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A self-biased heterogeneous microwave ferromagnetic thin film material and its preparation method

A ferromagnetic thin film and heterogeneous technology, which is applied in the field of self-biased heterogeneous microwave ferromagnetic thin film materials and its preparation, can solve the problems of uneven film thickness and affecting the use of the film, so as to overcome the uneven thickness and operation The effect of convenience and simple preparation method

Active Publication Date: 2016-08-17
QINGDAO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Magnetic field heat treatment or magnetic field in-situ deposition methods are widely used, but the obtained magnetic anisotropy field is small, usually less than 50Oe, which makes the ferromagnetic resonance frequency of the film generally lower than 3GHz [see literature [8] S.X.Wang, N.X.Sun , M.Yamaguchi, and S.Yabukami, Nature, vol.407(2000) 150–151; [9] J.Shim, J.Kim, S.H.Han, H.J.Kim, K.H.Kim, and M.Yamaguchi, J.Magn .Magn.Mater.,290–291(2005)205–208;[10]C.J.Jiang,D.S.Xue,D.W.Guo,and X.L.Fan,J.Appl.Phys.,106(2009)103910;[11] J.C.Sohn, D.J.Byun, and S.H.Lim, J.Magn.Magn.Mater.,272–276(2004)1500–1502.]; Inclined sputtering and target sputtering can obtain a magnetic anisotropy field of 200-300Oe , but the thickness of the film is not uniform, which seriously affects the use of the film ; [13] W.D.Li, O.Kitakami, and Y.Shimada, J.Appl.Phys., 83(1998) 6661; [14] E.Yu, J.S.Shim, I.Kim, J.Kim, S.H.Han, H.J.Kim, K.H.Kim, and M.Yamaguchi, IEEE Trans. Magn., 41(2005) 3259–3261; [15] A.Iljinas, J.Dudonis, R. andA. Nonlinear Analysis Modeling and Control,10(2005)57–64.]; the exchange coupling between ferromagnetic-antiferromagnetic or ferromagnetic-ferromagnetic thin films can generate a large magnetic anisotropy field, but the exchange coupling It often only occurs between extremely thin films, and it is difficult for the film to achieve a practical thickness [see literature [9] J.Shim, J.Kim, S.H.Han, H.J.Kim, K.H.Kim, and M.Yamaguchi, J.Magn .Magn.Mater., 290–291(2005) 205–208; [16] M.Sonehara, T.Sugiyama, T.Sato, K.Yamasawa, and Y.Miura, IEEE Trans.Magn., 41(2005) 3511–3513; [17] C.Pettiford, A.Zeltser, S.D.Yoon, V.G.Harris, C.Vittoria, and N.X.Sun, IEEE Trans. Magn., 42(2006) 2993–2995; [18] H.Le Gall , J. Ben Youssef, N. Vukadinovic, and J. Ostorero, IEEE Trans. Magn., 38(2002) 2526–2528.]

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] Embodiment 1: (Fe 70 co 30 )x -B y Heterogeneous Ferromagnetic Thin Film Materials

[0011] In this example, Fe 70 co 30 It is a ferromagnetic parent material target, B is used as a doping element target, and a single crystal Si substrate with a length of 5 cm x 1 cm is used as a substrate. The length direction of the substrate is along the radial direction of the circular sample turntable. The single crystal Si substrate facing Fe 70 co 30 target, so that from Fe 70 co 30 The Fe and Co elements of the target are evenly distributed on the substrate; the distance between the target position of the B target and the end of the substrate center is 5-10cm and adjustable, so that the concentration of the B element from the B target is on the substrate from the center of the sample turntable to The edge gradually increases; adjusting the distance L of the B target position away from the sample center can adjust the B element distribution concentration range on the Si s...

Embodiment 2

[0012] Embodiment 2: (Fe 70 co 30 ) x -Hf y Heterogeneous Ferromagnetic Thin Film Materials

[0013] In this example, Fe 70 co 30 is the ferromagnetic parent material target, Hf is used as the doping element target, and the ferromagnetic parent material target Fe 70 co 30 and the sputtering power of the doped Hf target were set to 80 and 16W respectively, and the sputtering time was 30 minutes, and all the other conditions were the same as in Example 1 to obtain (Fe 70 co 30 ) x -Hf y A heterogeneous ferromagnetic thin film material, the hard axis of the heterogeneous thin film material is along the length direction of the substrate, the magnetic anisotropy field is as high as 360Oe, and the self-biased ferromagnetic resonance frequency is 5.2GHz.

Embodiment 3

[0014] Embodiment 3: (Fe 50 co 50 ) x -(Al 2 o 3 ) y Heterogeneous Ferromagnetic Thin Film Materials

[0015] In this example, Fe 50 co 50 is the ferromagnetic parent material target, with Al 2 o 3 For the doping element target, the ferromagnetic parent material target Fe 50 co 50 and doped Al 2 o 3 The sputtering power of the target is set to 80 and 120W respectively, and the sputtering time is 30 minutes, and all the other conditions are identical with embodiment 1, can obtain (Fe 50 co 50 ) x -(Al 2 o 3 ) y Heterogeneous ferromagnetic thin film material. The hard axis of the heterogeneous thin film material is along the length direction of the substrate, the magnetic anisotropy field is as high as 350Oe, and the self-biased ferromagnetic resonance frequency is 5.1GHz.

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Abstract

The invention belongs to the technical field of microwave ferromagnetic materials, and relates to a self-biased non-homogeneous microwave ferromagnetic thin film material and a preparation method thereof. The preparation method includes the steps that at room temperature, a ferromagnetic base material M is used as a ferromagnetic mother material target, a doping element D is used as a doping element target, a single-crystal Si substrate is used as a substrate, the length direction of the substrate is the radial direction of a round sample rotary disc, the substrate directly faces the ferromagnetic mother material target, the target position of the doping element target is deviated from one end of the center of the substrate by 5-10cm, after the vacuum pressure of a magnetron sputtering vacuum chamber is lower than 5.0*10-6 Torrs, Ar gas or N2 gas is led into the magnetron sputtering vacuum chamber for sputtering, and then the self-biased non-homogeneous microwave ferromagnetic thin film material is obtained. The preparation method of the self-biased non-homogeneous microwave ferromagnetic thin film material is simple and convenient to operate, and the prepared thin film material is stable in performance, high in ferromagnetic resonance frequency and wide in application range.

Description

Technical field: [0001] The invention belongs to the technical field of microwave ferromagnetic materials, and relates to a heterogeneous ferromagnetic thin film material and a preparation process thereof, in particular to a self-biased heterogeneous microwave ferromagnetic thin film material and a preparation method thereof. Background technique: [0002] At present, ferromagnetic thin film materials are widely used in RF / microwave components such as DC-DC converters, filters, phase shifters, isolators and couplers [see literature [1] C.S.Kim, S.Bae, H.J.Kim , S.E.Nam, H.J.Kim, IEEE Trans.on Magn., 37(2001) 2894-2896; [2] M.Yamaguchi, K.Yamada, and K.H.Kim, IEEE Trans.on Magn., 42(2006) 3341- 3343; [3] Y. Hayakawa, A. Makino, H. Fujimori, and A. Inoue, J. Appl. Phys., 81(1997) 3747-3752; [4] B. Orlando, A.–S. Royer , and B.Viala,IEEE Trans.on Magn.,42(2001)3371-3373.], in these application fields, the radio frequency / microwave ferromagnetic properties of ferromagnetic thin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F10/10H01F41/14H01F41/18
Inventor 李山东徐洁何丽珠石星军杜洪磊薛倩高小洋陈彩云谢施名
Owner QINGDAO UNIV
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