A kind of hydrophilic functional carbon sphere and its application in removing heavy metal ions in wastewater
A heavy metal ion, hydrophilic technology, used in alkali metal compounds, water/sewage treatment, adsorbed water/sewage treatment, etc., can solve the problems of unfavorable environmental protection, harsh conditions, and complicated steps of organic solvents, and achieve rich content in nature. , the effect of mild reaction conditions and simple process
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Embodiment 1
[0029] a. Preparation of starch solution: Dissolve potato starch in water, heat and dissolve at 100° C. for 0.5 h, and prepare a 10 g / L transparent solution.
[0030] b. Preparation of hydrophilic functional carbon spheres: Take 120mL of the prepared solution and put it into a 200mL autoclave for 4 hours of hydrothermal reaction at 200°C. After the reaction is completed, cool naturally to room temperature to obtain hydrophilic functional carbon brown solution of balls;
[0031] c. Take the brown solution containing hydrophilic functional carbon spheres and freeze-dry to obtain monodisperse hydrophilic functional carbon sphere powder.
[0032] d. Preparation of copper ion solution: the cupric chloride taken by weighing is mixed with the solution that concentration is 0.05M for subsequent use;
[0033] f. The method for removing copper ions in wastewater by hydrophilic functional carbon spheres: take 50mL of the hydrophilic functional carbon sphere solution obtained in step b i...
Embodiment 2
[0035] a. Preparation of starch solution: Dissolve wheat starch in water, heat and dissolve at 90° C. for 24 hours, and prepare a transparent solution of 0.1 g / L.
[0036] b. Preparation of hydrophilic functional carbon spheres: Take 150mL of the prepared solution and put it into a 200mL autoclave for 24 hours of hydrothermal reaction at 120°C. After the reaction is completed, cool naturally to room temperature to obtain hydrophilic functional carbon brown solution of balls;
[0037] c. Take the brown solution containing hydrophilic functional carbon spheres and freeze-dry to obtain monodisperse hydrophilic functional carbon sphere powders.
[0038] d. The preparation of zinc ion solution: take a certain amount of zinc chloride and be mixed with the solution that concentration is 0.001M for subsequent use;
[0039] f. The method for removing zinc ions in wastewater by hydrophilic functional carbon spheres: take 100mL of the hydrophilic functional carbon sphere solution obtain...
Embodiment 3
[0041] a. Preparation of starch solution: Dissolve cornstarch in water, heat and dissolve at 100° C. for 6 hours, and prepare a transparent solution of 15 g / L.
[0042] b. Preparation of hydrophilic functional carbon spheres: Take 120mL of the prepared solution and put it into a 200mL autoclave for 12 hours of hydrothermal reaction at 180°C. After the reaction is completed, cool naturally to room temperature to obtain hydrophilic functional carbon brown solution of balls;
[0043] c. Freeze-drying the brown solution containing the hydrophilic functional carbon spheres to obtain a monodisperse hydrophilic functional carbon sphere powder.
[0044] d. Preparation of cadmium heavy metal ion solution: take a certain amount of cadmium chloride and prepare a solution with a concentration of 0.05M for subsequent use;
[0045] f. The method for removing cadmium ions in wastewater by hydrophilic functional carbon spheres: take 50mL of the hydrophilic functional carbon sphere solution o...
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