive and thermally conductive graphene slurry for future use.

[0043] Take the above slurry: 12.8g, 25.0g, 37.5g, 50g; hydroxyacrylate A160: 83.3g, 75g, 70g, 63.3g; curing agent N3390: 50g, 45g, 42g, 38g; talcum powder: 20g; Leveling agent: 0.1g; coupling agent: 0.1g; organic solvent: appropriate amount; high-speed mixing evenly; high-speed mixing evenly to prepare a conductive and thermally conductive coating.

[0044] Apply the paint, wait for the film to dry, and test the resistivity (see image 3 ).

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PUM

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Abstract

The invention relates to a conductive heat-conductive graphene slurry and a coating. The conductive heat-conductive graphene slurry comprises the following raw materials: 0.1-90wt% of conductive heat-conductive graphene slurry ( consisting of 3-20wt% of less graphene, 0-80wt% of base solvent, 0-80wt% of base resin), 0-60wt% of filler, 0-10% of dispersing agent, 10-60wt% of resin, 10-60wt% of curing agent, and 30-70wt% of solvent, wherein not only can the graphene slurry be antistatic, conductive and heat-conducting despite of less addition amount, but also the surface of a coated article is smoother and finer, firmer and more durable; compared with the addition amount of the existing conductive material, the conductive heat-conductive graphene slurry is lower in addition amount and can also reach lower resistivity.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to a conductive and thermally conductive graphene slurry and coating. Background technique [0002] Conductive and heat-conductive coating is a kind of functional material that has emerged with the rapid development of coating industry and modern industry in recent years. The film-forming substrate is generally insulating. In order to make the coating have electrical and thermal conductivity, the common method is to add conductive and thermal particles. Conductive and thermally conductive coatings have important practical value in the electronics industry, automobile industry, storage and transportation of natural gas and oil products, aerospace and other aspects. [0003] Conductive carbon black, graphite, conductive mica, metals (gold, silver, copper, nickel), and carbon fiber are the traditional conductive and thermal conductive materials currently used in the mai...

Claims

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Application Information

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IPC IPC(8): C08J3/09C08L63/00C08L67/00C08L33/00C08K3/04C09D163/00C09D175/06C08G18/42C09D175/04C08G18/62C09D5/24C09D7/12
Inventor 何斌李琦蔡庆荣
Owner SUPERCDONGGUAN TECH
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