Adhesive composition and adhesive sheet
A technology of adhesives and compositions, applied in the direction of adhesive types, ester copolymer adhesives, polymer adhesive additives, etc., can solve the problem of not obtaining antistatic properties, re-peelable appearance characteristics, and difficult to deal with Surface protection film improvement requirements and other issues, to achieve the effect of excellent adhesion
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Embodiment 1
[0257] (Preparation of Acrylic Emulsion Polymer)
[0258] Mix 90 parts by weight of water, 92 parts by weight of 2-ethylhexyl acrylate (2EHA), 4 parts by weight of acrylic acid (AA), and 4 parts by weight of methyl methacrylate (MMA) as shown in Table 1. 2 parts by weight of a nonionic anionic emulsifier (manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd., trade name "Aquaron HS-1025") was stirred and mixed with a high-speed mixer to prepare a monomer emulsion.
[0259] Then, 50 parts by weight of water and 0.07 parts by weight of a polymerization initiator (ammonium persulfate) were added to a reaction vessel having a condenser tube, a nitrogen gas introduction tube, a thermometer, and a stirrer, and after heating to 75° C., the mixture was stirred under a nitrogen atmosphere. , The above-mentioned monomer emulsion was added over 3 hours, and then emulsion polymerization was performed at 75° C. for 3 hours. Then, it was cooled to 30° C., and the pH was adjusted to 8 by a...
Embodiment 2~8、 comparative example 1~3
[0265] As shown in Table 1, a PSA composition and a PSA sheet were obtained in the same manner as in Example 1, changing the type and compounding amount of the raw material monomers, nonionic surfactant (acetylene glycol-based compound), and the like. In addition, about the additive which is not described in a table|surface, it prepared with the same compounding quantity as Example 1.
[0266] [Evaluation]
[0267] The water-dispersed acrylic pressure-sensitive adhesive compositions and pressure-sensitive adhesive sheets obtained in Examples and Comparative Examples were evaluated by the following measurement methods or evaluation methods. In addition, the evaluation results are shown in Table 2.
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