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Low-energy-consumption oxygen-enriched combustion system coupling solar energy and chemical loop air separation

A technology coupled with solar energy and oxygen-enriched combustion, applied in solar thermal power generation, combustion equipment, combustion methods, etc., can solve problems such as high energy consumption of the system, lower efficiency of the oxygen-enriched combustion system, and less oxygen production, and achieve easy capture , Avoid flue gas recirculation loop, improve efficiency

Active Publication Date: 2014-10-15
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The current oxyfuel combustion system using chemical looping air separation technology usually passes the recirculated flue gas into the oxygen release reactor to produce a mixed gas rich in oxygen and carbon dioxide, but this system often requires more external heat to maintain oxygen release The required temperature conditions in the reactor and the oxygen absorbing reactor make the energy consumption of the system high. In addition, because the flue gas passed into the oxygen releasing reactor already contains a certain amount of oxygen, it is easier to achieve the balance of oxygen absorbing and releasing oxygen. The amount of oxygen produced is small, which is difficult to meet the needs of oxygen-enriched combustion; there are also some oxygen-enriched combustion schemes that use chemical looping air separation technology to extract part of the steam from the steam turbine of the oxygen-enriched combustion unit as the fluidized gas of the oxygen release reactor, but this way will significantly reduce the efficiency of the oxyfuel combustion system

Method used

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  • Low-energy-consumption oxygen-enriched combustion system coupling solar energy and chemical loop air separation
  • Low-energy-consumption oxygen-enriched combustion system coupling solar energy and chemical loop air separation
  • Low-energy-consumption oxygen-enriched combustion system coupling solar energy and chemical loop air separation

Examples

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Effect test

Embodiment 1

[0050] The low-energy oxygen-enriched combustion system coupled with solar energy and chemical looping air separation technology of this example includes a dry steam production unit 1, a chemical looping air separation unit 3 and an oxygen-enriched combustion unit 4, and the dry steam production unit 1 is used to produce The dry steam required for the reaction is taken, the chemical looping air separation unit 3 is used to separate high-purity oxygen, and the oxygen-enriched combustion unit 4 is used for oxygen-enriched combustion and the capture of carbon dioxide. The oxygen carrier used is a copper-based oxygen carrier.

[0051] The dry steam production device 1 includes a solar heat collector 5, a steam generator 6 and a flow divider 2. The water fed into the steam generator 6 generates dry steam under the action of the heat of the solar heat collector 5, and the dry steam passes through the flow divider for 2 minutes. It is two streams: one dry steam F enters the chemical l...

Embodiment 2

[0055] This example includes dry steam production unit, chemical looping air separation unit, conventional air separation unit and oxygen-enriched combustion unit, and its difference with embodiment one is that this system also includes conventional air separation unit, conventional air separation unit and chemical The chain air separation unit together provides the high-purity oxygen required by the oxyfuel combustion unit.

[0056] Using the oxygen-enriched combustion system described in this embodiment, realizing a clean and low-energy-consumption oxygen-enriched combustion method mainly includes the following steps:

[0057] a) Utilize the trough type solar heat collector 5 to collect solar energy, the steam generator 6 utilizes the collected solar energy to produce dry steam, the dry steam is divided into two strands through the splitter 2, and one strand of dry steam F enters the chemical chain air separation unit 3 As the fluidizing gas in its oxygen release reactor 10,...

Embodiment 3

[0064] In this example, dry steam is produced by using a solar dry steam production device, and the circulating flue gas and dry steam are put into the oxygen release reactor of the chemical looping air separation system as fluidization gas, and the oxygen partial pressure is controlled to produce oxygen-enriched mixed gas. It then goes into the boiler unit where it reacts with the fuel.

[0065] a) Utilize the trough solar collector 5 to collect solar energy, and the steam generating device 6 utilizes the collected solar energy to produce dry steam, and the dry steam is divided into two streams through the splitter 2, and one stream of dry steam F passes through the mixer 18 and the circulating smoke Gas mixing enters the chemical looping air separation unit 3 as the fluidization gas in its oxygen release reactor 10, and another stream of dry steam 1 enters the oxygen-enriched combustion unit;

[0066] b) The fluidization gas of the oxygen absorption reactor 8 is air, and the...

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Abstract

The invention discloses a low-energy-consumption oxygen-enriched combustion system coupling solar energy and chemical looping air separation. The system comprises a dry steam preparing device, a chemical looping air separation device and an oxygen-enriched combustion device. The dry steam preparing device comprises a solar thermal collector, a steam generator and a distributor. Dry steam generated by the dry steam preparing device is divided into two parts by the distributor, one part of the dry steam enters the chemical looping air separation device to serve as the fluidization gas of an oxygen suction reactor, and the other part of the dry steam enters the oxygen-enriched combustion device. High-purity oxygen generated by the chemical looping air separation device enters the oxygen-enriched combustion device to be mixed with the dry steam and fuel for mixed combustion, and high-purity carbon dioxide is acquired by simply condensing and separating combustion products. The low-energy-consumption oxygen-enriched combustion system has the advantages that the dry steam prepared by solar energy can be used as the fluidization gas of the chemical looping air separation device and can also be fed into the oxygen-enriched combustion device to participate in combustion reaction, smoke recycling loops are reduced, energy consumption of the oxygen-enriched combustion system is lowered, and system efficiency is increased.

Description

technical field [0001] The invention belongs to the technical field of oxygen-enriched combustion, and more specifically relates to a low-energy-consumption oxygen-enriched combustion system based on coupled solar energy and chemical chain air separation technology. Background technique [0002] Since the industrial revolution, due to the needs of industrial development, a large amount of fossil fuels have been used, causing the concentration of carbon dioxide in the atmosphere to rise continuously and rapidly, seriously affecting the global environment. Aiming at the global issue of carbon dioxide emission reduction, many countries have proposed their own research plan. Among them, oxygen-enriched combustion technology, as one of the carbon dioxide capture technologies, can rely on the existing traditional coal-fired power plants and has a good development prospect. [0003] Oxygen-enriched combustion technology is a high-efficiency cleaning technology that uses high-conce...

Claims

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Application Information

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IPC IPC(8): F23L7/00F22B1/00F24J2/00C01B13/02
CPCY02E10/40Y02E20/34Y02P20/133
Inventor 赵海波邹希贤金波郑楚光
Owner HUAZHONG UNIV OF SCI & TECH
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