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A kind of building thermal insulation airgel material and preparation method thereof

A technology of building thermal insulation and airgel, which is applied in the field of building thermal insulation materials, can solve the problems of low strength, high cost, and complicated preparation process of airgel, and achieve the effects of good strength, high porosity, and simple production process

Active Publication Date: 2016-06-29
陕西睿智环保建材有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Aiming at the defects of low airgel strength, complicated preparation process and high cost at present, the present invention provides a building thermal insulation airgel material that can be used in the field of building energy saving

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 1) Add 60 parts by weight of methyl orthosilicate and 20 parts by weight of ethylene glycol into the container and stir for 10 minutes, add 10 parts by weight of methyltriethoxysilane, add 10 parts of water, stir for 3 minutes, add hydrochloric acid Adjust the pH of the solution to 5, set the oil temperature in the container to 100°C and continue to stir and hydrolyze for 60 minutes to obtain a silica sol;

[0033]2) Grinding and modifying 80 parts of polyvinyl alcohol 1788, 10 parts of glycerin, 2 parts of polyethylene glycol-2000, and 1 part of borax to obtain polyvinyl alcohol hot melt adhesive powder;

[0034] 3) Add 10 parts by weight of polyvinyl alcohol hot melt adhesive powder and 2 parts of ethylene glycol (dioctyl pyrophosphate) titanium to 88 parts of silica sol solution, add triethanolamine to adjust the pH value to 10, stir evenly, and The polyvinyl alcohol hot melt adhesive powder is evenly dispersed in the wet gel, and then placed in a closed aging tank f...

Embodiment 2

[0040] 1) Add 55 parts by weight of tetraethyl orthosilicate and 20 parts by weight of ethylene glycol into the container and stir for 10 minutes, add 10 parts by weight of methyltriethoxysilane, add 15 parts of water, stir for 3 minutes, add hydrochloric acid Adjust the pH of the solution to 5, set the oil temperature in the container to 100°C and continue to stir and hydrolyze for 50 minutes to obtain a silica sol;

[0041] 2) Grinding and modifying 90 parts of polyvinyl alcohol 1788, 5 parts of glycerin, 2 parts of polyethylene glycol-2000, and 3 parts of succinic acid to obtain polyvinyl alcohol hot melt adhesive powder;

[0042] 3) Add 25 parts of polyvinyl alcohol hot melt adhesive powder and 2 parts of isopropoxytri(dioctyl pyrophosphate)titanium to 73 parts of silica sol solution, add triethanolamine to adjust the pH value to 10, stir evenly, and The polyvinyl alcohol hot melt adhesive powder is evenly dispersed in the wet gel, and then placed in a closed aging tank fo...

Embodiment 3

[0049] 1) Add 50 parts by weight of tetraethyl orthosilicate and 25 parts by weight of ethylene glycol into the container and stir for 5 minutes, add 5 parts by weight of methyltriethoxysilane, add 10 parts of water, stir for 3 minutes, add hydrochloric acid Adjust the pH of the solution to 5, set the oil temperature in the container to 100°C and continue to stir and hydrolyze for 30 minutes to obtain a silica sol;

[0050] 2) 85 parts of polyvinyl alcohol 1788, 8 parts of glycerin, 4 parts of polyethylene glycol-2000, and 3 parts of adipic acid were modified by grinding to obtain polyvinyl alcohol hot melt adhesive powder;

[0051] 3) Add 20 parts of polyvinyl alcohol hot melt adhesive powder and 2 parts of isopropoxytri(dioctyl pyrophosphate)titanium to 78 parts of silica sol solution, add triethanolamine to adjust the pH value to 9, stir evenly, and The polyvinyl alcohol hot melt adhesive powder is evenly dispersed in the wet gel, and then placed in a closed aging tank for ...

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Abstract

A building thermal insulation airgel material and a preparation method thereof. The building thermal insulation airgel material is characterized in that the raw material composition (parts by weight) is: 70-90 parts of silica sol, 10-28 parts of polyvinyl alcohol hot melt adhesive, and 1-2 parts of hydrophobic agent. The present invention takes silica sol as the main body, polyvinyl alcohol hot-melt adhesive as thermoplastic melt colloid, and inert gas as support body, through the instantaneous high temperature and high pressure of the continuous kneading screw reactor, the gel is in the extrusion cylinder Extruded, the liquid component in the wet gel expands due to instantaneous evaporation at the die mouth, and the inert gas acts as the airgel support while the liquid component volatilizes, ensuring that the airgel’s complete skeleton structure does not collapse, and the process is completed Transformation of wet gels to aerogels. The preparation process of the invention avoids the complex process of the supercritical drying method, and also avoids the defect of airgel channel collapse during normal pressure drying. The production process is simple, the operation is stable, and it can be produced continuously on a large scale. The airgel obtained has good strength, high porosity, and excellent thermal insulation performance, and can be applied to the fields of building insulation boards, insulation mortars, and insulation coatings.

Description

technical field [0001] The invention relates to the field of building thermal insulation materials, in particular to a building thermal insulation airgel material and a preparation method. Background technique [0002] Energy problems in today's world have become a major issue affecting development. Since building energy consumption accounts for 30% to 40% of the total energy consumption, building energy conservation is of great significance. Building thermal insulation materials are an important measure for building energy conservation. At present, the most widely used form of thermal insulation in the domestic market is external wall insulation. Due to the low thermal conductivity of organic thermal insulation materials and good thermal insulation performance, they are currently widely used in building energy conservation. However, organic thermal insulation materials have various disadvantages, such as the use of petroleum resources as raw materials, poor environmental pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/24
CPCC04B28/24C04B2111/28
Inventor 陈庆曾军堂
Owner 陕西睿智环保建材有限公司
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