High energy density lithium ion power battery
A high energy density, power battery technology, applied in the direction of battery electrodes, secondary batteries, non-aqueous electrolyte batteries, etc., can solve the problem that the energy density has not been improved better, the charge and discharge cut-off voltage cannot be broken through, and the limitation of lithium-ion power batteries Application and other issues, to achieve the effect of improving cycle performance at room temperature and high pressure
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[0030] 24 Preparation of:
[0031] (1) Take a certain amount of silicon powder with a particle size of 0.1-5μm, press Si-SnC 2 o 4 Medium Si and SnC 2 o 4 The mass ratio is 1-10:1 to calculate and take the required amount of soluble stannous salt, dissolve silicon powder and soluble stannous salt (stannous chloride or stannous sulfate) in water, stir evenly, and obtain a suspension , dissolving soluble oxalate (potassium oxalate, sodium oxalate or ammonium oxalate) in water to obtain a soluble oxalate solution;
[0032] (2) According to the molar ratio of soluble stannous salt to soluble oxalate is 1:1-1.3, pour the soluble oxalate solution into the suspension and adjust the pH of the whole reaction system to 0.5-3, and keep stirring for 1 -3h, to obtain the reaction solution;
[0033] (3) Separating the reaction liquid from solid to liquid, and washing the obtained solid with water and drying it at a temperature of 80-100°C to obtain Si-SnC 2 o 4 .
[0034] Prepar...
Embodiment 1
[0048] Prepare the positive electrode sheet: mix 92 parts by weight of high-nickel high-capacity ternary material (Li 1.04 Ni 0.8 co 0.15 Al 0.05 o 2 ), 2 parts by weight of conductive carbon black SP, 2 parts by weight of carbon nanotubes (CNT), and 4 parts by weight of polyvinylidene fluoride (PVDF), and added 80 parts by weight of N-N-dimethylpyrrolidone and stirred to form a slurry , uniformly coated on the calendered aluminum foil of the positive electrode base fluid, and rolled with a rolling machine after drying to make the positive electrode sheet.
[0049] Prepare the negative electrode sheet: mix 90 parts by weight of the C-Sn-Si high-capacity composite material (Si-SnC 2 o 4 ), 2 parts by weight of conductive carbon black SP and 8 parts by weight of polyvinylidene fluoride (PVDF), and add 140 parts by weight of N-N-dimethylpyrrolidone and stir to form a slurry, which is evenly coated on the negative electrode base fluid electrolytic copper foil After drying, i...
Embodiment 2
[0056] Prepare the positive electrode sheet: mix 92 parts by weight of high-nickel high-capacity ternary material (Li 1.04 Ni 0.8 co 0.15 Al 0.05 o 2 ), 2 parts by weight of conductive carbon black SP, 2 parts by weight of carbon nanotubes (CNT), and 4 parts by weight of polyvinylidene fluoride (PVDF), and added 80 parts by weight of N-N-dimethylpyrrolidone and stirred to form a slurry , uniformly coated on the calendered aluminum foil of the positive electrode base fluid, and rolled with a rolling machine after drying to make the positive electrode sheet.
[0057] Prepare the negative electrode sheet: mix 92 parts by weight of C-Sn-Si high-capacity composite material (Si-SnC 2 o 4 ), 2 parts by weight of conductive carbon black SP and 6 parts by weight of polyacrylic acid, and add 130 parts by weight of deionized water to stir to form a slurry, which is evenly coated on the negative electrode base fluid electrolytic copper foil, and after drying, use a roller compactor ...
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